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Homoleptic Ferrocenyl Stibine and Bismuthine: Synthesis and Characterization

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Abstract

New tertiary ferrocenyl stibines (I and III) and bismuthine (II) have been synthesized. All these compounds have been characterized by IR, MS, and NMR spectroscopy and the molecular structures of I–III have been determined by X-ray crystallography. Compounds I–III have also been studied by cyclic voltammetry (CV). Crystal structures of homoleptic stibine and bismuthine (I, II) adopt a “propeller” configuration with the three ferrocenyl groups tilted to minimize interatomic repulsion and exhibit helicoidal chirality. The structures of I and III show that both the stibines exhibit an intramolecular C−H···C interaction. The voltammograms of stibines show that E1/2 values are more positive than that of ferrocene indicating that oxidation of Fc3Sb is slightly more challenging in comparison to ferrocene. Triferrocenyl bismuthine (II) displays two redox waves with low resolution and a non-reversible process.

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Funding

This research was funded by DGAPA-UNAM (IN209020) and CONAHCYT (Fellowship 368610) for financial support.

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Authors and Affiliations

  1. Institute of Chemistry, National Autonomous University of Mexico UNAM, 04510, Mexico City, Mexico

    Rocio Rosales, Claudia P. Villamizar C., Rodary Dymarcus, Dorancelly Fernandez & Pankaj Sharma

  2. Faculty Cs. Chemistry BUAP, 72592, Mexico City, Mexico

    Bertin Anzaldo, Guadalupe Hernandez & Rene Gutiérrez Pérez

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  1. Rocio Rosales
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  2. Claudia P. Villamizar C.
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  3. Rodary Dymarcus
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Correspondence to Pankaj Sharma.

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Supplementary Information

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The supporting information includes crystallographic data, NMR spectra, IR and mass spectrometry. The CIF file containing complete information on the studied structure was deposited with CCDC nos. 226161, 1900165, 226162, and is freely available upon request from the following web site: www.ccdc.cam.ac.uk/data_request/cif.

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Rocio Rosales, Villamizar C., C.P., Dymarcus, R. et al. Homoleptic Ferrocenyl Stibine and Bismuthine: Synthesis and Characterization. Russ. J. Inorg. Chem. 68, 1963–1971 (2023). https://doi.org/10.1134/S0036023623602696

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  • DOI: https://doi.org/10.1134/S0036023623602696

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