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Anion-hosting cathodes for current and late-stage dual-ion batteries

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Abstract

Anion-hosting cathodes capable of reversibly storing large-size anions play a leading role in dual-ion batteries (DIBs). The purpose of the present review is to summarize the most promising anion-hosting cathodes for current and late-stage DIBs. This review first summarizes the developments in conventional graphite cathodes, especially the latest advances in the graphite-related research. Next, organic cathodes for the anion storage are discussed, including aromatic amine polymers, heterocyclic polymers, bipolar compounds, and all-carbon-unsaturated compounds. Then, the review focuses on the conversion-type cathodes with high theoretical specific capacities. Finally, the future research directions of the cathodes of DIBs are proposed.

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Acknowledgements

The authors gratefully acknowledge the financial support from National Key R&D Program of China (2022YFB2402600), National Natural Science Foundation of China (52125105, 51972329), NSFC/RGC Joint Research Scheme (Project No: N_CityU104/20 and 52061160484), Science and Technology Planning Project of Guangdong Province (2021TQ05L894), and Shenzhen Science and Technology Planning Project (JSGG20211108092801002, JSGG20220831104004008), Quality and Reform Project of Guangdong province undergraduate teaching (XQSYS-2222873), and Key Scientific Research Projects of General Universities in Guangdong Province (2021KCXTD086).

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  1. These authors contributed equally to this work.

Authors and Affiliations

  1. School of Chemistry and Materials Science, Guangdong University of Education, Guangzhou, 510303, China

    Miao Zhang

  2. Advanced Energy Storage Technology Research Center, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055, China

    Miao Zhang, Wenyong Zhang, Fan Zhang & Yongbing Tang

  3. Center of Super-Diamond and Advanced Film (COSDAF), City University of Hong Kong, Kowloon, 999077, China

    Chun-Sing Lee

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  1. Miao Zhang
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  2. Wenyong Zhang
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  3. Fan Zhang
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Correspondence to Fan Zhang or Yongbing Tang.

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Zhang, M., Zhang, W., Zhang, F. et al. Anion-hosting cathodes for current and late-stage dual-ion batteries. Sci. China Chem. 67, 1485–1509 (2024). https://doi.org/10.1007/s11426-023-1957-3

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