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Rhenium Cluster Complexes with Polyborohydride Anions, [Re6S8(Me2PzH)6]X (X = B10H10, B12H12)

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Abstract

Interaction of [Re6S8(Me2PzH)6]Br2 with K2B10H10 and (Et3NH)2B12H12 yields novel [Re6S8(Me2PzH)6][B10H10] (1) and [Re6S8(Me2PzH)6][B12H12] (2) hybrid compounds combining [Re6S8 (Me2PzH)6]2+ metal-cluster cations and [BnHn]2– polyborohydride cluster anions (n = 10, 12) in their structure. Crystals of the prepared compounds exhibit an ionic 3D supramolecular structure formed by short H–B⋯H–C contacts. At room temperature, these compounds exhibit red phosphorescence with λmax = 680 nm (1) and 670 nm (2), respectively.

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This work was funded by the Russian Science Foundation (project No. 19-73-20196-P).

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  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    M. P. Davydova, T. S. Sukhikh, M. I. Rakhmanova, K. A. Brylev & A. V. Artem’ev

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Russian Text © The Author(s), 2024, published in Zhurnal Strukturnoi Khimii, 2024, Vol. 65, No. 1, 121365.https://doi.org/10.26902/JSC_id121365

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Davydova, M.P., Sukhikh, T.S., Rakhmanova, M.I. et al. Rhenium Cluster Complexes with Polyborohydride Anions, [Re6S8(Me2PzH)6]X (X = B10H10, B12H12). J Struct Chem 65, 186–195 (2024). https://doi.org/10.1134/S0022476624010177

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