${\mathrm{V}}_2{\mathrm{O}}_3$, as a typical strongly correlated material, possesses great application value due to its unique metal-insulator transition property. However, the difficulty of epitaxially growing high-quality ${\mathrm{V}}_2{\mathrm{O}}_3$ thin films on semiconductor substrates has dramatically limited its development in electronic devices. Here, we utilize the similarity of the local structure of the (001) plane to achieve the epitaxial growth of high-quality ${\mathrm{V}}_2{\mathrm{O}}_3$ thin films on the 4H-SiC substrate. By changing the strain in the films to induce the paramagnetic metal (PM) to paramagnetic insulator (PI) transition occurrence, we realize a giant resistivity change ($\mathrm{\Delta }\mathrm{R}/\mathrm{R}=107500\%$) at room temperature. Raman spectra results show that the electrical properties of the strain-controlled films are realized by increasing/decreasing the $a_{1g}$ orbital occupation, supporting the scenario of trigonal distortion, in which the PM-PI transition can be understood as orbital-selective MIT caused by small changes in the trigonal distortion. The ability to epitaxially grow on semiconductor substrates and to modulate electrical properties by strain makes ${\mathrm{V}}_2{\mathrm{O}}_3/\text{4H-SiC}$ thin films an ideal platform for exploring and studying Mott devices.

• Received 19 November 2023
• Revised 17 January 2024
• Accepted 20 February 2024

DOI:https://doi.org/10.1103/PhysRevMaterials.8.035001