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Quantitative applications of the electronegativity scale

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Abstract

This paper briefly discusses electronegativity and uses of the electronegativity scale. It demonstrates that values of electronegativity can be used quantitatively in simple equations. Formulas containing derived values of elemental electronegativities are shown to calculate dipole moments, bond lengths, and bond energies reliably. Comparison between calculated and experimental values shows very good agreement in the vast majority of cases.

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No confidential data were used in this work. All data are available in the CRC Handbook of Chemistry and Physics or listed in the references.

References

  1. Pauling L (1939) Nature of the Chemical Bond, 1st edn. Cornell University Press, New York

    Google Scholar 

  2. Henderson W (2000) Main Group Chemistry. Royal Society Chemistry, London

    Book  Google Scholar 

  3. Lang PF, Smith BC (2015) Phys Chem Chem Phys 17:3355

    Article  CAS  PubMed  Google Scholar 

  4. Jones CJ (2001) d- and f-Block chemistry. Royal Society Chemistry, London

    Book  Google Scholar 

  5. Shriver DF, Atkins PW, Langford CH (1990) Inorganic Chemistry. Oxford University Press, Oxford

    Google Scholar 

  6. Cotton FC, Wilkinson G (1972) Advanced Inorganic Chemistry, 3rd edn. Interscience, New York

    Google Scholar 

  7. Rumble J (ed) (2023–2024) CRC Handbook of Chemistry and Physics, 104th edn. CRC Press, Boca Raton

  8. Donnay JD, Ondik HM (eds) (1973) Crystal Data Determinative Tables, 3rd edn, vols 1 and 2. United States Department of Commerce, National Bureau of Standards and Joint Committee on Powder Diffraction Standards, Washington DC

  9. Ondik HM, Mighell AD (eds) (1978) Crystal Data Determinative Tables, 3rd edn, vols 3 and 4. United States Department of Commerce, National Bureau of Standards and Joint Committee on Powder Diffraction Standards, Washington DC

  10. Mingos DMP (1995) Essentials of Inorganic Chemistry 1. Oxford University Press, Oxford

    Book  Google Scholar 

  11. Norman NC (1994) Periodicity and the p Block elements. Oxford University Press, Oxford

    Google Scholar 

  12. Lang PF, Smith BC (2014) Dalton Trans 43:8016

    Article  CAS  PubMed  Google Scholar 

  13. Lang PF, Smith BC (2003) J Chem Educ 80:938

    Article  CAS  Google Scholar 

  14. Lang PF, Smith BC (2010) J Chem Educ 87:875

    Article  CAS  Google Scholar 

  15. Schomaker V, Stevenson DP (1941) J Am Chem Soc 63:37

    Article  CAS  Google Scholar 

  16. Ives DJG (1971) Chemical Thermodynamics. Macdonald, London

    Google Scholar 

  17. Lang PF (2023). Found Chem. https://doi.org/10.1007/s10698-023-09486-7

    Article  Google Scholar 

  18. Lang PF, Smith BC (2010) Dalton Trans 39:7786

    Article  CAS  PubMed  Google Scholar 

  19. Herzberg G (1950) Molecular Spectra and Molecular Structure I, Spectra of Diatomic Molecules. Van Nostrand Reinhold, New York, USA

  20. Huber KP, Herzberg G (1979) Molecular Spectra and Molecular Structure IV, Constants of Diatomic Molecules. Van Nostrand Reinhold, New York, USA

  21. Harmony MD, Laurie VW, Kuczkowski RL, Schwendeman RH, Ramsay DA, Lovas FJ, Lafferty WJ, Maki AG (1979) J Phys Chem Ref Data 8:619

    Article  CAS  Google Scholar 

  22. Donohue J (1974) The Structures of the Elements. Wiley, New York, USA

    Google Scholar 

  23. Jones M Jr (1997) Organic Chemistry. WW Norton, New York

    Google Scholar 

Download references

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Correspondence to Peter F. Lang.

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Lang, P.F. Quantitative applications of the electronegativity scale. Monatsh Chem 155, 507–513 (2024). https://doi.org/10.1007/s00706-024-03191-7

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  • DOI: https://doi.org/10.1007/s00706-024-03191-7

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