Abstract
A study on anti-ferroelectric (PbLa)(ZrTi)O3 (PLZT) for electric vehicles (EV) applicable to DC-link was conducted. Multilayer ceramic capacitors (MLCCs) for DC-link require high-electric field properties and reliability. Oxygen vacancies are a major cause affecting insulation properties and reliability. There are acceptors and donors as methods for controlling the mobility and concentration of oxygen vacancies. The mobility and concentration of oxygen vacancies were simultaneously controlled, rather than individually controlled. Mn4+ was selected as the acceptor and Dy3+ was selected as the donor. After fixing Mn4+ = 5.0 mol% to (Pb0.82La0.12)(Zr0.86Ti0.14)O3, insulation properties and reliability were evaluated according to Dy3+ = 5.0, 10.0, 15.0 and 20.0 mol%. A high sintered density was obtained at a temperature of 1200°C in a reduction atmosphere. When Mn4+ = 5.0 mol% and Dy3+ = 10.0 mol% were co-substituted into PLZT, a dielectric constant of about 1800 and a breakdown voltage of about 12 kV mm−1 were obtained. In the co-substituted PLZT, capacitance change and insulation degradation properties were greatly improved. Oxygen vacancy mobility and concentration control were effective in reliability properties. Thermally stimulated depolarization current (TSDC) was analysed to confirm the polarization of oxygen vacancies. TSDC increased with electric field and time. TSDC decreased in co-substituted PLZT compared to un-substituted PLZT. A factor affecting TSDC is the behaviour of oxygen vacancies. Based on the result, the oxygen vacancies are polarized and moved by the application of an electric field, resulting in degradation of insulating properties.
Similar content being viewed by others
References
Seok-Hyun Y, Mi-Yang K and Dong-Hun K 2020 J. Mater. Chem. C 8 9373
Gang Y, Zhenxing Y, Zhilun C and Longtu L 2008 J. Appl. Phys. 104 074115
Hiroshi H, Takayuki G, Koichiro M, Yoshiki I and Takaaki T 2022 J. Ceram. Soc. Jpn 12 913
Hiroshi K, Yasuyuki I, Koichiro M, Yoshiki I and Takaaki T 2022 J. Ceram. Soc. Jpn 12 920
Dong-Woo H and Young-Ho H 2009 J. Korean Ceram. Soc. 46 219
Seok-Hyun Y, Jae-Sung P, Sang-Hyuk K and Doo-Young K 2013 Appl. Phys. Lett. 103 042901
Xiangjun M, Ye Z, Jianye Z, Lipeng Z, Yong L and Xihong H 2022 J. Eur. Ceram. Soc. 42 6493
Li Jinglei, Li Fei, Zhuo Xu and Zhang Shujun 2018 Adv. Mater. 30 1802155
Zhongqiang H, Beihai M, Rachel E K and Uthamalingam B 2014 Appl. Phys. Lett. 104 263902
Xihong H, Jiwei Z, Jinbao X and Xi Y 2007 Ferroelectrics 357 218
Ioana Veronica C, Chingchang C, Chris M F, Jonathon E G, Jennifer Sue F, Jacob L J et al 2017 J. Eur. Ceram. Soc. 37 4631
Zhongqiang H, Beihai M, Shanshan L, Manoj N and Uthamalingam B 2014 Ceram. Inter. 40 557
Ioana Veronica C, Liliana M and Carmen G 2016 J. Am. Ceram. Soc. 99 2382
Huiling G, Xiaohui W, Shaopeng Z, Hai W and Longtu L 2014 J. Eur. Ceram. Soc. 34 1733
Huiling G, Xiaohui W, Shaopeng Z, Zhibin Tian and Longtu L 2012 J. Appl. Phys. 112 114
Takao S and Nobuyoshi F 2017 Jpn J. Appl. Phys. 56 10PB04
Kurt L and George A S 1962 J. Appl. Phys. 33 2036
Eugene L 1982 J. Appl. Phys. 53 6229
Surendra Singh B, Basanta R, Nirupam B and Kumar Mahesh 2016 J. Appl. Phys. 120 115305
Rainer W, Tudor B and Karl-Heinz H 1990 J. Am. Ceram. Soc. 73 1645
Rainer W, Tudor B and Karl-Heinz H 1990 J. Am. Ceram. Soc. 73 1654
Tudor B, Rainer W and Karl-Heinz H 1990 J. Am. Ceram. Soc. 73 1663
Russell Alan M, Thomas A P, Patrick M L and Clive A R 2015 J. Appl. Phys. 118 164102
Yumei Z, Dezhen X, Xiangdong D, Lixue Z, Jun S and Xiaobing R 2013 J. Phys. Condens. Matter 25 435901
Russell A and Clive A R 2016 J. Am. Ceram. Soc. 99 3360
Seok-Hyun Y, Clive A R and Kang-Heon H 2010 J. Appl. Phys. 108 064101
Seok-Hyun Y, Jong-Bong L, Sang-Hyuk K and Doo-Young K 2013 J. Mater. Res. 28 3252
Smyth Donald M 2002 J. Electroceram. 9 179186
Ning H C, Ranjan S and Donald M S 1981 J. Electrochem. Soc. 128 1762
Surendra Singh B, Vijendra Singh B and Mahesh K 2017 Thin Solid Films 17 107
Xin G and Zaoli Z 2003 Acta Mater. 51 2539
Sung-Yoon C, Duk Yong Y and Suk-Joong L K 2002 Acta Mater. 50 3361
Hwan-Wen L, Mike S H C and Hong-Yang L 2009 J. Am. Ceram. Soc. 92 3037
In-Tae S, Hyung-Won K and Seung Ho H 2022 J. Korean. Inst. Electr. Electron. Mater. Eng. 35 103118
Takaaki T, Motohiro S, Hirofumi K, Satoshi W, Kenji S and Hirokazu C 2005 Jpn J. Appl. Phys. 44 69
Junko Y, Naoki K, Arashi T, Akira S, Yukie N and Takeshi N 1996 J. Power Sources 60 199
Shinsuke T, Koichiro M, Youichi M and Hiroshi K 2007 Ferroelectrics 356 78
Wayne L and Clive A R 2008 J. Am. Ceram. Soc. 91 3251
Wayne L and Clive A R 2008 J. Am. Ceram. Soc. 91 3245
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Choi, J.S., Kim, D.C., Shin, H.S. et al. Effect of oxygen vacancies on dielectric property and reliability of anti-ferroelectric PLZT applicable to EV-MLCC. Bull Mater Sci 47, 39 (2024). https://doi.org/10.1007/s12034-023-03105-z
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s12034-023-03105-z