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Preparation and characterization of Fe3O4/ZIF-8 and Fe3O4–MnO2/ZIF-8 composites

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Abstract

Metal–organic frameworks (MOFs) have been employed in many studies recently because of their stability, porosity, and high surface area. Although zeolitic imidazole frameworks (ZIF-8) have many advantages among MOFs, they have disadvantages such as low activity, conductivity, and reusability depending on the application. To overcome these drawbacks, Fe3O4 and a mixture of Fe3O4 and MnO2 were added into the structure of ZIF-8. The SEM and STEM analysis of the synthesized materials showed that the polyhedral structure of ZIF-8 was hardly affected by the integration of metal oxides into the structure. FTIR and XPS results showed the presence of peaks arising from organic ligands and metal bonds with ZIF-8 in metal oxide/ZIF-8. Addition of Fe3O4 and Fe3O4–MnO2 to structure of ZIF-8 decreased the surface area of ZIF-8 with the formation of mesopores and accumulation of metal oxide particles in pores. When the synthesized metal oxide/ZIF-8 samples were tested in supercapacitor applications, MnO2/ZIF-8 electrode showed the highest specific capacitance. In addition, the presence of metal oxides in the ZIF-8 improved conductivity of the material. Based on the properties of metal oxide/ZIF-8 composites, the materials have also a potential for applications such as gas storage, adsorption, catalysts, and membranes.

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No computer codes are developed. All the experimental results are presented and discussed in the manuscript.

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Acknowledgements

Ayten Ateş thanks the Sivas Cumhuriyet University Research Foundation (CUBAP), which provided financial support for this project under Grant Number M-2021-803.

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  1. Ayten Ateş

    Present address: Department of Chemical Engineering, Engineering Faculty, Sivas Cumhuriyet University, 58140, Sivas, Turkey

Authors and Affiliations

  1. Department of Chemical Engineering, Engineering Faculty, Sivas Cumhuriyet University, 58140, Sivas, Turkey

    Fulya Kümbetlioğlu

  2. Department of Metallurgical and Materials Engineering, Sivas Cumhuriyet University, Sivas, Turkey

    Kürşad Oğuz Oskay

Authors
  1. Fulya Kümbetlioğlu
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  2. Kürşad Oğuz Oskay
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  3. Ayten Ateş
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FK helped in methodology, conceptualization, original draft preparation, and writing, review, and editing. KOO contributed to review and methodology. AA worked in supervision, review, methodology, and editing.

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Correspondence to Ayten Ateş.

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Kümbetlioğlu, F., Oskay, K.O. & Ateş, A. Preparation and characterization of Fe3O4/ZIF-8 and Fe3O4–MnO2/ZIF-8 composites. J IRAN CHEM SOC 21, 1079–1088 (2024). https://doi.org/10.1007/s13738-024-02978-z

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  • DOI: https://doi.org/10.1007/s13738-024-02978-z

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