Abstract
A novel 1D Mn(II) coordination polymer, namely, [Mn3(bpz)2(MeCN)2Cl6] n (1) was synthesized by a solvothermal method based on bpz and MnCl2, where bpz is di(1H-pyrazol-1-yl)methane. The X-ray diffraction data show that the crystal structure of complex 1 is a one-dimensional polymer with two different coordination modes of the Mn(II) ions. The structure was modelled with Density Functional Theory (DFT) calculations and the intermolecular interactions were analyzed using the Hirshfeld surface method.
-
Research ethics: None declared.
-
Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
-
Competing interests: The authors declare no conflicts of interest regarding this article.
-
Research funding: This work was supported by Anhui Provincial Engineering Laboratory of Silicon-based Materials, New Energy Materials and Device Innovation Team of Bengbu University, the excellent innovative scientific research team of silicon based materials(2022AH010101), Excellent Young Talents Foundation in Universities of Anhui Province (gxyq2022109), Natural Science in Universities of Anhui Province (KJ2021A1124, 2023AH040363) and Industry-University-Research Collaboration of Bengbu University (00012370, 00012869, 00012870, 00012876, 00012873, 00013322).
-
Data availability: Not applicable.
References
1. Zhang, S. H., Wang, J. M., Zhang, H. Y., Fan, Y. P., Xiao, Y. Dalton Trans. 2017, 46, 410–419; https://doi.org/10.1039/c6dt04059d.Search in Google Scholar PubMed
2. Yang, L., Huang, Q. P., Zhang, C. L., Zhao, R. X., Zhang, S. H. Supramol. Chem. 2014, 26, 81–87; https://doi.org/10.1080/10610278.2013.824084.Search in Google Scholar
3. Cai, G., Cui, P., Shi, W., Morris, S., Lou, S. N., Chen, J., Ciou, J. H., Paidi, V. K., Lee, K. S., Li, S., Lee, P. S. Adv. Sci. 2020, 7, 1903109; https://doi.org/10.1002/advs.201903109.Search in Google Scholar PubMed PubMed Central
4. You, C., Wu, H., Wang, M., Zhang, Y., Wang, J., Luo, Y., Zhai, L., Sun, B., Zhang, X., Zhu, J. Chem. Eur. J. 2017, 23, 5352–5360; https://doi.org/10.1002/chem.201700059.Search in Google Scholar PubMed
5. Xue, C., Zhang, S. X., Zeng, F. L., Dong, H., Ma, S. H., Luo, Y. H. Adv. Mater. Technol. 2023, 8, 2201188; https://doi.org/10.1002/admt.202201188.Search in Google Scholar
6. Sánchez, G., Serrano, J. L., de Arellano, M. C. R., Pérez, J., López, G. Polyhedron 2000, 19, 1395–1046.10.1016/S0277-5387(00)00427-7Search in Google Scholar
7. Tang, L., Wang, Z., Wang, J. Chin. J. Org. Chem. 1999, 19, 442–447.Search in Google Scholar
8. Martins, L. M., PombeiroCoord, A. J. L. Coord. Chem. Rev. 2014, 265, 74–88; https://doi.org/10.1016/j.ccr.2014.01.013.Search in Google Scholar
9. Reger, D. L., Gardinier, J. R., Pellechia, P. J., Smith, M. D., Brown, K. J. Inorg. Chem. 2003, 42, 7635–7643; https://doi.org/10.1021/ic034631g.Search in Google Scholar PubMed
10. Pershina, E. A., Burlutskiy, N. P., Pavlov, D. I., Ryadun, A. A., Fedin, V. P., Potapov, A. S. Russ. J. Coord. Chem. 2022, 48, 601–607; https://doi.org/10.1134/s1070328422100049.Search in Google Scholar
11. Frisch, M. J., Trucks, G. W., Schlegel, H. B., Scuseria, G. E., Robb, M. A., Cheeseman, J. R., Scalmani, G., Barone, V., Mennucci, B., Petersson, G. A., Nakatsuji, H., Caricato, M., Li, X., Hratchian, H. P., Izmaylov, A. F., Bloino, J., Zheng, G., Sonnenberg, J. L., Hada, M., Ehara, M., Toyota, K., Fukuda, R., Hasegawa, J., Ishida, M., Nakajima, T., Honda, Y., Kitao, O., Nakai, H., Vreven, T., Montgomery, J. A.Jr., Peralta, J. E., Ogliaro, F., Bearpark, M., Heyd, J. J., Brothers, E., Kudin, K. N., Staroverov, V. N., Kobayashi, R., Normand, J., Raghavachari, K., Rendell, A., Burant, J. C., Iyengar, S. S., Tomasi, J., Cossi, M., Rega, N., Millam, J. M., Klene, M., Knox, J. E., Cross, J. B., Bakken, V., Adamo, C., Jaramillo, J., Gomperts, R., Stratmann, R. E., Yazyev, O., Austin, A. J., Cammi, R., Pomelli, C., Ochterski, J. W., Martin, R. L., Morokuma, K., Zakrzewski, V. G., Voth, G. A., Salvador, P., Dannenberg, J. J., Dapprich, S., Daniels, A. D., Farkas, Ö., Foresman, J. B., Ortiz, J. V., Cioslowski, J., Fox, D. J. Gaussian 09, (Revision E.01); Gaussian, Inc.: Wallingford CT (USA), 2016.Search in Google Scholar
12. Atay, C. K., Tilki, T., Dede, B. J. Mol. Liq. 2018, 269, 315–326; https://doi.org/10.1016/j.molliq.2018.08.009.Search in Google Scholar
13. Mohammadi, A., Khalili, B., Haghayegh, A. S. Spectrochim. Acta A 2019, 222, 117193; https://doi.org/10.1016/j.saa.2019.117193.Search in Google Scholar PubMed
14. Spackman, M. A., Jayatilaka, D. CrystEngComm 2009, 11, 19–32; https://doi.org/10.1039/b818330a.Search in Google Scholar
15. Spackman, P. R., Turner, M. J., McKinnon, J. J., Wolff, S. K., Grimwood, D. J., Jayatilaka, D., Spackman, M. A. J. Appl. Crystallogr. 2021, 54, 1006–1011; https://doi.org/10.1107/s1600576721002910.Search in Google Scholar PubMed PubMed Central
16. Wolff, S. K., Grimwood, D. J., McKinnon, J. J., Turner, M. J., Jayatilaka, D., Spackman, M. A. CrystalExplorer (Version 3.1); University of Western Australia: Crawley, Western Australia, 2013; pp. 2005–2013.Search in Google Scholar
17. Feng, C., Guo, J. J., Li, Z. Q., Khan, A. Mol. Cryst. Liq. Cryst. 2023, 756, 118–124; https://doi.org/10.1080/15421406.2022.2119737.Search in Google Scholar
18. Xie, W. N., Hua, F. Z., Feng, C., Jiang, Y. H., Zhao, H. Inorg. Chem. Commun. 2020, 119, 108124; https://doi.org/10.1016/j.inoche.2020.108124.Search in Google Scholar
19. Sheldrick, G. M. Acta Crystallogr. 2008, A64, 112–122.10.1107/S0108767307043930Search in Google Scholar PubMed
© 2024 Walter de Gruyter GmbH, Berlin/Boston
