Isopointal intermetallics: the cP24, dca phases as a representative set of examples, along with their vacancy-ordered variants β-Mn and SrSi2

Oliver Janka; Rainer Pöttgen

doi:10.1515/znb-2024-0002

Published by De Gruyter February 23, 2024

Isopointal intermetallics: the cP24, dca phases as a representative set of examples, along with their vacancy-ordered variants β-Mn and SrSi₂

Oliver Janka and Rainer Pöttgen

From the journal Zeitschrift für Naturforschung B

https://doi.org/10.1515/znb-2024-0002

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Abstract

The crystal-chemical relationship of the cubic Laves phase MgCu₂ (space group F d 3 ‾ m, cF24) with the ternary phases Cd₂Cu₃In, Na₂Au₃Al, Mg₂Rh₃P, Li₂Pd₃B, Ag₂Pd₃S, Cu₃Pt₂B, Mo₃Al₂C, Mo₃Ni₂N, and V₃Ga₂N (subgroup P4₁32, cP24, dca) is discussed based on a group-subgroup scheme. The course of the lattice parameters and the free positional parameters show substantially different distortions and thus clear differences in chemical bonding, classifying these phases as isopointal rather than isotypic (usually they are all assigned to the Mo₃Al₂C type). The group-subgroup scheme further shows that the β-Mn and SrSi₂ structures are vacancy-ordered variants of the cP24, dca phases. The structures of Mn₃IrSi and LaIrSi (space group types P2₁3; translationengleiche subgroups) are their ternary ordered versions.

Keywords: crystal chemistry; isopointal phases; intermetallics; vacancy ordering variants

Corresponding authors: Oliver Janka, Universität des Saarlandes, Anorganische Festkörperchemie, Campus C4 1, 66123 Saarbrücken, Germany, E-mail: oliver.janka@uni-saarland.de; and Rainer Pöttgen, Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 30, 48149 Münster, Germany, E-mail: pottgen@uni-muenster.de

Research ethics: Not applicable.
Author contributions: Both authors accept responsibility for the entire content of this manuscript and have approved its submission.
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
Research funding: This research was funded by Universität Münster and Universität des Saarlandes.
Data availability: All data is available within the manuscript.

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Received: 2024-01-04

Accepted: 2024-01-12

Published Online: 2024-02-23

Published in Print: 2024-02-26

Isopointal intermetallics: the cP24, dca phases as a representative set of examples, along with their vacancy-ordered variants β-Mn and SrSi₂

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