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Solubility Study for the Components of Aqueous System Containing Ammonium Chloroethylphosphonates, Ammonium Dihydrogen Phosphate, Ammonium Sulfate, and Sodium Tricarbamidochlorate with the Aim to Develop Multipurpose Defoliant

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Abstract

Solubility diagram for complex aqueous system containing ammonium chloroethylphosphonates, ammonium phosphate, ammonium sulfate, and sodium tricarbamide chlorate has been studied by visual polythermal method in the temperature range from –21 to +52°C. Polythermal phase diagram with demarcated fields for ice and components crystallization has been plotted. Formation of new compound, ammonium chloroethylphosphonate monochlorate NH4ClO3∙ClCH2CH2HPO3NH4, has been established; its composition was confirmed by chemical and physicochemical analysis. Viscosity, density (at 25°C), and crystallization temperature for a number of mixtures in [65%NaClO3∙3CO(NH2)2 + 5%(NH4)2SO4 + 30%H2O]–[21%ClCH2CH2PO(OH)2∙NH3 + 11%ClCH2CH2PO(OH)2∙2NH3 + 12%NH4H2PO4 + 56%H2O] system have been studied.

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Funding

This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained.

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Authors and Affiliations

  1. Institute of General and Inorganic Chemistry, Academy of Sciences of the Republic of Uzbekistan, 100170, Tashkent, Uzbekistan

    Sh. Sh. Yakubov, D. O. Obidjonov, J. Sh. Shukurov, B. Kh. Kucharov & B. S. Zakirov

  2. Tashkent Institute of Chemical Technology, 100170, Tashkent, Uzbekistan

    M. Sh. Adilova

Authors
  1. Sh. Sh. Yakubov
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  2. D. O. Obidjonov
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  3. M. Sh. Adilova
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  4. J. Sh. Shukurov
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  5. B. Kh. Kucharov
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  6. B. S. Zakirov
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Correspondence to D. O. Obidjonov.

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Translated by I. Kudryavtsev

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Yakubov, S.S., Obidjonov, D.O., Adilova, M.S. et al. Solubility Study for the Components of Aqueous System Containing Ammonium Chloroethylphosphonates, Ammonium Dihydrogen Phosphate, Ammonium Sulfate, and Sodium Tricarbamidochlorate with the Aim to Develop Multipurpose Defoliant. Russ. J. Inorg. Chem. (2024). https://doi.org/10.1134/S003602362360257X

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