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Phase Tree, Analysis of Crystallizing Phases, and Description of Chemical Interaction in the Ca,Ba||F,Cl Three-Component Reciprocal System

  • PHYSICOCHEMICAL ANALYSIS OF INORGANIC SYSTEMS
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Abstract—The paper analyzes the phases crystallizing in the Ca,Ba||F,Cl, ternary reciprocal system and describes ion-exchange and complexation reactions therein. The system is partitioned into simplexes using graph theory. A phase tree of the system has been designed, on the basis of which the number and compositions of phases crystallizing in stable elements have been predicted. A 3D model of the phase assemblage of the Ca,Ba||F,Cl system has been designed in the KOMPAS 3D v21 software. The presence of a quasi-binary eutectic and the stability of the crystallizing phases (CaF2 and BaCl2) on the CaF2–BaCl2 stable diagonal were confirmed by thermogravimetry (TG) and X-ray powder diffraction (XRD).

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Funding

The work was supported by the Ministry of Science and Higher Education of the Russian Federation (theme No. FSSE-2023-0003) as part of the Government assignment to Samara State Technical University.

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Authors and Affiliations

  1. Samara State Technical University, 443100, Samara, Russia

    T. D. Slavnov, E. M. Egorova, I. K. Garkushin, A. V. Burchakov & M. A. Demina

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  1. T. D. Slavnov
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  2. E. M. Egorova
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  3. I. K. Garkushin
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  4. A. V. Burchakov
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  5. M. A. Demina
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Correspondence to E. M. Egorova.

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Translated by O. Fedorova

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Slavnov, T.D., Egorova, E.M., Garkushin, I.K. et al. Phase Tree, Analysis of Crystallizing Phases, and Description of Chemical Interaction in the Ca,Ba||F,Cl Three-Component Reciprocal System. Russ. J. Inorg. Chem. (2024). https://doi.org/10.1134/S0036023623602556

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  • DOI: https://doi.org/10.1134/S0036023623602556

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