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Photoinduced Increase in the Conjugation Length of Polymer Chains in Blue-Phase Polydiacetylene Films based on Diacetylene Alcohol Derivatives

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Abstract

Photoinduced polymerization of Langmuir–Schaefer monolayers of four unsymmetrical hydroxyalkadiynyl N-arylcarbamate derivatives, prepared on the basis of diynes solutions with an extremely low concentration, was studied under prolonged UV irradiation. The kinetics of these diacetylene (DA) molecules films transition to the blue phase of polydiacetylenes (PDA) films, which is not characteristic of any other DA alcohol derivatives, has been studied by light absorption spectroscopy and scanning electron microscopy. The structure homogeneity of DA and PDA films was demonstrated. A continuous shift of the optical absorption band of each PDA film to the long-wavelength region of the spectrum during 60 min of UV light irradiation was found. That indicated an increase of the chains conjugation length in blue-phase PDA samples.

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ACKNOWLEDGMENTS

The work was carried out using equipment of the Center of Collective Use at the Federal Research Center “Crystallography and Photonics,” Russian Academy of Sciences.

Funding

The study was carried out within the framework of the state task of the Prokhorov General Physics Institute, Russian Academy of Sciences, and Federal Research Center “Crystallography and Photonics,” Russian Academy of Sciences. No additional grants to carry out or direct this particular research were obtained.

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Authors and Affiliations

  1. Prokhorov General Physics Institute, Russian Academy of Sciences, 119991, Moscow, Russia

    A. S. Alekseev, A. B. Ivanov & R. M. Sarimov

  2. Shubnikov Institute of Crystallography, Federal Research Center “Crystallography and Photonics”, Russian Academy of Sciences, 119333, Moscow, Russia

    V. V. Klechkovskaya, M. S. Lukasov & T. O. Teplyakova

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  1. A. S. Alekseev
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  2. A. B. Ivanov
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  3. V. V. Klechkovskaya
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  4. M. S. Lukasov
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  6. T. O. Teplyakova
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Correspondence to A. S. Alekseev.

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The presented work is dedicated to the memory of Professor I.N. Domnin.

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Alekseev, A.S., Ivanov, A.B., Klechkovskaya, V.V. et al. Photoinduced Increase in the Conjugation Length of Polymer Chains in Blue-Phase Polydiacetylene Films based on Diacetylene Alcohol Derivatives. rev. and adv. in chem. 13, 265–275 (2023). https://doi.org/10.1134/S263482762360010X

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