Abstract
Ceramic samples with compositions along the (1 – 2x)BiScO3·(2 – y)xPbTiO3∙yxPbMg1/3Nb2/3O3 (y = 1.2, 1.0, 0.9, 0.5) sections in the BiScO3–PbTiO3–PbMg1/3Nb2/3O3 (BS–PT–PMN) system have been characterized by X-ray diffraction and dielectric, piezoelectric, and thermally stimulated depolarization current measurements. The materials with 1 – x ≲ 0.5 have been shown to consist of perovskite solid solutions. With increasing BS content, the symmetry of the solid solutions rises from tetragonal to cubic. In the intermediate composition region (morphotropic region (MR)), the samples consist of a mixture of solid solutions differing in symmetry. We have located the MR boundaries and examined the effect of composition on the dielectric and piezoelectric properties of the solid solutions.
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ACKNOWLEDGMENTS
In this study, we used equipment at the Shared Research Instrumentation Center, Moscow Institute of Radio Engineering, Electronics, and Automation, Russian Technological University, supported by the Russian Federation Ministry of Science and Higher Education, agreement no 075-15-2021-689, September 1, 2021.
Funding
This work was supported by the Russian Federation Ministry of Science and Higher Education, state research target, project FSFZ-2022-0007: Foundation of New Youth Laboratories.
A.A. Nogai acknowledges the support from the Ministry of Science and Higher Education of the Republic of Kazakhstan, grant no. AP14972981.
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Sysoev, M.A., Bush, A.A., Kamentsev, K.E. et al. Preparation, Structure, and Electrophysical Properties of Ceramic Samples of (1 – 2x)BiScO3∙(2 – y)xPbTiO3∙yxPbMg1/3Nb2/3O3 Perovskite Solid Solutions. Inorg Mater 59, 1345–1355 (2023). https://doi.org/10.1134/S0020168523120087
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DOI: https://doi.org/10.1134/S0020168523120087