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Rate Enhancement of Cu(II) Catalyzed L-Glutamic Acid Oxidation by Hexacyanoferrate(III) via Micelle Encapsulation

  • CHEMICAL KINETICS AND CATALYSIS
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Abstract

The proposed study aimed to explore the kinetics of L-glutamic acid (Glu) oxidation in a micellar media of cetylpyridinium chloride (CPC) by hexacyanoferrate(III) {HCF(III)}. The reduction in absorbance at 420 nm, which is indicative of the concentration of HCF(III), was measured to determine the reaction rate. Applying the pseudo-first-order state, The reaction’s progression was analyzed as an indicator of [HCF], temperature, [Glu], [Cu(II)], [CPC], ionic strength, and [OH–]. The findings indicate that the [CPC] is the crucial factor that significantly affects the rate of the reaction. The HCF(III) undergoes a 2 : 1 stoichiometric interaction with Glu and has a first-order reliance on [HCF(III)]. The observed reaction exhibits fractional-first-order kinetics with regards to [Glu], [OH–], and Cu(II), within the range of concentrations investigated. The observed linear augmentation in reaction rate upon electrolyte’s introduction is suggestive of a positive salt effect. The inclusion of CPC substantially enhances the catalytic activity of the process. After reaching its maximum rate, the reaction exhibits a very steady behavior even when the [CPC] is further increased. The observed decrease in CPC CMC could potentially be attributed to the diminished electrostatic repulsion among the cationic surfactant headgroups, which is caused by the anionic [Cu(OH)4]2–, OH–, and HCF(III) species.

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DATA AVAILABILITY

The datasets generated or analyzed during the current study are available from the corresponding author on reasonable request.

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Funding

We did not receive any specific grant for this research from any funding agencies in the public, commercial, or not-for-profit sectors.

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Authors and Affiliations

  1. Department of Chemistry, GLA University, Mathura, U.P., India

    Abhishek Srivastava

  2. Department of Chemistry, D.D.U. Gorakhpur University, Gorakhpur, U.P., India

    Neetu Srivastava

  3. Faculty of Chemical Sciences, Shri Ramswaroop Memorial University Lucknow-Dewa Road, 225003, Barabanki, U.P., India

    Krishna Srivastava

  4. Department of Chemistry, B.N. College of Engineering and Technology, Lucknow, U.P., India

    Ruchi Singh

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  1. Abhishek Srivastava
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  2. Neetu Srivastava
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  3. Krishna Srivastava
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Correspondence to Neetu Srivastava.

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Srivastava, A., Srivastava, N., Srivastava, K. et al. Rate Enhancement of Cu(II) Catalyzed L-Glutamic Acid Oxidation by Hexacyanoferrate(III) via Micelle Encapsulation. Russ. J. Phys. Chem. 97, 3249–3258 (2023). https://doi.org/10.1134/S0036024424030026

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