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Synthesis, Structure, and Photoluminescent Properties of Zn2+, Mn2+, Cd2+, Eu3+, and Tb3+ Complexes with 4-Allyl-2,3,5,6-Tetrafluorobenzoic Acid Anions and 1,10-Phenanthroline

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Abstract

We report a synthesis of a series of molecular compounds and coordination polymers of Zn2+, Mn2+ Cd2+, Eu3+, and Tb3+ with 4-allyl-2,3,5,6-tetrafluorobenzoic acid (4-Afb) anions and 1,10-phenanthroline with compositions [Zn(H2O)(phen)(4-Afb)2] (1), [Mn(H2O)(phen)(4-Afb)2]n·nH2O (2), [Cd(H2O)(phen)(4-Afb)2]n (3), [Cd(phen)(4-Afb)2]n (4), [Ln2(phen)2(4-Afb)6] (Ln = Eu 5Eu; Tb 5Tb). It is shown that the obtained cadmium coordination polymers have various compositions and structures, depending on crystallization conditions. The prepared compounds are characterized by single-crystal XRD, powder XRD, IR spectroscopy, and CHN analysis. Noncovalent interactions are analyzed using the Hirshfeld surface analysis. It is determined that the crystal packings is mainly stabilized by π⋯π, C–H⋯F, and C–F⋯π interactions. The photoluminescent properties of the 5Eu and 5Tb complexes are studied. It is shown that the structure-forming effects of non-covalent “arene–perfluoroarene” interactions can be possibly used for preorganizing reactive functional groups in the crystal.

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Funding

This work was funded by the Russian Science Foundation (project No. 22-73-10192).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    M. A. Shmelev, A. S. Chistyakov, G. A. Razgonyaeva, J. K. Voronina, E. A. Varaksina, A. A. Sidorov & I. L. Eremenko

  2. Lebedev Physical Institute of the Russian Academy of Sciences, Moscow, Russia

    E. A. Varaksina & I. V. Taydakov

Authors
  1. M. A. Shmelev
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  2. A. S. Chistyakov
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  3. G. A. Razgonyaeva
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  4. J. K. Voronina
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  5. E. A. Varaksina
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  6. I. V. Taydakov
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  7. A. A. Sidorov
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  8. I. L. Eremenko
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Correspondence to M. A. Shmelev.

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Russian Text © The Author(s), 2024, published in Zhurnal Strukturnoi Khimii, 2024, Vol. 65, No. 2, 122814.https://doi.org/10.26902/JSC_id122814

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Shmelev, M.A., Chistyakov, A.S., Razgonyaeva, G.A. et al. Synthesis, Structure, and Photoluminescent Properties of Zn2+, Mn2+, Cd2+, Eu3+, and Tb3+ Complexes with 4-Allyl-2,3,5,6-Tetrafluorobenzoic Acid Anions and 1,10-Phenanthroline. J Struct Chem 65, 362–380 (2024). https://doi.org/10.1134/S0022476624020148

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  • DOI: https://doi.org/10.1134/S0022476624020148

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