Issue 34, 2024
From the journal:

Chemical Communications

Phenylglycine amphiphile-metal ion chiral supramolecular nanozymes for enantioselective catalysis†

Dongying Li,‡a   Cong Gao,‡a   Cici Zhao,a   Qingqing Sun, ORCID logo *a   Zheng Xi, ORCID logo *a   Jie Han ORCID logo *a  and  Rong Guo ORCID logo a  

* Corresponding authors

a Yangzhou University, School of Chemistry and Chemical Engineering, Yangzhou, Jiangsu 225002, China
E-mail: sunqingqing@yzu.edu.cn, xizheng@yzu.edu.cn, hanjie@yzu.edu.cn

Abstract

L/D-Phenylglycine amphiphiles and metal ions with peroxidase-like activity self-assembled into chiral nanoribbons, which act as efficient chiral supramolecular nanozymes for catalyzing the 3,4-dihydroxy-L/D-phenylalanine (L/D-DOPA) oxidation reactions. The catalytic efficiency and enantioselectivity are dominated by the chirality transfer and the synergistic effect between the metal ions and chiral nanoribbons.

Graphical abstract: Phenylglycine amphiphile-metal ion chiral supramolecular nanozymes for enantioselective catalysis

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Article information

DOI
https://doi.org/10.1039/D4CC00637B
Article type
Communication
Submitted
07 Feb 2024
Accepted
27 Mar 2024
First published
28 Mar 2024

Chem. Commun., 2024,60, 4569-4572

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Phenylglycine amphiphile-metal ion chiral supramolecular nanozymes for enantioselective catalysis

D. Li, C. Gao, C. Zhao, Q. Sun, Z. Xi, J. Han and R. Guo, Chem. Commun., 2024, 60, 4569 DOI: 10.1039/D4CC00637B

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