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A Tris-Chelate Nickel Complex of Formylhydrazine: Synthesis and Crystal Structure

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Abstract

The Ni(FH)3Cl2·H2O complex is prepared by the in situ reaction of formic acid, hydrazine hydrate, and nickel(II) chloride. It is structurally characterized as a tris-chelated complex cation containing chloride anions as counterions and crystallizing in the P21/c centrosymmetric monoclinic space group.

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REFERENCES

  1. Yu. Ya. Kharitonov, R. I. Machkhoshvili, D. P. Metreveli, and N. I. Pirtskhalava. Kompleksnye soedineniya nitratov i tiotsianatov metallov s formilgidrazinom (Complex compounds of metal nitrates and thiocyanates with formylhydrazine). Koord. Khim., 1977, 3(6), 897. [In Russian]

  2. Yu. Ya. Kharitonov, R. I. Machkhoshvili, D. P. Metreveli, and N. I. Pirtskhalava. Kompleksnye soedineniya khloridov i sul′fatov metallov s formilgidrazinom (Complex compounds of metal chlorides and sulfates with formylhydrazine). Koord. Khim., 1977, 3(7), 1069. [In Russian]

  3. J. Macicek. Bis(formylhydrazine-N,O)-bis(isothiocyanato)-cobalt(II). Abstracts of Papers: IX European Crystallographic Meeting (ECM-9), Torino, Italy, Sept 2-6, 1985. 1985, 183.

  4. K. Srinivasan, S. Govindarajan, and W. T. A. Harrison. Divalent metal complexes of formylhydrazine: Syntheses and crystal structures of M(CH4N2O)2(H2O)2·2NO3 (M = Zn, Co). Inorg. Chem. Commun., 2009, 12, 619. https://doi.org/10.1016/j.inoche.2009.05.002

    Article  CAS  Google Scholar 

  5. W. F. Zhu, J. B. Qiao, and G. L. Zhou. Pd/C-catalyzed reductive coupling of aryl halides using formic hydrazide as reducing agent. Chin. J. Org. Chem., 2008, 28, 1259. http://sioc-journal.cn/Jwk_yjhx/EN/Y2008/V28/I07/1259

  6. CrysAlisPro, version 1.171.38.41. Oxford, England: Rigaku Oxford Diffraction, 2015. https://www.rigaku.com/en/products/smc/crysalis

  7. G. M. Sheldrick. SHELXT - Integrated space-group and crystal-structure determination. Acta Crystallogr., Sect. A: Found. Adv., 2015, 71(1), 3-8. https://doi.org/10.1107/s2053273314026370

    Article  ADS  Google Scholar 

  8. G. M. Sheldrick. Crystal structure refinement with SHELXL. Acta Crystallogr., Sect. C: Struct. Chem., 2015, 71(1), 3-8. https://doi.org/10.1107/s2053229614024218

    Article  ADS  Google Scholar 

  9. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, and H. Puschmann. OLEX2: a complete structure solution, refinement and analysis program. J. Appl. Crystallogr., 2009, 42(2), 339-341. https://doi.org/10.1107/s0021889808042726

    Article  CAS  Google Scholar 

  10. M. M. Mostafa, R. M. El-Shazly, T. H. Rakha, and M. H. Abdel-Rahman. The dangers of using KBr, KI and CaI2 as mulling agents during the preparation of infrared discs of complexes. Transition Met. Chem., 2002, 27, 337. https://doi.org/10.1023/A:1014830319501

    Article  CAS  Google Scholar 

  11. C. Sitong, G. Weiming, Z. Bo, Z. Tonglai, and Y. Li. Methyl carbazate energetic complexes: Transition metal perchlorates - Syntheses, crystal structures and properties. Polyhedron, 2016, 117, 110. https://doi.org/10.1016/j.poly.2016.05.032

    Article  CAS  Google Scholar 

  12. A. Hołtra, P. Drozdzewski, and M. Kubiak. Reinvestigation of zinc(II) complexation by 2-thiophenecarboxylic hydrazide: X-ray structure of tris(2-thiophenecarboxyhydrazide)zinc(II) tetrachlorozincate(II) di(ethanol) and vibrational spectroscopy of its decomposition product. Polyhedron, 2007, 26, 2786. https://doi.org/10.1016/j.poly.2007.01.027

    Article  CAS  Google Scholar 

  13. R. K. Tukhtaev, S. V. Larionov, R. F. Klevtsova, L. I. Myachina, L. A. Glinskaya, T. A. Udalova, and N. Z. Lyakhov. Sintez melkodispersnogo nikelya putem termoliza kompleksa (N2H5)[Ni(NH2NHCOO)3]·H2O v organicheskikh zhidkostyakh i utochnenie kristallicheskoi struktury kompleksa (Synthesis of finely dispersed nickel by thermolysis of the complex (N2H5) [Ni (NH2NHCOO)3]·H2O in organic liquids and refinement of the crystal structure of the complex). Zh. Neorg. Khim., 2011, 56(6), 937. [In Russian]

  14. Yu. Ya. Kharitonov, I. K. Kireeva, D. P. Metreveli, and R. I. Machkhoshvili. IK spektry pogloshcheniya i lazernye spektry KR kompleksov khloridov metallov s formilgidrazinom (IR absorption spectra and laser Raman spectra of complexes of metal chlorides with formylhydrazine). Koord. Khim., 1977, 3(10), 1541. [In Russian]

  15. M. Pinsky and D. Avnir. Continuous symmetry measures. 5. The classical polyhedra. Inorg. Chem., 1998, 37(21), 5575-5582. https://doi.org/10.1021/ic9804925

    Article  CAS  PubMed  Google Scholar 

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Funding

This work was funded by the Ministry of Science and Higher Education of the Russian Federation (State Assignment in the field of scientific activity, 2023; project No. FENW-2023-0015).

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Authors and Affiliations

  1. Research Institute of Physics, Southern Federal University, Rostov-on-Don, Russia

    A. A. Zabolotnyi & N. V. Ter-Oganessian

  2. North-Caucasus Federal University, Stavropol, Russia

    O. P. Demidov

  3. Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia

    S. B. Zaichenko & A. V. Bicherov

Authors
  1. A. A. Zabolotnyi
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  2. O. P. Demidov
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  3. S. B. Zaichenko
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  4. A. V. Bicherov
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  5. N. V. Ter-Oganessian
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Correspondence to A. A. Zabolotnyi.

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Russian Text © The Author(s), 2024, published in Zhurnal Strukturnoi Khimii, 2024, Vol. 65, No. 2, 122810.https://doi.org/10.26902/JSC_id122810

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Zabolotnyi, A.A., Demidov, O.P., Zaichenko, S.B. et al. A Tris-Chelate Nickel Complex of Formylhydrazine: Synthesis and Crystal Structure. J Struct Chem 65, 355–361 (2024). https://doi.org/10.1134/S0022476624020136

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