Abstract
The results of a study of anodes obtained by carbonization of silicon monoxide by means of a reaction with solid-phase fluorocarbon CF0.8 are presented. Charge/discharge voltage profiles were studied at different currents depending on the composition and temperature of the synthesis of composites. The irreversible losses of the 1st cycle and the contribution to them of intrinsic losses due to the formation of lithium oxide and its silicates and losses associated with the formation of SEI are analyzed. A difference has been established in the behavior of anodes made of SiO carbonized by annealing with CF0.8 at T = 800°C (SiO/C composite) and silicon monoxide annealed with CF0.8 at T > 1000°C at which disproportionate occurs simultaneously with the carbonization of SiO (d-SiO/C composite). The difference consisting in a higher discharge capacity, a higher Coulomb efficiency, and better rate capability of d-SiO/C is explained by a change in the composition of the SiOx matrix that occurs during the disproportionation process. The effect of the formation of d-SiO/C anodes by preliminary lithiation with a low current, after which the electrodes can be charged and discharged with much higher currents, has been discovered. The effect is explained by the amorphization of silicon crystallites and the increasing diffusion coefficient of lithium.
REFERENCES
M. N. Obrovac, V. L. Chewier. Chem. Rev., 114, 11444 (2014). https://doi.org/10.1021/cr500207g
Zh. Liu, Q. Yu, Y. Zhao, R. He, M. Xu, S. Feng, S. Li, L. Zhou, L. Mai. Chem. Soc. Rev., 48, 285 (2019). https://doi.org/10.1039/c8cs00441b
T. Chen, J. Wu, Q. Zhang, X. Su. J. Power Sources, 363, 126 (2017). https://doi.org/10.1016/j.jpowsour.2017.07.073
M. Jiao, Y. Wang, C. Ye, C. Wang, W. Zhang, C. Liang. J. Alloy. Compd., 842, 155774 (2020). https://doi.org/10.1016/j.jallcom.2020.155774
J.-H. Kim, C.-M. Park, H. Kim, Y.-J. Kim, H.-J. Sohn. J. Electroanalyt. Chem., 661, 245 (2011). https://doi.org/10.1016/j.jelechem.2011.08.010
S. C. Jung, H.-J. Kim, J.-H. Kim, Y.-K. Han. J. Phys. Chem. C., 120 (2), 886 (2016). https://doi.org/10.1021/acs.jpcc.5b10589
Y. Nagao, H. Sakaguchi, H. Honda, T. Fukunaga, T. Esaka. J. Electrochem. Soc., 151 (10), A1572 (2004). https://doi.org/10.1149/1.1787173
M. Miyachi, H. Yamamoto, H. Kawai, T. Ohta, M. Shirakata. J. Electrochem. Soc., 152 (10), A2089 (2005). https://doi.org/10.1149/1.2013210
K. Yasuda, Y. Kashitani, S. Kizaki, K. Takeshita, T. Fujita, S. Shimosaki. J. Power Sources, 329, 462 (2016). https://doi.org/10.1016/j.jpowsour.2016.08.110
L. Y. Beaulieu, K. W. Eberman, R. L. Turner, L. J. Krause, J. R. Dahna. Electrochem. Solid-State Lett., 4 (9), A137 (2001). https://doi.org/10.1149/1.1388178
T. Kim, S. Park, S. M. Oh. J. Electrochem. Soc., 154, A1112 (2007). https://doi.org/10.1149/1.2790282
Y. Yamada Y. Iriyama, T. Abe, Z. Ogumi. J. Electrochem. Soc., 157 (1), A26 (2010). https://doi.org/10.1149/1.3247598
J. Cui, Y. Cui, S. Li, H. Sun, Z. Wen, J. Sun. ACS Appl. Mater. Interfaces, 8 (44), 30239 (2016). https://doi.org/10.1021/acsami.6b10260
Q. Yuan, F. Zhao, Y. Zhao, Z. Liang, D. Yan. Electrochimica Acta, 115, 16 (2014). https://doi.org/10.1016/j.electacta.2013.10.106
M. Yamada, A. Ueda, K. Matsumoto, T. Ohzuku. J. Electrochem. Soc., 158 (4), A417 (2011). https://doi.org/10.1149/1.3551539
T. Xu, Q. Wang, J. Zhang, X. Xie, B. Xia. ACS Appl. Mater. Interfac., 11, 19959 (2019). https://doi.org/10.1021/acsami.9b03070
L. Guo, H. He, Y. Ren, C. Wang, M. Li. Chem Eng. J., 335, 32 (2017). https://doi.org/10.1016/j.cej.2017.10.145
L. Hu, W. Xia, R. Tang, R. Hu, L. Ouyang, T. Sun. H. Wang. Frontiers in Chem., 8, 388 (2020). https://doi.org/10.3389/fchem.2020.00388
E. V. Astrova, V. P. Ulin, A. V. Parfeneva, V. B. Voronkov. Tech. Phys. Lett., 45, 664 (2019). https://doi.org/10.1134/S1063785019070022
E. V. Astrova, V. P. Ulin, A. V. Parfeneva, A. M. Rumyantsev, V. B. Voronkov, A. V. Nashchekin, V. N. Nevedomskiy, Y. M. Koshtyal, M. V. Tomkovich. J. Alloy. Compd., 826, 154242 (2020). https://doi.org/10.1016/j.jallcom.2020.154242
E. V. Astrova, V. P. Ulin, A. V. Parfeneva, A. V. Nashchekin, V. N. Nevedomskiy, M. V. Baydakova. Semiconductors, 54 (8), 900 (2020). https://doi.org/10.1134/S1063782620080059
D. A. Lozhkina, E. V. Astrova, A. I. Likhachev, A. V. Parfeneva, A. M. Ryumyantsev, A. N. Smirnov, V. P. Ulin. Tech. Phys., 91 (9), 1381 (2021). https://doi.org/10.21883/JTF.2021.09.51218.83-21
D. A. Lozhkina, E. V. Astrova, R. V. Sokolov, D. A. Kirilenko, A. A. Levin, A. V. Parfeneva, V. P. Ulin. Semiconductors, 55 (4), 373 (2021). https://doi.org/10.1134/S1063782621040096
A. S. Fialkov. Uglerod, mezhsloevye soedineniya i kompozity na ego osnove (Aspekt Press, M., 1997), p. 377–404 (in Russian).
M. Winter, P. Novak, A. Monnier. J. Electrochem. Soc., 145, 428 (1998). https://doi.org/10.1149/1.1838281
T. Tan, P.-K. Lee, D. Y. W. Yu. J. Electrochem. Soc., 166 (3), A5210 (2019). https://doi.org/10.1149/2.0321903jes
J. Yang, Y. Takeda, N. Imanishi, C. Capiglia, J. Y. Xie, O. Yamamoto. Solid State Ionics, 152–153, 125 (2002). https://doi.org/10.1016/S0167-2738(02)00362-4
Ch.-M. Park, W. Choi, Y. Hwa, J.-H. Kim, G. Jeong, H.-J. Sohn. J. Mater. Chem., 20, 4854 (2010). https://doi.org/10.1039/B923926J
K. Kitada, O. Pecher, P. C. M. M. Magusin, M. F. Groh, R. S. Weatherup, C. P. Grey. J. Am. Chem. Soc., 141, 7014 (2019). https://doi.org/10.1021/jacs.9b01589
Z. B. Stojnov, B. M. Grafov, B. S. Savova-Stojnova, V. V. Elkin. Elektrokhimicheskij impedans (Nauka, M., 1991), p. 336 (in Russian).
A. V. Churikov, K. I. Pridatko, A. V. Ivanishchev, I. A. Ivanishcheva, I. M. Gamayunova, K. V. Zapsis, V. O. Sycheva. Elektrokhimiya, 44 (5), 594 (2008) (in Russian). https://doi.org/10.1134/S1023193508050078
M. Xia, L. Yi-ran, X. Xiong, W. Hu, Y. Tang, N. Zhou, Z. Zhou, H. Zhang. J. Alloy. Compnd., 800, 116e124 (2019). https://doi.org/10.1016/j.jallcom.2019.05.365
F. Ozanam, M. Rosso. Mat. Sci. Eng., 213, 2 (2016). https://doi.org/10.1016/j.mseb.2016.04.016
H. Yang, F. Fan, W. Liang, X. Guo, T. Zhu, S. Zhang. J. Mech. Phys. Sol., 70, 349 (2014). https://doi.org/10.1016/j.jmps.2014.06.004
S. Yoshida, T. Okubo, Y. Masuo, Y. Oba, D. Shibata, M. Haruta, T. Doi, M. Inaba. Electrochemistry, 85 (7), 403 (2017). https://doi.org/10.5796/electrochemistry.85.403
M. Pharr, K. Zhao, X. Wang, Z. Suo, J.J. Vlassak. Nano Lett., 12 (9), 5039 (2012). https://doi.org/10.1021/nl302841y
J. Park, S. S. Park, Y. S. Won. Electrochim. Acta, 107, 467 (2013). https://doi.org/10.1016/j.electacta.2013.06.059
K. Pan, F. Zou, M. Canova, Y. Zhu, J.-H. Kim. J. Power Sources, 413, 20 (2019). https://doi.org/10.1016/j.jpowsour.2018.12.010
ACKNOWLEDGMENTS
Authors would like to thank M.V. Tomkovich and Yu.A. Kukushkina for the performed BET studies and M.P. Karusheva for help with EIS measurements studies.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflict of interest.
Additional information
Publisher’s Note.
Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Lozhkina, D.A., Astrova, E.V. & Rumyantsev, A.M. Dependence of the Electrochemical Parameters of Composite SiO/C Anodes for Lithium-Ion Batteries on the Composition and Synthesis Temperature. Tech. Phys. 68, 471–484 (2023). https://doi.org/10.1134/S1063784223900516
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063784223900516