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Local Structure of Amorphous (GeTe)x(Sb2Te3) Films

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Abstract

By the method of Mössbauer spectroscopy on the isotope 119Sn, it was shown that tetravalent germanium atoms in amorphous films (GeTe)x(Sb2Te3) (where x = 0.5, 1, 2, 3) form a tetrahedral system of chemical bonds, and in their local environment there are mainly tellurium atoms. In crystalline films (GeTe)x(Sb2Te3) is divalent hexoordinated germanium at positions 4 b of the NaCl type crystal lattice. By the method of Mössbauer spectroscopy on 121Sb and 125Te atoms, it was shown that the amorphization of (GeTe)x(Sb2Te3) films does not change the local environment of antimony and tellurium atoms.

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Authors and Affiliations

  1. Herzen State Pedagogical University of Russia, St. Petersburg, Russia

    A. V. Marchenko, Yu. A. Petrushin & P. P. Seregin

  2. Ioffe Institute, St. Petersburg, Russia

    E. I. Terukov

  3. St. Petersburg State Electrotechnical University “LETI”, St. Petersburg, Russia

    E. I. Terukov

  4. Peter the Great Saint-Petersburg Polytechnic University, St. Petersburg, Russia

    F. S. Nasredinov

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  1. A. V. Marchenko
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  3. F. S. Nasredinov
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  4. Yu. A. Petrushin
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Marchenko, A.V., Terukov, E.I., Nasredinov, F.S. et al. Local Structure of Amorphous (GeTe)x(Sb2Te3) Films. Tech. Phys. 68 (Suppl 1), S88–S95 (2023). https://doi.org/10.1134/S1063784223090104

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