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Licensed Unlicensed Requires Authentication Published online by De Gruyter March 26, 2024

Poplar wood treated with nano-silver–copper particles: fungal degradation and leaching analysis

  • Xiwei Wang , Tengfei Yi , Hongxue Luo , Yanran Qi , Fengbiao Yao , Yiliang Liu and Yongfeng Li EMAIL logo
From the journal Holzforschung

Abstract

This study investigated the inhibition effect of nanoscale silver–copper particle (20 nm) against Coriolus versicolor and Gloeophyllum trabeum. Poplar wood samples (Populus L.) were vacuum-impregnated using aqueous nano-AgCu solutions at concentrations of 0.01 %, 0.02 %, 0.03 %, 0.05 %, 0.075 %, and 0.1 %. Alkaline copper quaternary (ACQ, 0.1 %), boric acid (0.2 %) and untreated control group (CK) were employed for comparisons. Decay resistance and leachability were studied. The anti-fungi effects were compared between nano-AgCu, nano-Ag, Ag+ (silver nitrate), Cu2+ (copper nitrate), and a composite of Ag+–Cu2+. Nano-AgCu particle exhibited effective resistance to fungi after 12 weeks of exposure. The threshold retention of the nano-AgCu against C. versicolor and G. trabeum on poplar wood was 0.19 kg m−3 and 0.62 kg m−3, respectively. The silver–copper nanoparticles demonstrated excellent leach resistance, and the inhibition effect was retained after leaching. The nano-AgCu particle provided better antifungal effects than single ions or metal nanoparticles. This study illustrates the potential of using nano-AgCu particle as an efficient wood preservative compared to commercial water-soluble preservatives.


Corresponding author: Yongfeng Li, Key Laboratory of State Forestry Administration for Silviculture of the Lower Yellow River, College of Forestry, Shandong Agricultural University, Tai’an 271018, China, E-mail:
Xiwei Wang, Tengfei Yi and Hongxue Luo contributed equally to this work.

Award Identifier / Grant number: No. ZR2021MC095

Acknowledgments

The authors would like to acknowledge Ruizhi Gong, Jiajia Luo, Xiaojie Hu, Jianyu Gao and Ziyi Jiao from Shandong Agricultural University for their help in writing and drawing.

  1. Research ethics: Not applicable.

  2. Author contributions: Xiwei Wang: methodology, investigation, formal analysis, writing – original draft, writing – review & editing. Tengfei Yi: methodology, writing – review & editing, formal analysis. Hongxue Luo: methodology, investigation, formal analysis, writing – review & editing. Yanran Qi: investigation, writing – review & editing. Fengbiao Yao: formal analysis, writing – review & editing. Yiliang Liu: investigation, writing – review & editing. Yongfeng Li: conceptualization, methodology, resources, funding acquisition, project administration, writing – review & editing. All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  3. Competing interests: The authors state no conflict of interest.

  4. Research funding: This study was supported by the Project of Shandong Provincial Natural Science Foundation (Funder: Natural Science Foundation of Shandong Province; Grant no. ZR2021MC095).

  5. Data availability: The raw data can be obtained on request from the corresponding author.

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Supplementary Material

This article contains supplementary material (https://doi.org/10.1515/hf-2023-0128).


Received: 2023-12-21
Accepted: 2024-02-28
Published Online: 2024-03-26

© 2024 Walter de Gruyter GmbH, Berlin/Boston

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