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New Correlation Model of Thermal Conductivity of Liquid Hydrofluorochloro Derivatives of Olefins, Hydrofluorocarbons, and Hydrochlorofluorocarbons

  • THERMOPHYSICAL PROPERTIES OF MATERIALS
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High Temperature Aims and scope

Abstract

The correlation dependence of thermal conductivity \({{\lambda }_{{\text{s}}}}\) of liquid refrigerants on the saturation line is developed as a simple function of temperature \(T\): \({{\lambda }_{{\text{s}}}}{\text{/}}{{\lambda }_{0}} = {{(1 + \tau )}^{2}} + A{{\tau }^{{ - \chi }}}\) (where \({{\lambda }_{0}}\) is the criterion unit, \(\tau = 1 - T{\text{/}}{{T}_{{\text{c}}}}\), and \({{T}_{{\text{c}}}}\) is the critical temperature). This dependence satisfies the requirements of dynamic scale theory (ST), and in particular, the passage to the limit \({{\lambda }_{{\text{s}}}}(T \to {{T}_{{\text{c}}}}) \to + \infty \). The proposed correlation dependence is tested using the example of describing the thermal conductivity of 17 liquid substances in the range of state parameters from the saturation line to the critical pressure \({{p}_{{\text{c}}}}\) and in the temperature range from the triple point temperature Ttr to \({{T}_{{\text{c}}}}\). The substances reviewed include nine fourth-generation refrigerants of hydrofluorochloro derivatives of olefins, seven hydrochlorofluorocarbons and hydrofluorocarbons, and C3H8. Using the description of \({{\lambda }_{{\text{s}}}}\) of C3H8 as an example, it is shown that the proposed correlation dependence not only qualitatively but also quantitatively accurately conveys the behavior of \({{\lambda }_{{\text{s}}}}\) in the vicinity of the critical point. Based on the statistical analysis, it is shown that the proposed correlation with significantly less uncertainty describes the data on the thermal conductivity of liquid hydrofluorochloro derivatives of olefins both on the saturation line and in the single-phase region. Based on the proposed methodology, the thermal conductivity of the cis-isomer R1225ye(Z) is calculated for the first time in the temperature range \(134.3\,\,{\text{K}} \leqslant T \leqslant 373.15\,\,{\text{K}}\).

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  1. St. Petersburg National Research University of Information Technologies, Mechanics, and Optics, St. Petersburg, Russia

    S. V. Rykov, I. V. Kudryavtseva & V. A. Rykov

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Rykov, S.V., Kudryavtseva, I.V. & Rykov, V.A. New Correlation Model of Thermal Conductivity of Liquid Hydrofluorochloro Derivatives of Olefins, Hydrofluorocarbons, and Hydrochlorofluorocarbons. High Temp 61, 775–784 (2023). https://doi.org/10.1134/S0018151X23050140

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