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A Kinetic Investigation of Hg(II) Catalyzed Cyanide Substitution from [Ru(CN)6]4– by Isoniazid

  • CHEMICAL KINETICS AND CATALYSIS
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Abstract

The kinetics of Hg(II) accelerated substitution of cyanide with isoniazid (INH) from [Ru(CN)6]4– was investigated via measurement of the rise in absorbance at 502 nm. Employing the pseudo-first-order condition, the reaction’s advancement has been examined as an indicator of [Hg(II)], pH, [INH], \([{\text{Ru(CN)}}_{6}^{{4 - }}]\), temperature, and ionic strength. The findings demonstrate that [Hg(II)] and pH are the crucial factors that substantially affect the reaction rate. INH interacts with [Ru(CN)6]4– in a 1 : 1 ratio. At low concentrations, the reaction is first-order dependent on \([{\text{Ru}}\left( {{\text{CN}}} \right)_{6}^{{4 - }}]\), whereas at higher concentrations, it follows fractional order kinetics. In the analyzed ranges of [INH], the reaction reveals first-order kinetics. The linear decline in reaction rate with the addition of electrolytes signifies a negative salt effect. With rising [Hg(II)], complicated behavior in the reaction rate was noticed. The calculated value of activation parameters viz. entropy of activation, enthalpy of activation, and energy of activation are –279.89, 276.35, and 278.99 kJ M–1, respectively. A relevant mechanistic scheme that is consistent with the experimental data and is endorsed by activation parameters has been proposed.

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DATA AVAILABILITY

The datasets generated or analyzed during the current study are available from the corresponding author on reasonable request.

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Authors and Affiliations

  1. Department of Chemistry, B.N College of Engineering and Technology, Lucknow, U.P., India

    Ruchi Singh

  2. Department of Chemistry, GLA University, 281006, Mathura, U.P., India

    Abhishek Srivastava

  3. Department of Chemistry, University of Lucknow, 226007, Lucknow, U.P., India

    Pradeep Kumar Pandey, Shiv Bali Singh Yadav & Radhey Mohan Naik

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  1. Ruchi Singh
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  2. Abhishek Srivastava
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  3. Pradeep Kumar Pandey
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  4. Shiv Bali Singh Yadav
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  5. Radhey Mohan Naik
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Correspondence to Radhey Mohan Naik.

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Singh, R., Srivastava, A., Pandey, P.K. et al. A Kinetic Investigation of Hg(II) Catalyzed Cyanide Substitution from [Ru(CN)6]4– by Isoniazid. Russ. J. Phys. Chem. 97, 3268–3275 (2023). https://doi.org/10.1134/S0036024424030221

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