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The Study of Thermodynamic Properties of Diethylene Glycol Monobuthyl Ether with 2-Alkanols (C3–C6) with Use of PC-SAFT Modeling at Different Temperatures

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Abstract

This study investigated the density (ρ), speed of sound (u), and refractive index (\({n}_{{\text{D}}}\)) of binary mixtures of diethylene glycol monobuthyl ether (DEGBE) and 2-alkanols (C3–C6) at various compositions and temperatures (T = 298.15, 308.15, 318.15 K) under normal pressure. The experimental data were used to compute derived properties such as excess molar volume (\({V}_{{\text{m}}}^{{\text{E}}}\)), excess partial molar volume (\({\overline{V} }_{{\text{m}},{\text{i}}}^{{\text{E}}}), \mathrm{deviations in}\) isentropic compressibility (Δ \({K}_{{\text{s}}})\), and in refractive index (\(\Delta {n}_{D}\)). These derived properties were fitted with the Redlich–Kister polynomial equation. A digital vibrating-tube densitometer (Anton Paar DSA 5000) was used to measure the density and speed of sound of pure substances and mixtures at different temperatures. The results revealed the intermolecular interactions and structure factors of the binary mixtures. Moreover, the Perturbed Chain Statistical Association Fluid Theory (PC-SAFT) model was applied to predict the density data of binary mixtures and compare them with the experimental data.

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Acknowledgements

The authors would like to thank Bu – Ali University for providing financial support for conducting this study.

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  1. Department of Physical Chemistry, Faculty of Chemistry and Petroleum Science, Bu-Ali Sina University, Hamedan, Iran

    Fatane P. Chegini & Hossein Iloukhani

  2. Department of Research and Development, Reference Analytical Chemistry Lab, Hamedan, Iran

    Khatereh Khanlarzadeh

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Hossein Iloukhani and Khatereh Khanlarzadeh wrote the main manuscript text. Fattane Chegini did the experiments and prepared figures and tables. figures 1-3. All authors reviewed the manuscript."

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Correspondence to Hossein Iloukhani.

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Chegini, F.P., Iloukhani, H. & Khanlarzadeh, K. The Study of Thermodynamic Properties of Diethylene Glycol Monobuthyl Ether with 2-Alkanols (C3–C6) with Use of PC-SAFT Modeling at Different Temperatures. Int J Thermophys 45, 58 (2024). https://doi.org/10.1007/s10765-024-03353-z

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