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Synthesis, Crystal Structure, and Mechanism of Formation of the Half-Sandwich Ruthenium Complexes Based on 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligand and PhCH(OH)C≡CH

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Abstract

Treatment of 16e complex (p-cymene)Ru(S2C2B10H10) (1) with PhCH(OH)C≡CH in CH2Cl2 at room temperature leads to two novel complexes (p-cymene)Ru(S2C2B10H9)(PhCH=CCH2OCH(Ph)C≡CH) (2) and (p-cymene)Ru(S2C2B10H9)(PhCH(OH)C=CH2) (3). Both complexes have been characterized through elemental analysis, mass, IR and NMR spectroscopies. Notably, complex 2 has been studied by X-ray diffraction. It has been determined that complex 2 crystallizes in triclinic system, space group P\(\overline{1}\) with: a = 11.1020(10) Å, b = 11.8445(10) Å, c = 13.8071(12) Å, α = 78.3630(10)°, β = 75.7330(10)°, γ = 68.7580(10)°, C30H38B10ORuS2, Mr = 687.89, V = 1627.3(2) Å3, ρ = 1.404 g/cm3, Z = 2, F(000) = 704, µ(MoKα) = 0.636 mm–1, R = 0.0388 and ωR = 0.1100 for 5658 observed reflections (I > 2σ(I)). The formation mechanisms for the title complexes have been studied.

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Funding

Project supported by the Public Welfare Research Plan Project of Jiaxing City (nos. 2023AY11025; 2021AY10044), the National Natural Science Foundation of China (no. 21261020), the Research Start-up Funding of Jiaxing Nanhu University (nos. QD61220001; N41472001-YB14), and the Open Fund of Zhejiang Engineering Technology Center for Arene Sulfonic Acid (no. ERC202302).

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Authors and Affiliations

  1. College of Advanced Materials Engineering, Jiaxing Nanhu University, 314001, Zhejiang, China

    J. R. Hu, J. S. Liu & S. Q. Sun

  2. College of Humanities and Arts, Jiaxing Nanhu University, 314001, Zhejiang, China

    J. H. Wang

  3. Department of Pharmacy, Pinghu Traditional Chinese Medicine Hospital, 314200, Zhejiang, China

    J. Y. Jin

  4. College of Biology and Chemical engineering, Jiaxing University, 314001, Zhejiang, China

    C. P. Miao

  5. Zhejiang Engineering Research Center for Arene Sulfonic Acid, 314001, Zhejiang, China

    C. P. Miao

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  1. J. R. Hu
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Hu, J.R., Wang, J.H., Jin, J.Y. et al. Synthesis, Crystal Structure, and Mechanism of Formation of the Half-Sandwich Ruthenium Complexes Based on 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligand and PhCH(OH)C≡CH. Russ. J. Inorg. Chem. 68, 1956–1962 (2023). https://doi.org/10.1134/S0036023623603094

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