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Synthesis, Supramolecular Insight, Hirshfeld Surface Analyses and Magnetic Properties of Two Lanthanide Complexes of 1,8-naphthalene Dicarboxylate

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Abstract

Two isostructural mononuclear complexes of lanthanides (Ln = La and Pr) constructed from 1,8-naphthalene dicarboxylate (NDC) and 1,10-phenanthroline (Phen) as auxiliary ligand are reported. Both the complexes were formed through an in situ hydrolytic ring opening reaction of 1,8-naphthalic anhydride with Phen ligands. 3D supramolecular structures are observed which are guided by different weak interactions. The crystal structures of both the complexes were determined by single crystal X-ray diffraction. The room temperature photoluminescence studies, carried out in the powder state displayed three noticeable peaks from excited (3PJ; J = 2, 1, and 0) to ground state (3H4) at ~464 nm, 497 nm, and 538 nm, respectively, under UV excitation. Temperature dependent dc susceptibility (χ = M/H) as a function of temperature is investigated where Pr-complex shows antiferromagnetic behaviour. The Hirshfeld surface analysis of the two complexes is also described.

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  1. Department of Chemistry, S. B. Deorah College, Ulubari, Guwahati, India

    J. K. Nath

  2. Department of Physics, IIT Guwahati, Guwahati, Assam, India

    R. Borah

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Text © The Author(s), 2024, published in Zhurnal Strukturnoi Khimii, 2024, Vol. 65, No. 2, 119099.https://doi.org/10.26902/JSC_id119099

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Nath, J.K., Borah, R. Synthesis, Supramolecular Insight, Hirshfeld Surface Analyses and Magnetic Properties of Two Lanthanide Complexes of 1,8-naphthalene Dicarboxylate. J Struct Chem 65, 217–229 (2024). https://doi.org/10.1134/S002247662402001X

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