Abstract
One-step co-precipitation method was used to prepare the flower-like BiOCl/BiOBr composite materials (BOBCs) with heterojunction structures, in which various amounts of BiOBr were used to adjust the band gap of BiOCl and thereby improve its photocatalytic activity. Based on photocatalytic performance experiments, BOBC2, in which the molar ratio of BiOCl to BiOBr is 1:0.75, exhibited the highest photodegradation efficiency (90.5%) to remove ofloxacin after 100 min illumination. The cyclic utilization performance of BOBC2 under the same conditions was tested by a cycle experiment. It was found that its photocatalytic activity remained at a high level after three cycles. The composition and microstructure of the material were analyzed by characterization techniques including XRD, FTIR, XPS, and SEM. The optical properties and the degradation process of the material were studied by DRS, PL, photocurrent, and active species trapping methods. The reasonable mechanism for photocatalytic degradation of ofloxacin was proposed.
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References
C.M. Jung, T.M. Heinze, R. Strakosha, C.A. Elkins, J.B. Sutherland, Acetylation of fluoroquinolone antimicrobial agents by an Escherichia coli strain isolated from a municipal wastewater treatment plant. J. Appl. Microbiol. 106(2), 564–571 (2009)
D. Huang, J. Li, G. Zeng, W. Xue, S. Chen, Z. Li, R. Deng, Y. Yang, M. Cheng, Facile construction of hierarchical flower-like Z-scheme AgBr/Bi2WO6 photocatalysts for effective removal of tetracycline: degradation pathways and mechanism. Chem. Eng. J. 375, 121991 (2019)
R. Jiang, G. Lu, Z. Yan, D. Wu, R. Zhou, X. Bao, Insights into a CQD-SnNb2O6/BiOCl Z-scheme system for the degradation of benzocaine: influence factors, intermediate toxicity and photocatalytic mechanism. Chem. Eng. J. 374, 79–90 (2019)
D. Díez-del-Molino, E. García-Berthou, R.M. Araguas, C. Alcaraz, O. Vidal, N. Sanz, J.L. García-Marín, Insights into a CQD-SnNb2O6/BiOCl Z-scheme system for the degradation of benzocaine: influence factors, intermediate toxicity and photocatalytic mechanism. Sci. Total Environ. 637, 1372–1382 (2018)
Y. Qi, J. Li, Y. Zhang, Q. Cao, Y. Si, Z. Wu, M. Akram, X. Xu, Novel lignin-based single atom catalysts as peroxymonosulfate activator for pollutants degradation: role of single cobalt and electron transfer pathway. Appl. Catal. B 286, 119910 (2021)
J. Xue, S. Ma, Y. Zhou, Z. Zhang, M. He, Facile photochemical synthesis of Au/Pt/g-C3N4 with plasmon-enhanced photocatalytic activity for antibiotic degradation. ACS Appl. Mater. Interfaces 7(18), 9630–9637 (2015)
T. Paul, M.C. Dodd, T.J. Strathmann, Photolytic and photocatalytic decomposition of aqueous ciprofloxacin: transformation products and residual antibacterial activity. Water Res. 44(10), 3121–3132 (2010)
S. Castiglioni, R. Bagnati, R. Fanelli, F. Pomati, D. Calamari, E. Zuccato, Removal of pharmaceuticals in sewage treatment plants in Italy. Environ. Sci. Technol. 40(1), 357–363 (2006)
Z. Zhu, P. Huo, Z. Lu, Y. Yan, Z. Liu, W. Shi, C. Li, H. Dong, Fabrication of magnetically recoverable photocatalysts using g-C3N4 for effective separation of charge carriers through like-Z-scheme mechanism with Fe3O4 mediator. Chem. Eng. J. 331, 615–625 (2018)
W. Zhang, F. Bi, Y. Yu, H. He, Phosphoric acid treating of ZSM-5 zeolite for the enhanced photocatalytic activity of TiO2/HZSM-5. J. Mol. Catal. A: Chem. 372, 6–12 (2013)
Z. Li, M. Qi, C. Tu, W. Wang, J. Chen, A.J. Wang, Highly efficient removal of chlorotetracycline from aqueous solution using graphene oxide/TiO2 composite: properties and mechanism. Appl. Surf. Sci. 425, 765–775 (2017)
Y. Wu, F. Xu, D. Guo, Z. Gao, D. Wu, K. Jiang, Synthesis of ZnO/CdSe hierarchical heterostructure with improved visible photocatalytic efficiency. Appl. Surf. Sci. 274, 39–44 (2013)
Y. Guo, J. Zhang, D. Zhou, S. Dong, Fabrication of Ag/CDots/BiOBr ternary photocatalyst with enhanced visible-light driven photocatalytic activity for 4-chlorophenol degradation. J. Mol. Liq. 262, 194–203 (2018)
X.J. Guo, M. Zhen, H. Liu, L. Liu, BiOBr–BiOI microsphere assembled with atom-thick ultrathin nanosheets and its high photocatalytic activity. RSC Adv. 5(31), 24777–24782 (2015)
R.B. Arthur, J.C. Ahern, H.H. Patterson, Application of BiOX photocatalysts in remediation of persistent organic pollutants. Catalysts 8(12), 604 (2018)
S. Zhao, Y. Zhang, Y. Zhou, K. Qiu, C. Zhang, J. Fang, X. Sheng, Reactable polyelectrolyte-assisted preparation of flower-like Ag/AgCl/BiOCl composite with enhanced photocatalytic activity. J. Photochem. Photobiol. A 350, 94–102 (2018)
J. Cai, Y. Xie, C. Ma, X. Wang, L. Wang, P. Ning, Y. Ma, rGO-modified BiOX (X = Cl, I, Br) for enhanced photocatalytic eradication of gaseous mercury. Appl. Surf. Sci. 594, 153502 (2022)
J. Li, Y. Liu, Y. Zhou, S. Liu, Y. Liang, T. Luo, G. Dai, Enhanced visible-light photocatalytic activity of Bi2O2CO3 nanoplates by Fe-doping in the degradation of rhodamine B. Mater. Res. Bull. 107, 438–445 (2018)
X. Li, J. Xiong, X. Gao, J. Ma, Z. Chen, B. Kang, J. Liu, H. Li, Z. Feng, J. Huang, Novel BP/BiOBr S-scheme nano-heterojunction for enhanced visible-light photocatalytic tetracycline removal and oxygen evolution activity. J. Hazard. Mater. 387, 121690 (2020)
J. Mei, Y. Tao, C. Gao, Q. Zhu, H. Zhang, J. Yu, Z. Fang, H. Xu, Y. Wang, G. Li, Photo-induced dye-sensitized BiPO4/BiOCl system for stably treating persistent organic pollutants. Appl. Catal. B 285, 119841 (2021)
J. Zhang, J. Xia, S. Yin, H. Li, H. Xu, M. He, L. Huang, Q. Zhang, Improvement of visible-light photocatalytic activity over flower-like BiOCl/BiOBr microspheres synthesized by reactable ionic liquids. Colloids Surf. A 420, 89–95 (2013)
S.M. Aghdam, M. Haghighi, S. Allahyari, L. Yosefi, Precipitation dispersion of various ratios of BiOI/BiOCl nanocomposite over g-C3N4 for promoted visible-light nanophotocatalyst used in removal of acid orange 7 from water. J. Photochem. Photobiol. A 338, 201–212 (2017)
Z. Liu, H. Ran, B. Wu, P. Feng, Y. Zhu, Synthesis and characterization of BiOI/BiOBr heterostructure films with enhanced visible-light photocatalytic activity. Colloids Surf. A 452, 109–114 (2014)
S. Zhang, J. Yang, Microwave-assisted synthesis of BiOCl/BiOBr composites with improved visible-light photocatalytic activity. Ind. Eng. Chem. Res. 54(41), 9913–9919 (2015)
X. Xiao, R. Hao, M. Liang, X. Zuo, J. Nan, L. Li, W. Zhang, One-pot solvothermal synthesis of three-dimensional (3D) BiOI/BiOCl composites with enhanced visible-light photocatalytic activities for the degradation of bisphenol-A. J. Hazard. Mater. 233, 122–130 (2012)
H. Liao, J. Zhong, J. Li, S. Huang, R. Duan, Photocatalytic properties of flower-like BiOBr/BiOCl heterojunctions in-situ constructed by a reactable ionic liquid. Inorg. Chem. Commun. 134, 109063 (2021)
G. Liu, H. Xu, D. Li, Z. Zou, Q. Li, D. Xia, BiOCl/BiOBr heterojunction with rich oxygen vacancies induced by ultraviolet and its enhanced photocatalytic performance. Eur. J. Inorg. Chem. 2019(46), 4887–4893 (2019)
X. Jia, J. Cao, H. Lin, M. Zhang, X. Guo, S. Chen, Transforming type-I to type-II heterostructure photocatalyst via energy band engineering: a case study of I-BiOCl/I-BiOBr. Appl. Catal. B 204, 505–514 (2017)
H.T. Wang, M.S. Shi, H.F. Yang, N. Chang, H. Zhang, Y.P. Liu, M.C. Lu, D. An, D.Q. Chu, Transforming type-I to type-II heterostructure photocatalyst via energy band engineering: a case study of I-BiOCl/I-BiOBr. Mater. Lett. 222, 164–167 (2018)
L. Ye, J. Liu, Z. Jiang, T. Peng, L. Zan, Transforming type-I to type-II heterostructure photocatalyst via energy band engineering: a case study of I-BiOCl/I-BiOBr. Appl. Catal. B 142, 1–7 (2013)
W. Li, Y. Zou, X. Geng, F. Xiao, G. An, D. Wang, Constructing highly catalytic oxidation over BiOBr-based hierarchical microspheres: importance of redox potential of doped cations. Mol. Catal. 438, 19–29 (2017)
X. Gao, W. Peng, G. Tang, Q. Guo, Y. Luo, Highly efficient and visible-light-driven BiOCl for photocatalytic degradation of carbamazepine. J. Alloy. Compd. 757, 455–465 (2018)
J. Liu, Y. Luan, C. An, J. Zhang, D. Wang, Y. Li, Silver iodide nanospheres wrapped in reduced graphene oxide for enhanced photocatalysis. ChemCatChem 7(18), 2918–2923 (2015)
F. Qiu, W. Li, F. Wang, H. Li, X. Liu, C. Ren, Preparation of novel pn heterojunction Bi2O2CO3/BiOBr photocatalysts with enhanced visible-light photocatalytic activity. Colloids Surf. A 517, 25–32 (2017)
J. Di, J. Xia, M. Ji, B. Wang, S. Yin, Q. Zhang, Z. Chen, H. Li, Carbon quantum dots modified BiOCl ultrathin nanosheets with enhanced molecular oxygen activation ability for broad spectrum photocatalytic properties and mechanism insight. ACS Appl. Mater. Interfaces. 7(36), 20111–20123 (2015)
H. Liu, Y. Su, Z. Chen, Z. Jin, Y. Wang, Graphene sheets grafted three-dimensional BiOBr0.2I0.8 microspheres with excellent photocatalytic activity under visible-light. J. Hazard. Mater. 266, 75–83 (2014)
Q. Hu, M. Ji, J. Di, B. Wang, J. Xia, Y. Zhao, H. Li, Ionic liquid-induced double regulation of carbon quantum dots modified bismuth oxychloride/bismuth oxybromide nanosheets with enhanced visible-light photocatalytic activity. J. Colloid Interface Sci. 519, 263–272 (2018)
Q. Wang, J. Huang, H. Sun, K.Q. Zhang, Y. Lai, Uniform carbon dots@ TiO2 nanotube arrays with full spectrum wavelength light activation for efficient dye degradation and overall water splitting. Nanoscale 9(41), 16046–16058 (2018)
T.B. Li, G. Chen, C. Zhou, Z.Y. Shen, R.C. Jin, J.X. Sun, New photocatalyst BiOCl/BiOI composites with highly enhanced visible-light photocatalytic performances. Dalton Trans. 40(25), 6751–6758 (2011)
X. He, F. Deng, T. Shen, L. Yang, D. Chen, J. Luo, X. Luo, X. Min, F. Wang, Exceptional adsorption of arsenic by zirconium metal-organic frameworks: engineering exploration and mechanism insight. J. Colloid Interface Sci. 539, 223–234 (2019)
J. Xia, S. Yin, H. Li, H. Xu, L. Xu, Y. Xu, Improved visible-light photocatalytic activity of sphere-like BiOBr hollow and porous structures synthesized via a reactable ionic liquid. Dalton Trans. 40(19), 5249–5258 (2011)
L. Ye, J. Liu, C. Gong, L. Tian, T. Peng, L. Zan, Two different roles of metallic Ag on Ag/AgX/BiOX (X = Cl, Br) visible-light photocatalysts: surface plasmon resonance and Z-scheme bridge. ACS Catal. 2(8), 1677–1683 (2012)
J. Wang, L. Tang, G. Zeng, Y. Deng, H. Dong, Y. Liu, L. Wang, B. Peng, C. Zhang, F. Chen, F. Chen, 0D/2D interface engineering of carbon quantum dots modified Bi2WO6 ultrathin nanosheets with enhanced photoactivity for full spectrum light utilization and mechanism insight. Appl. Catal. B 222, 115–123 (2018)
Y.J. Sun, J.Y. He, D. Zhang, X.J. Wang, J. Zhao, R.H. Liu, F.T. Li, Simultaneous construction of dual-site phosphorus modified g-C3N4 and its synergistic mechanism for enhanced visible-light photocatalytic hydrogen evolution. Appl. Surf. Sci. 517, 146192 (2020)
Q. Xiang, J. Yu, M. Jaroniec, Preparation and enhanced visible-light photocatalytic H2-production activity of graphene/C3N4 composites. J. Phys. Chem. C 115(15), 7355–7363 (2011)
Z. Jia, T. Li, Z. Zheng, J. Zhang, J. Liu, R. Li, Y. Wang, X. Zhang, Y. Wang, C. Fan, Preparation and enhanced visible-light photocatalytic H2-production activity of graphene/C3N4 composites. Chem. Eng. J. 380, 122422 (2020)
D. Ma, J. Zhong, R. Peng, J. Li, R. Duan, Effective photoinduced charge separation and photocatalytic activity of hierarchical microsphere-like C60/BiOCl. Appl. Surf. Sci. 465, 249–258 (2019)
Y. Lv, Y. Zhu, Y. Zhu, Enhanced photocatalytic performance for the BiPO4−x nanorod induced by surface oxygen vacancy. J. Phys. Chem. C 117(36), 18520–18528 (2013)
S. Jonjana, A. Phuruangrat, S. Thongtem, O. Wiranwetchayan, T. Thongtem, Preparation and characterization of Ag3VO4/Bi2MoO6 nanocomposites with highly visible-light-induced photocatalytic properties. Mater. Lett. 180, 93–96 (2016)
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Class III Peak Discipline of Shanghai—Materials Science and Engineering (High-Energy Beam Intelligent Processing and Green Manufacturing).
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This work was funded by Class III Peak Discipline of Shanghai—Materials Science and Engineering (High-Energy Beam Intelligent Processing and Green Manufacturing).
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YZ: Writing—original draft, Investigation, Validation, Methodology, Data curation, software, Formal analysis, Writing—review & editing. WL: Conceptualization, Project administration, Writing—review & editing, Formal analysis. RG: Investigation, Conceptualization, Project administration. HL: Software, Formal analysis, Writing—original draft. YH: Investigation, Validation, Methodology.
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Zhang, Y., Lin, W., Gao, R. et al. The flower-like BiOCl/BiOBr with heterojunction prepared by co-precipitation method to enhance its photocatalytic performance. Journal of Materials Research (2024). https://doi.org/10.1557/s43578-024-01324-6
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DOI: https://doi.org/10.1557/s43578-024-01324-6