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Platinum-free materials as cathode for dye-sensitized solar cells: a brief review

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Abstract

This article reviews the use of various types of platinum (Pt)-free materials as cathode for dye-sensitized solar cell. The materials such as conducting polymers, alloys, metal sulphide, metal nitride and metal selenide have been applied as a cathode in the device using TiO2 photoanode, Ru-based dye and a liquid electrolyte containing I–/I3– for Pt substitution. The use of binary, ternary and quaternary metal chalcogenides has been highlighted in this review. The efficiency of the device with those materials has been compared with that of Pt-based device counterparts. The electrochemical impedance spectroscopy, cyclic voltammetry, Tafel parameters and also incident-photon conversion efficiency correlating with power conversion efficiency have been discussed.

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References

  1. O’Regan B and Gratzel M 1991 Nature 353 737

    Article  ADS  Google Scholar 

  2. Rahman M S, Hammed W A, Yahya R B, Muhammad H N and Mahmud E 2016 J. Poly. Res. 23 193

    Article  Google Scholar 

  3. Saranya K, Rameez M and Subramania A 2015 Eur. Poly. J. 66 207

    Article  CAS  Google Scholar 

  4. Wu M and Ma T 2012 ChemSusChem 5 1343

    Article  CAS  PubMed  Google Scholar 

  5. Wang W, Xu X, Liu Y, Zhong Y and Shao Z 2018 Adv. Energy Mater. 8 1800172

    Article  Google Scholar 

  6. Rashidi S, Heydari R K, Esmaeili S, Tran N, Thangi D and Wei W 2021 Prog. Photovolt. 29 238

    Article  CAS  Google Scholar 

  7. Wu J, Lan Z, Lin J, Huang M, Huang Y, Fan L et al 2017 Chem. Soc. Rev. 46 5975

    Article  CAS  PubMed  Google Scholar 

  8. Jin Z, Zhang M, Wang M, Feng C and Wang Z S 2017 Acc. Chem. Res. 50 895

    Article  CAS  PubMed  Google Scholar 

  9. Pringle J M, Armel V and MacFarlane D R 2010 Chem. Commun. 46 5367

    Article  CAS  Google Scholar 

  10. Wang H, Feng Q, Gong F, Li Y, Zhou G and Wang Z S 2013 J. Mater. Chem. A 1 97

    Article  Google Scholar 

  11. Torabi N, Behjat A and Jafari F 2014 Thin Solid Films 573 112

    Article  ADS  CAS  Google Scholar 

  12. Kim D H, Atanasov S E, Lemaire P, Lee K and Parsons G N 2015 ACS Appl. Mater. Interf. 7 3866

    Article  CAS  Google Scholar 

  13. Zhang J, Hao Y, Yang L, Mohammadi H, Vlacopoulus N, Sun L et al 2019 Electrochim. Acta 300 482

    Article  CAS  Google Scholar 

  14. Peri R, Mathan P K and Muthuraaman B 2020 RSC. Adv. 10 4521

    Article  ADS  CAS  PubMed  PubMed Central  Google Scholar 

  15. Pradhan S C and Soman S 2021 Res. Surf. Interf. 5 100030

    Google Scholar 

  16. He B, Meng X and Tang Q 2014 ACS Appl. Mater. Interf. 6 4812

    Article  CAS  Google Scholar 

  17. Omelianovych O, Dao V D, Larina L L and Choi H S 2016 Electrochim. Acta 211 842

    Article  CAS  Google Scholar 

  18. Yang Q, Duan J, Yang P and Tang Q 2016 Electrochim. Acta 190 648

    Article  CAS  Google Scholar 

  19. Bae K H, Park E, Dao V D and Choi H S 2017 J. Alloys Compd. 702 449

    Article  CAS  Google Scholar 

  20. Liu W W, Jiang W, Liu Y C, Niu W J, Liu M C, Kong L B et al 2020 Sci. Rep. 10 9157

    Article  ADS  CAS  PubMed  PubMed Central  Google Scholar 

  21. Yang Q, Yang P, Duan J, Wang X, Wang L, Wang Z et al 2016 Electrochim. Acta 190 85

    Article  CAS  Google Scholar 

  22. Yang X, Zhou L, Feng A, Tang H, Zhang H, Ding Z et al 2014 J. Mater. Res. 29 935

    Article  ADS  CAS  Google Scholar 

  23. Shukla S, Loc N H, Boix P P, Koh T M, Prabhakar R R, Mulmudi H K et al 2014 ACS Nano 8 10597

    Article  CAS  PubMed  Google Scholar 

  24. Hu Z, Xia K, Zhang J, Hu Z and Zhu Y 2014 RSC Adv. 4 42917

    Article  ADS  CAS  Google Scholar 

  25. Hu Z, Xia K, Zhang J, Hu Z and Zhu Y 2015 Electrochim. Acta 170 39

    Article  CAS  Google Scholar 

  26. Huo J, Zheng M, Tu Y, Wu J, Hu L and Dai S 2016 Electrochim. Acta 159 166

    Article  Google Scholar 

  27. Li Y, Chang Y, Zhao Y, Wang J and Wang C 2016 J. Alloys Compd. 679 384

    Article  CAS  Google Scholar 

  28. Wang X, Xie Y, Cai Z, Xiong N, Xu Z, Li M et al 2018 J. Alloys Compd. 739 568

    Article  CAS  Google Scholar 

  29. Vijaya S, Landi G, Wu J J and Anandan S 2019 Electrochim. Acta 294 134

    Article  CAS  Google Scholar 

  30. Kumar K A, Pandurangan A, Arumugam S and Sathiskumar M 2019 Sci. Rep. 9 1228

    Article  ADS  Google Scholar 

  31. Chen X, Zhang Y, Pang Y and Jiang Q 2020 Mater. 13 4647

    Article  CAS  Google Scholar 

  32. Mohammad T, Alam F, Sadhanala A, Upadhyaya H M and Dutta V 2022 ACS Omega 7 39690

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  33. Chen S L, Tao J, Shu H B, Tao H J, Tang Y X, Chen Y Z et al 2017 J. Power Sources 34 60

    Article  Google Scholar 

  34. Yin J, Wang Y, Meng W, Zhou T, Li B, Wei T et al 2017 Nanotech. 28 345403

    Article  ADS  Google Scholar 

  35. Patil S A, Hussain S, Shrestha N K, Mengal N, Jalalah M, Jung J et al 2020 Energy 202 117730

    Article  CAS  Google Scholar 

  36. Aiswarya K M, Raguram T and Rajni K S 2020 Polyhedron 176 114267

    Article  CAS  Google Scholar 

  37. Baptayev B, Tashenov Y, Aliakbarova A, Adilov S and Balanay M 2022 Mater. Today: Proceed. 71 94

    CAS  Google Scholar 

  38. Peter I J, Rajamanickam N, Ragavendran V, Mayandi J and Nithiananthi P 2023 Mater. Sci. Eng. B 287 116142

    Article  Google Scholar 

  39. Qian X, Liu L, Huang J, Chen M and Hou L 2021 J. Alloys Compd. 851 156899

    Article  CAS  Google Scholar 

  40. Wang G, Hou S, Yan C, Lin Y and Liu S 2017 Chem. Eng. J. 322 611

    Article  CAS  Google Scholar 

  41. Gnanasekar S, Van Le Q and Grace A N 2021 Sol. Energy 213 145

    Article  ADS  CAS  Google Scholar 

  42. Kushwaha S and Mandal S 2022 J. Sol. State Electrochem. (in press)

  43. Gong F, Wang H, Xu X, Zhou G and Wang Z S 2012 J. Am. Chem. Soc. 134 10953

    Article  CAS  PubMed  Google Scholar 

  44. Feng C, Zhao G, Li Y, Cheng H and Wang Z S 2019 J. Power Sources 426 16

    Article  ADS  CAS  Google Scholar 

  45. Xia J, Wang Q, Xu Q, Yu R, Chen L, Jiao J et al 2020 Appl. Surf. Sci. 530 147238

    Article  CAS  Google Scholar 

  46. Zatirostami A 2020 J. Alloys Compd. 844 156151

    Article  CAS  Google Scholar 

  47. Razamin N A Y, Woo H J and Winie T 2022 Opt. Mater.: X 13 100119

    CAS  Google Scholar 

  48. Aziz N A S, Rahman M Y A and Umar A A 2022 Sol. State Electron. 190 108255

    Article  CAS  Google Scholar 

  49. Theerthagiri J, Senthil R A, Buraidah M H, Raghavender M, Madhavan J and Arof A K J. Sol. State Chem. 238 113

  50. Qian X, Li H, Shao L, Jiang X and Hou L 2016 ACS Appl. Mater. Interf. 8 29486

    Article  CAS  Google Scholar 

  51. Jiang Q, Pan K, Lee C S, Hu G and Zhou Y 2017 Electrochim. Acta 235 672

    Article  CAS  Google Scholar 

  52. Shao L, Qian X, Li H, Xu C and Hou L 2017 Chem. Eng. J. 315 562

    Article  CAS  Google Scholar 

  53. Wei P, Li J, Hao Z, Yang Y, Li X, Jiang C et al 2019 Appl. Surf. Sci. 492 520

    Article  ADS  CAS  Google Scholar 

  54. Wang H, Huang S, Wang S, Hu Z, Ding G, Qian X et al 2019 J. Electroanal. Chem. 834 26

    Article  ADS  CAS  Google Scholar 

  55. Jiang Q S, Cheng W, Wu J, Li W, Zhu J, Zhu Y et al 2019 Int. J. Hyd. Energy 44 23936

    Article  CAS  Google Scholar 

  56. Huang S, He Q, Liu M, An H and Hou L 2020 J. Alloys Compd. 818 152817

    Article  CAS  Google Scholar 

  57. Du Y F, Fan J Q, Zhou W H, Zhou Z J, Jiao J and Wu S X 2012 ACS Appl. Mater. Interf. 4 1796

    Article  CAS  Google Scholar 

  58. Lou Y, Zhao W, Li C, Huang H, Bai T, Chen C et al 2017 ACS Appl. Mater. Interf. 9 18046

    Article  CAS  Google Scholar 

  59. Wang M, Li Y, Feng C, Zhao G and Wang Z S 2019 Chem. Asian J. 14 1034

    Article  CAS  PubMed  Google Scholar 

  60. Mary C I, Senthilkumar M, Manobalaji G and Babu S M 2021 Sol. State Sci. 116 106612

    Article  Google Scholar 

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Acknowledgements

This work was supported by the Ministry of Higher Education via Universiti Kebangsaan Malaysia under research grant FRGS/1/2019/STG02/UKM/02/1.

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Authors and Affiliations

  1. Institute of Microengineering and Nanoelectronics (IMEN), Universiti Kebangsaan Malaysia, 43600, Bangi, Malaysia

    M Y A Rahman & M Ahmadipour

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  1. M Y A Rahman
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  2. M Ahmadipour
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Correspondence to M Y A Rahman.

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Rahman, M.Y.A., Ahmadipour, M. Platinum-free materials as cathode for dye-sensitized solar cells: a brief review. Bull Mater Sci 47, 45 (2024). https://doi.org/10.1007/s12034-023-03118-8

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