Skip to main content
Log in

The Effects of Shear Parameters on the Stability of Emulsion Explosive Matrices

  • Published:
Colloid Journal Aims and scope Submit manuscript

Abstract

This work demonstrated the criterion of shear stability of emulsion explosive matrices (EEM), combined with rheology test, interfacial tension test, droplet size test and the crystallization test of emulsion explosive matrices. The shear stability of emulsion explosive matrices was defined as the characteristic refinement time of the droplet size decrease in emulsification process. The constitutive relationship between the characteristic refinement time and droplet size of inner phase droplets was proposed by theoretical analysis and experiments on the emulsification process of emulsion explosive matrices. By analyzing the relationship between rheological properties and characteristic refinement time of emulsion explosive matrices, the relationship model between Bingham coefficient and dimensionless coefficient was established to characterize the shear stability of emulsion explosive matrices. The effects of shear strength, shear time and shear shape on the stability of emulsion explosive matrices were studied. In addition, there exists a critical value to quantitatively characterize the shear stability of emulsion explosive matrices.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.
Fig. 9.
Fig. 10.

Similar content being viewed by others

REFERENCES

  1. Masalova, I., Malkin, A.Y., Slatter, P., and Wilson, K., The rheological characterization and pipeline flow of high concentration water-in-oil emulsions, J. Non-Newtonian Fluid Mech., 2003, vol. 112, nos. 2–3, pp. 101–114. https://doi.org/10.1016/S0377-0257(03)00064-8

    Article  CAS  Google Scholar 

  2. Pal, R., Novel viscosity equations for emulsions of two immiscible liquids, J. Rheol., 2001, vol. 45, no. 2, pp. 509–520. https://doi.org/10.1122/1.1339249

    Article  ADS  CAS  Google Scholar 

  3. Pal, R., Viscous behavior of concentrated emulsions of two immiscible Newtonian fluids with interfacial tension, J. Colloid Interface Sci., 2003, vol. 263, no. 1, pp. 296–305. https://doi.org/10.1016/S0021-9797(03)00125-5

    Article  ADS  CAS  PubMed  Google Scholar 

  4. Wang, Y. and Wang, X., Crystallization of interphase droplets in emulsion explosive matrices, J. Dispersion Sci. Technol., 2016, vol. 38, no. 10, pp. 1483–1488. https://doi.org/10.1080/01932691.2016.1255954

    Article  CAS  Google Scholar 

  5. Zhang, K. and Ni, O., Effect of PIBSA-based surfactants on the interfacial interaction, rheology, and stability of highly concentrated water-in-oil emulsion, J. Dispersion Sci. Technol., 2015, vol. 36, no. 4, pp. 556–562. https://doi.org/10.1080/01932691.2014.916622

    Article  CAS  Google Scholar 

  6. Zhang, K. and Ni, O., Rheological properties and stability of highly concentrated water-in-oil emulsions with different emulsifiers, J. Dispersion Sci. Technol., 2015, vol. 36, no. 4, pp. 549–555. https://doi.org/10.1080/01932691.2014.916621

    Article  CAS  Google Scholar 

  7. Zhou, J., Wang, X., and Gong, M., The effect of surfactant on the rheology and stability properties of emulsion explosive matrices, J. Dispersion Sci. Technol., 2022, vol. 43, no. 14, pp. 2156–2164. https://doi.org/10.1080/01932691.2021.1924191

    Article  CAS  Google Scholar 

  8. Zhang, K. and Ni, O., Rheological properties and stability of emulsion explosive matrix, J. Dispersion Sci. Technol., 2015, vol. 36, no. 2, pp. 932–937. https://doi.org/10.1080/01932691.2014.942315

    Article  CAS  Google Scholar 

  9. Masalova, I. and Kharatyan, E., Effect of silica particles on stability of highly concentrated water-in-oil emulsions with non-ionic surfactant, Colloid J., 2013, vol. 75, no. 1, pp. 95–102. https://doi.org/10.1134/S1061933X13010079

    Article  CAS  Google Scholar 

  10. Li, K. and Jin, E., Theory and practice of LKS continuous mulser, Explos. Mater., 2007, vol. 36, no. 1, pp. 33–36. https://doi.org/10.3969/j.issn.1001-8352.2007.06.011

    Article  ADS  Google Scholar 

  11. Zhang, M., Study on the influence of stirring impeller on the storage stability of emulsion explosive, Explos. Mater., 1999, vol. 8, no. 1, pp. 9–14. https://doi.org/10.3969/j.issn.1001-8352.1999.04.003

    Article  Google Scholar 

  12. Mason, T., Bibette, J., and Weitz, D., Yielding and flow of monodisperse emulsions, J. Colloid Interface Sci., 1996, vol. 179, no. 2, pp. 439–448. https://doi.org/10.1006/jcis.1996.0235

    Article  ADS  CAS  Google Scholar 

  13. Bibette, J., Mason, T., and Hu, G., Kinetically induced ordering in gelation of emulsions, Phys. Rev. Lett., 1992, vol. 69, no. 2, pp. 981–984. https://doi.org/10.1103/PhysRevLett.69.981

    Article  ADS  CAS  PubMed  Google Scholar 

  14. Mason, T. and Bibette, J., Shear rupturing of droplets in complex fluids, Langmuir, 1997, vol. 13, no. 17, pp. 4600–4613. https://doi.org/10.1021/la9700580

    Article  CAS  Google Scholar 

  15. Goubault, C., Pays, K., and Olea, D., Shear rupturing of complex fluids: Application to the preparation of quasi-monodisperse water-in-oil-in-water double emulsions, Langmuir, 2001, vol. 17, no. 17, pp. 5184–5188. https://doi.org/10.1021/la010407x

    Article  CAS  Google Scholar 

  16. Morton, B., Taylor, G., and Turner, J., Turbulent gravitational convection from maintained and instantaneous sources, Proc. R. Soc. London, Ser. A, 1956, vol. 234, no. 1196, pp. 1–23. https://doi.org/10.1098/rspa.1956.0011

    Article  ADS  MathSciNet  Google Scholar 

  17. Karam, H. and Bellinger, J., Deformation and breakup of liquid droplets in a simple shear field, Ind. Eng. Chem. Fundam., 1968, vol. 7, no. 4, pp. 576–581. https://doi.org/10.1021/i160028a009

    Article  CAS  Google Scholar 

  18. Aggarwal, N. and Sarkar, K., Deformation and breakup of a viscoelastic drop in a Newtonian matrix under steady shear, J. Fluid Mech., 2007, vol. 584, pp. 1–21. https://doi.org/10.1017/S0022112007006210

    Article  ADS  MathSciNet  Google Scholar 

  19. Bentley, B. and Leal, L., An experimental investigation of drop deformation and breakup in steady, two-dimensional linear flows, J. Fluid Mech., 1986, vol. 167, pp. 241–283. https://doi.org/10.1017/S0022112086002811

    Article  ADS  CAS  Google Scholar 

  20. Rayleigh, L., On the instability of jets, Proceedings of the London Mathematical Society, 1878, vol. 1, no. 1, pp. 4–13. https://doi.org/10.1112/plms/s1-10.1.4

    Article  MathSciNet  Google Scholar 

  21. Rayleigh, L., On the capillary phenomena of jets, Proc. R. Soc. London, 1879, vol. 29, nos. 196–199, pp. 71–97. https://doi.org/10.1098/rspl.1879.0015

    Article  Google Scholar 

  22. Bruijn, R., Tipstreaming of drops in simple shear flows, Chem. Eng. Sci., 1993, vol. 48, no. 2, pp. 277–284. https://doi.org/10.1016/0009-2509(93)80015-I

    Article  CAS  Google Scholar 

  23. Stone, H., Bentley, B., and Leal, L., An experimental study of transient effects in the breakup of viscous drops, J. Fluid Mech., 1986, vol. 173, pp. 131–158. https://doi.org/10.1017/S0022112086001118

    Article  ADS  CAS  Google Scholar 

  24. Mason, T. and Bibette, J., Emulsification in viscoelastic media, Phys. Rev. Lett., 1996, vol. 77, no. 16, pp. 3481–3484. https://doi.org/10.1103/physrevlett.77.3481

    Article  ADS  CAS  PubMed  Google Scholar 

  25. Mabille, C., Lealcalderon, F., and Bibette, J., Monodisperse fragmentation in emulsions: Mechanisms and kinetics, Europhys. Lett., 2003, vol. 61, no. 5, pp. 708–712. https://doi.org/10.1209/epl/i2003-00133-6

    Article  ADS  CAS  Google Scholar 

  26. Schmitt, V., Lealcalderon, F., and Bibette, J., Preparation of monodisperse particles and emulsions by controlled shear, Colloid Chemistry II, 2003, vol. 227, pp. 195–215. https://doi.org/10.1007/3-540-36412-9_8

    Article  CAS  Google Scholar 

  27. Yang, G., Wang, X., and Wang, Y., An influence of microstructure of emulsion explosive on macro performance, Engineering Blasting, 2016, vol. 22, no. 5, pp. 40–44. https://doi.org/10.3969/j.issn.1006-7051.2016.05.009

    Article  Google Scholar 

  28. Zhang, Y., Wang, X., and Wang, Y., Crystallization kinetics of emulsion explosive matrix during aging process, CIESC J., 2018, vol. 69, no. 10, pp. 4464–4470. https://doi.org/10.11949/j.issn.0438-1157.20180399

    Article  CAS  Google Scholar 

  29. Liu, J., Xu, Z., and Kong, Y., Storage stability and demulsion mechanism of emulsion explosives, Explos. Mater., 2015, vol. 44, no. 6, pp. 38–42. https://doi.org/10.3969/j.issn.1001-8352.2015.06.009

    Article  ADS  CAS  Google Scholar 

  30. Masalova, I., Fabrice, K.K., Tshilumbu, N.N., George, N., and Malkin, A.Y., Emulsification of highly concentrated emulsions—A criterion of shear stability, J. Rheol., 2018, vol. 62, no. 3, pp. 781–790.https://doi.org/10.1122/1.5018794

    Article  ADS  CAS  Google Scholar 

Download references

Funding

This work was supported by the State Key Laboratory of Precision Blasting and Hubei Key Laboratory of Blasting Engineering Jianghan University (PBSKL2022C02), National Natural Science Foundation of China (52064003), Science and Technology Research and Development Program of China National Railway Group Co., Ltd. (K2021G024).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yongsheng Jia.

Ethics declarations

The authors of this work declare that they have no conflicts of interest.

Additional information

Publisher’s Note.

Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jianmin Zhou, Jia, Y., Yao, Y. et al. The Effects of Shear Parameters on the Stability of Emulsion Explosive Matrices. Colloid J 86, 153–168 (2024). https://doi.org/10.1134/S1061933X23600872

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061933X23600872

Keywords:

Navigation