Abstract
TiO2/Au had been prepared readily from tetrabutyl titanate and chloroauric acid by in situ solvothermal method. SEM, XRD, UV-vis, FTIR, etc were used for characterizing the morphology, crystal structure, and optical performance of TiO2 and TiO2/Au. The photocatalytic degradation performance on methyl orange and antibacterial properties against Escherichia coli of TiO2 and TiO2/Au were studied. The results showed that the TiO2/Au both possessed superior photocatalytic properties under simulated or nature sunlight. The photocatalytic degradation rate of TiO2/Au on methyl orange was up to 91.57% that was obviously better than TiO2 (65.13%). Moreover, TiO2 and TiO2/Au had significant antibacterial properties against Escherichia coli, and the inhibition rate was up to 99.89%. The activity of TiO2 and TiO2/Au was tested by ESR and H2-TPR for analyzing the mechanism of the improvement of the photocatalytic activity and antibacterial properties.
REFERENCES
Aslam. M., Abdullah, A.Z., Rafatullah, M., and Fawad, A., Abelmoschus esculentus (Okra) seed extract for stabilization of the biosynthesized TiO2 photocatalyst used for degradation of stable organic substance in water, Environ. Sci. Pollut. Res., 2022, vol. 29, no. 27, pp. 41053–41064. https://doi.org/10.1007/s11356-021-18066-1
Kubacka, A., Diez, M.S., Rojo, D., Bargiela, R., Ciordia, S., Zapico, I., Albar, J.P., Barbas, C., dos Santos, V.A.P.M., Fernández-García, M., and Ferrer, M., Understanding the antimicrobial mechanism of TiO2-based nanocomposite films in a pathogenic bacterium, Sci. Rep., 2014, vol. 4, no. 1, article no. 4134, pp. 1–9. https://doi.org/10.1038/srep04134
Cheng, J.-Z., Liu, L.-L., Liao, G., Shen, Z.-Q., Tan, Z.-R., Xing, Y.-Q., Li, X.-X., Yang, K., Chen, L., and Liu, S.-Y., Achieving an unprecedented hydrogen evolution rate by solvent-exfoliated CPP-based photocatalysts, J. Mater. Chem. A, 2020, vol. 8, no. 12, pp. 5890–5899.
Di, J., Xia, J., Li X, Li, X., Ji, M., Xu, H., Chen, Z., and Li, H., Constructing confined surface carbon defects in ultrathin graphitic carbon nitride for photocatalytic free radical manipulation, Carbon, 2016, vol. 107, pp. 1–10. https://doi.org/10.1016/j.carbon.2016.05.028
Fujishima, A. and Honda, K., Electrochemical photolysis of water at a semiconductor electrode, Nature, 1972, vol. 238, no. 5358, pp. 37–38. https://doi.org/10.1038/238037a0
Garcia-Garcia, S., López-Ortega, A., Zheng, Y., Nie, Y., Cho, K., Chuvilin, A., and Knez, M., Ligand-induced reduction concerted with coating by atomic layer deposition on the example of TiO2-coated magnetite nanoparticles, Chem. Sci., 2019, vol. 10, no. 7, pp. 2171–2178. https://doi.org/10.1039/C8SC04474K
GB 18466-2005: Discharge standard of water pollutants for medical organization. Beijing: China Environ. Sci. Press, 2005. https://www.chinesestandard.net/PDF/ English.aspx/GB18466-2005. Cited January 02, 2024.
Gnanaprakasam, A., Sivakumar, V.M., Sivayogavalli, P.L., and Thirumarimurugan, M., Characterization of TiO2 and ZnO nanoparticles and their applications in photocatalytic degradation of azodyes, Ecotoxicol. Environ. Saf., 2015, vol. 121, pp. 121–125. https://doi.org/10.1016/j.ecoenv.2015.04.043
Ishibashi, K., Fujishima, A., Watanabe, T., and Hashimoto, K., Quantum yields of active oxidative species formed on TiO2 photocatalyst, J. Photochem. Photobiol., A, 2000, vol. 134, nos. 1–2, pp. 139–142. https://doi.org/10.1016/S1010-6030(00)00264-1
Kütahya, C., Wang, P., Li, S., Liu, S., Li, J., Chen, Z., and Strehmel, B., Carbon dots as a promising green photocatalyst for free radical and ATRP-based radical photopolymerization with blue LEDs, Angew. Chem., Int. Ed., 2020, vol. 59, no. 8, pp. 3166–3171. https://doi.org/10.1002/anie.201912343
Li, Y., Zhang, P., Wan, D., Xue, C., Zhao, J., and Shao, G., Direct evidence of 2D/1D heterojunction enhancement on photocatalytic activity through assembling MoS2 nanosheets onto super-long TiO2 nanofibers, Appl. Surf. Sci., 2020, vol. 504, article no. 144361. https://doi.org/10.1016/j.apsusc.2019.144361
Nam, Y., Lim, J.H., Ko, K.C., and Lee, J.Y., Photocatalytic activity of TiO2 nanoparticles: A theoretical aspect, J. Mater. Chem. A, 2019, vol. 7, no. 23, pp. 13833–13859. https://doi.org/10.1039/C9TA03385H
Patra, K.K. and Gopinath C.S., Bimetallic and plasmonic Ag–Au on TiO2 for solar water splitting: An active nanocomposite for entire visible-light-region absorption, ChemCatChem, 2016, vol. 8, no. 20, pp. 3294–3311. https://doi.org/10.1002/cctc.201600937
Pham, T.-D., Lee, B.-K., and Lee, C.-H., The advanced removal of benzene from aerosols by photocatalytic oxidation and adsorption of Cu-TiO2/PU under visible light irradiation, Appl. Catal., B, 2016, vol. 182, pp. 172–183. https://doi.org/10.1016/j.apcatb.2015.09.023
Sopha, H., Hromadko, L., Motola, M., and Macak, J.M., Fabrication of TiO2 nanotubes on Ti spheres using bipolar electrochemistry, Electrochem. Commun., 2020, vol. 111, article no. 106669. https://doi.org/10.1016/j.elecom.2020.106669
Tao, X., Zhu, L., Wang, X., Chen, X., and Liu, X., Preparation of Zr/Y co-doped TiO2 photocatalyst and degradation performance of hydroquinone, Environ. Sci. Pollut. Res., 2022, vol. 29, no. 27, pp. 40854–40864. https://doi.org/10.1007/s11356-021-18155-1
Welch, D., Buonanno, M., Grilj, V., Shuryak, I., Crickmore, C., Bigelow, A.W., Randers-Pehrson, G., Johnson, G.W., and Brenner, D.J., Far-UVC light: A new tool to control the spread of airborne-mediated microbial diseases, Sci. Rep., 2018, vol. 8, no. 1, article no. 2752, pp. 1–7. https://doi.org/10.1038/s41598-018-21058-w
Xu, Q., Wang, Y., Chi, M., Hu, W., Zhang, N., and He, W., Porous polymer-titanium dioxide/copper composite with improved photocatalytic activity toward degradation of organic pollutants in wastewater: Fabrication and characterization as well as photocatalytic activity evaluation, Catalysts, 2020, vol. 10, no. 3, article no. 310, pp. 1–12. https://doi.org/10.3390/catal10030310
Zhang, L., Han, B., Cheng, P., and Hu, Y.H., In-situ FTIR-DRS investigation on shallow trap state of Cu-doped TiO2 photocatalyst, Catal. Today, 2020, vol. 341, pp. 21–25. https://doi.org/10.1016/j.cattod.2018.06.049
ACKNOWLEDGMENTS
The authors acknowledge Huanghuai University.
Funding
This research was financially supported by the project of youth backbone teachers of Henan province (Grant no. 2017GGJS172), Henan provincial natural science foundation of China (Grant nos. 182102311053, 192102310492 and 222102110180), Key scientific research projects of colleges and universities in Henan province (Grant no. 21B150012), and the key science and technology innovation demonstration projects of Henan province (Grant nos. 191110110600 and 17702).
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Xu, Q., Liu, Z. Studies on Photocatalytic Degradation for Organic Pollutants by TiO2/Au Composite and its Antibacterial Properties. Theor Found Chem Eng 57, 1610–1617 (2023). https://doi.org/10.1134/S0040579523330114
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DOI: https://doi.org/10.1134/S0040579523330114