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Synthesis, Structure, and Properties of 4-Methyl-N-[2-(Pentafluorophenyliminomethyl)Phenyl]Methyl-Benzenesulfamide and the Copper(II) Complex Based on It

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Abstract

A new azomethine compound 4-methyl-N-[2-pentafluorophenyliminomethyl)phenyl]methylbenzenesulfamide and a Cu(II) complex based on it are obtained and characterized by 1H NMR, IR spectroscopy and the elemental analysis. Crystal structures of azomethine and its complex are analyzed by single crystal X-ray diffraction (XRD). From the single crystal XRD data it is found that the Cu(II) complex crystallizes in the triclinic space group \(P\bar{1}\). The unit cell contains two crystallographically independent mononuclear molecules with similar geometries. In the complex, copper ions have a distorted tetrahedral environment of four nitrogen atoms, which is formed by two bidentate coordinated azomethine ligands. From magnetic measurements it is found that the Cu(II) complex is paramagnetic.

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Scheme 1
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Funding

The work was supported by the Ministry of Science and Higher Education of the Russian Federation (state assignment in the research field No. FENW-2023-0014, 2023).

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Authors and Affiliations

  1. Southern Federal University, Institute of Physics, Rostov-on-Don, Russia

    V. G. Vlasenko & A. A. Shiryaeva

  2. Southern Federal University, Institute of Physical and Organic Chemistry, Rostov-on-Don, Russia

    A. S. Burlov & S. A. Mashchenko

  3. Kurnakov Institute of General and Inorganic Chemistry, Moscow, Russia

    S. A. Nikolaevskii & M. A. Kiskin

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Russian Text © The Author(s), 2024, published in Zhurnal Strukturnoi Khimii, 2024, Vol. 65, No. 2, 121603.https://doi.org/10.26902/JSC_id121603

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Vlasenko, V.G., Burlov, A.S., Nikolaevskii, S.A. et al. Synthesis, Structure, and Properties of 4-Methyl-N-[2-(Pentafluorophenyliminomethyl)Phenyl]Methyl-Benzenesulfamide and the Copper(II) Complex Based on It. J Struct Chem 65, 256–266 (2024). https://doi.org/10.1134/S0022476624020045

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