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Facile synthesis of rodlike ZSM-5 zeolite microspheres and catalytic performance in methanol to propylene reaction

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Abstract

Rodlike ZSM-5 zeolite microspheres (R-Z5) were synthesized via a seed induced hydrothermal method with S-1 seeds in the presence of β-cyclodextrin (CD). The synthesized ZSM-5 zeolites were characterized with XRD, SEM, N2 adsorption and desorption, NH3-TPD, the catalytic performance of R-Z5 catalysts was studied for the methanol to propylene (MTP) reaction. The effects of the ratio of CD/SiO2 on the morphologies and textural properties of the products were discussed in detail. A possible formation process of R-Z5 was proposed. The results showed that CD played a key role in the preparation of R-Z5, which could be ascribed to the amphipathy of CD for the formation of rodlike ZSM-5 crystals. Compared with the conventional seed induced method, R-Z5 zeolites possessed the larger BET surface area and mesopore volumes and the more moderate acidic sites. Moreover, the synthesized R-Z5 catalysts exhibited excellent conversion activity (64 h) and propylene selectivity (41.35%) in the primary catalytic performance of MTP reaction.

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Authors and Affiliations

  1. College of Materials Science and Engineering, Hebei University of Engineering, Handan, 056038, Hebei, P.R. China

    Hengbao Chen, Tianyang Li, Zehan Li, Bing Li & Manli Zhang

Authors
  1. Hengbao Chen
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  2. Tianyang Li
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  3. Zehan Li
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  4. Bing Li
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  5. Manli Zhang
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Contributions

HC carried out most of the experiment, data analysis and wrote the main manuscript. TL prepared the zeolites and edited the manuscript. ZL and BL assisted the centrifugation of zeolites suspension and contributed to the discussion of results, MZ supervised and conceptualized the study. All authors reviewed the manuscript.

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Correspondence to Hengbao Chen.

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Chen, H., Li, T., Li, Z. et al. Facile synthesis of rodlike ZSM-5 zeolite microspheres and catalytic performance in methanol to propylene reaction. J Porous Mater (2024). https://doi.org/10.1007/s10934-024-01590-z

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  • DOI: https://doi.org/10.1007/s10934-024-01590-z

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