Abstract
The paper presents an investigation into the reduction and adsorption performance of hierarchically structured carbon films (HSCFs). The HSCFs are synthesized from glucose using a molten magnesium catalyst under a layer of molten salts during their reaction with an aqueous sodium permanganate solution at pH values from 1 to 14 and temperatures from 20 to 80 °C. By increasing the temperature from 20 to 80 °C, the reduction and adsorption of Mn (VII) on the HSCFs is accelerated by a factor of 150; moreover, the reaction products are not temperature-dependent. According to Raman and photoelectron spectroscopy data, synthesis in the neutral and basic sodium permanganate solutions produces an “HSCF-sodium-manganese spinel” nanocomposite, the greater part (≈ 80%) of whose manganese is in a tetravalent state, while the remainder is in a trivalent state. The predominant precipitation of manganese spinel nanocrystals on the developed side of the carbon film may be related to the full disappearance of the sp hybridized carbon peak on the XPS spectra. It is shown for the first time that the reactivity of carbon varies with its valence state. Of the three hybridized states of carbon, sp hybridized carbon is demonstrated to have the highest reactivity. It is confirmed that 100% reduction and adsorption from 0.01 to 0.1 M sodium permanganate solutions occur in neutral and basic media. The adsorption capacity of the hierarchically structured carbon film interacting with 0.1 M sodium permanganate solution is more than 450 mg/g, representing a high adsorption performance as compared to other carbon nanomaterials investigated earlier.
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References
R.A. Wuan, F.E. Okieimen, J.A. Imborvungu, Removal of heavy metals from a contaminated soil using organic chelating acids. Int. J. Environ. Sci. Technol.J. Environ. Sci. Technol. 7, 485–496 (2010). https://doi.org/10.1007/BF03326158
L. Li, Y. Li, C. Yang, Chemical filtration of Cr (VI) with electrospun chitosan nanofiber membranes. Carbohydr. Polym. 140, 299–307 (2016). https://doi.org/10.1016/j.carbpol.2015.12.067
F. Fu, Q. Wang, Removal of heavy metal ions from wastewaters: a review. J. Environ. Manage. 92, 407–418 (2011)
S. Ghobadi, B. Samiey, A. Ghanbari, Adsorption and reduction coupling of permanganate on MoS2: water treatment and metal ion separation. J. Solid State Chem. 304, 122588 (2021)
S. Ghobadi, B. Samiey, E. Esmaili, C.H. Cheng, Comparison of kinetics of adsorption of permanganate on Co-Al-layered double hydroxide and MoS2 nanocompounds. Acta Chim. Slov. 70, 44–58 (2023)
F. Chen, M. Hong, W. You, Ch. Li, Y. Yu, Simultaneous efficient adsorption of Pb2+ and MnO4− ions by MCM-41 functionalized with amine and nitrilotriacetic acid anhydride. Appl. Surf. Sci. 357, 856–865 (2015)
I.A. Ahmed, M. Badawi, A. Bonilla-Petriciolet, E.C. Lima, M.K. Seliem, M. Mobarak, Insights into the Mn(VII) and Cr(VI) adsorption mechanisms on purified diatomite/MCM-41 composite: experimental study and statistical physics analysis. Front. Chem. 9, 814431 (2022)
S.A. Bani-Atta, Potassium permanganate dye removal from synthetic wastewater using a novel, low-cost adsorbent, modifed from the powder of Foeniculum vulgare seeds. Sci. Rep. 12, 4547 (2022). https://doi.org/10.1038/s41598-022-08543-z
R.K. Verma, R. Kapoor, S.K. Gupta, R.R. Chaudhari, An efficient technique for removal of K+ and MnO4- ions through adsorption in aqueous solution by using activated charcoal. Pharm. Chem. J. 1(2), 20–25 (2014)
T.C. Egbosiuba, A.S. Abdulkareem, A.S. Kovo, E.A. Afolabi, J.O. Tijani, W.D. Roos, Enhanced adsorption of As(V) and Mn (VII) from industrial wastewater using multi-walled carbon nanotubes and carboxylated multi-walled carbon nanotubes. Chemosphere 254, 126780 (2020)
N. Kumar, J.R. Rodriguez, V.G. Pol, A. Sen, Facile synthesis of 2D graphene oxide sheet enveloping ultrafine 1D LiMn2O4 as interconnected framework to enhance cathodic property for Li-ion battery. Appl. Surface Sci. 463, 132–140 (2019)
L. Chen, D. Li, X. Zheng, L. Chen, Y. Zhang, Z. Liang, Integrated nanocomposite of LiMn2O4/graphene/carbon nanotubes with pseudocapacitive properties as superior cathode for aqueous hybrid capacitors. J. Electroanal. Chem. 842, 74–81 (2019)
R. Kumar, A. Soam, Synthesis and characterization of sucrose derived carbon/MnO2 nanocomposite. Mater. Today: Proc. 35, 76–78 (2021)
R. Tabassam, F. Alvi, N. Aslam, R. Raza, L.S. Saifur-Rehman et al., Electrochemical investigation of LiMn2O4/asphalt and LiMn2O4/bituminous coal based cathode composites for efficient lithium-ion battery. Mater. Lett. 302, 130275 (2021)
N. Kano, M. Pang, Y. Deng, H. Imaizumi, Adsorption of rare earth elements (REEs) onto activated carbon modified with potassium permanganate (KMnO4). J. Appl. Sol. Chem. Model. 6, 51–61 (2017)
Z. Gao, S. Xu, L. Li, G. Yan, W. Yang, C. Wu, I.D. Gates, On the adsorption of elemental mercury on single-atom TM (TM = V, Cr, Mn, Co) decorated graphene substrates. Appl. Surface Sci. 516, 146037 (2020)
S. Mopoung, T. Bunterm, KMnO4 modified carbon prepared from waste of pineapple leaf fiber production processing for removal of ferric ion from aqueous solution. Am. J. Appl. Sci. 13(6), 814–826 (2016)
J. Zhang, Phenol removal from water with potassium permanganate modified granular activated carbon. J. Environ. Prot. 4(5), 411–417 (2013). https://doi.org/10.4236/jep.2013.45049
M.M. Kadam, K.B. Dhopte, N. Jha, V.G. Gaikar, P.R. Nemade, Synthesis, characterization and application of c-MnO2/graphene oxide for the selective aerobic oxidation of benzyl alcohols to corresponding carbonyl compounds. New J. Chem. 40, 1436 (2016)
T. Prasankumar, J. Vigneshwaran, M. Bagavathi, S. Jose, Expeditious and eco-friendly synthesis of spinel LiMn2O4 and its potential for fabrication of supercapacitors. J. Alloys Compd. 834, 155060 (2020)
D.B. Freitas Neto, F.F.S. Xavier, E.Y. Matsubara, R. Parmar, R. Gunnella, J.M. Rosolen, The role of nanoparticle concentration and CNT coating in high-performance polymer-free micro/nanostructured carbon nanotube-nanoparticle composite electrode for Li intercalation. J. Electroanal. Chem. 858, 113826 (2020)
H.J. Yue, X.K. Huang, D.P. Lv, Y. Yang, Hydrothermal synthesis of LiMn2O4/C composite as a cathode for rechargeable lithium-ion battery with excellent rate capability. Electrochim. Acta 54, 5363–5367 (2009)
V.A. Yolshina, L.A. Yolshina, V.A. Elterman, E.G. Vovkotrub, A.A. Shatunova, V.I. Pryakhina, N.A. Khlebnikov, N.V. Tarakina, Synthesis of and characterization of freestanding, high-hierarchically structured graphene-nanodiamond films. Mater. Design 135, 343–352 (2017)
L.A. Yolshina, V.A. Yolshina, S.V. Pershina, V.I. Pryakhina, Study of thermal stability of hierarchical structured carbon composite flakes. Diam. Relat. Mater. 119, 108556 (2021)
V.A. Yolshina, L.A. Yolshina, V.I. Pryakhina, SEM and XPS study of Cr6+ removal from wastewater via reduction and adsorption by hierarchically structured carbon composite in neutral media. J. Inorg. Organomet. Polym. Mater. 31(8), 3624–3635 (2021)
V.A. Dorogova, L.A. Elshina, Synthesis of hybrid carbon nanocomposites with potassium spinel KMn2O4 at low temperatures in a neutral medium. Russ. Metall. (Metally) 8, 906–913 (2022)
L.A. Elshina, V.A. Elshina, Synthesis of a nanocrystalline α-Al2O3 powder in molten halides in the temperature range 700–800°C. Russ. Metall. (Metally) 2, 138–141 (2020)
A. Sadezky, H. Muckenhuber, H. Grothe, R. Niessner, U. Poschl, Raman microspectroscopy of soot and related carbonaceous materials: spectral analysis and structural information. Carbon 43, 1731–1742 (2005)
R. Trócoli, A. Morata, C. Erinmwingbovo, F. La Mantia, A. Tarancón, Self-discharge in Li-ion aqueous batteries: a case study on LiMn2O4. Electrochim. Acta 373, 137847 (2021)
P. Taddesse, H. Gebrekiros, G. Semu, M. Duressa, Y.C. Chemeda, N. Murali, K. Vijaya Babu, Investigation of structural, vibrational spectroscopic and properties study of LiMn2O4 and LiMn1.9Cu0.05Fe0.05O4 cathode materials. Res. Mater. 12, 100224 (2021)
M.C. Biesinger, B.P. Payne, A.P. Grosvenor, L.W.M. Lau, A.R. Gerson, R.S.C.C. Smart, Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni. Appl. Surf. Sci. 257, 2717 (2011). https://doi.org/10.1016/j.apsusc.2010.10.051
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This work was partially supported by Russian Presidential Scholarship [scholarship no. SP-6070.2021.1] and partially in accordance with the budget plan of The Institute of High Temperature Electrochemistry, Ural Branch of the Russian Academy of Sciences on the topic 122020100210-9 and performed in the Institute of High-Temperature Electrochemistry of the Ural Branch of the RAS using the equipment of the Shared Access Center Composition of Compounds and the Ural Center for Shared Used “Modern Nanotechnologies” of Ural Federal University (Reg. 2968).
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VAD Investigation: Synthesis of carbon composite and Mn7+ interaction, Software, LAY Supervision, Conceptualization, Methodology, Writing, VIP Formal analysis, Resources, X-Ray spectroscopy. EGV Investigation: Raman spectroscopy.
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Dorogova, V.A., Yolshina, L.A., Pryakhina, V.I. et al. Reduction of MnO4− Ions and Selective Deposition of Sodium-Manganese Spinel Nanocrystals on the Surface of Hierarchically Structured Carbon Films in Aqueous Solutions. J Inorg Organomet Polym (2024). https://doi.org/10.1007/s10904-024-03017-3
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DOI: https://doi.org/10.1007/s10904-024-03017-3