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Measurement and Empirical Models of Thermal Conductivity of Trifluoroiodomethane (CF3I)

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Abstract

This research is focused on the experimental measurement of the thermal conductivity of CF3I and the subsequent development of empirical models, which are integral to engineering system design calculations. CF3I is identified as a potential key component in the formulation of future refrigerant mixtures, owing to its non-explosive nature, low toxicity, and minimal contribution to ozone layer depletion and global warming. Its applicability is further reinforced by its advantageous thermodynamic properties, including a low boiling point and a high critical temperature, making it a vital constituent in refrigerant mixtures. The study employs the well-established transient hot-wire method to measure the thermal conductivity of CF3I in both its liquid and vapor phases. This method is characterized by the sequential arrangement of two platinum wires which are linked in parallel to nullify any impacts from axial heat conduction. Experimental data were methodically gathered across a range of temperatures, spanning from 311 K to 374 K for the liquid phase and from 312 K to 394 K for the vapor phase, under varying pressures from 1.5 MPa to 4.0 MPa and 0.5 MPa to 3.0 MPa, respectively. The combined uncertainties associated with these measurements were meticulously calculated, amounting to 1.8% for the liquid phase and 2.0% for the vapor phase. Furthermore, the research advanced to the development of thermal conductivity models for CF3I, employing both the Extended Corresponding States method and the modified Residual Entropy Scaling method. These models effectively encapsulate the empirical findings, fitting within the established uncertainty limits with reasonable extrapolating behavior. Critically, these models are expected to play a pivotal role in predicting the thermal conductivity of refrigerant mixtures that incorporate CF3I as a component, marking a significant contribution to the field of refrigerant technology.

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Acknowledgements

The authors thankfully acknowledge the Tosoh Finechem Corporation, Japan for providing the fluid sample and Professor Ryo Akasaka (Kyushu Sangyo University) for sharing Helmholtz energy-based equation of state before publication.

Funding

This work is supported by the New Energy and Industrial Technology Development Organization (NEDO) research project (Project Code: P18005).

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Authors and Affiliations

  1. Graduate School of Science and Engineering, Saga University, Saga, 840-8502, Japan

    Atiqur R. Tuhin & Monjur Morshed

  2. Department of Energy Science and Engineering, Khulna University of Engineering and Technology, Khulna, 9203, Bangladesh

    Monjur Morshed

  3. Department of Mechanical Engineering, Saga University, Saga, 840-8502, Japan

    Keishi Kariya & Akio Miyara

  4. International Institute for Carbon-Neutral Energy Research, Kyushu University, Fukuoka, 819-0385, Japan

    Akio Miyara

Authors
  1. Atiqur R. Tuhin
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  2. Monjur Morshed
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  3. Keishi Kariya
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  4. Akio Miyara
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Contributions

ART contributed by performing experiments, collecting data, calculating uncertainty, reporting the results, and engaging in the writing, reviewing, and editing of the manuscript. MM was involved in fitting the consistent data to the ECS and RES models, reporting and writing and evaluating the results of ECS and RES portion, comparing models with previously obtained experimental data, and participating in the reviewing and editing of the manuscript. KK and AM contributed through supervision, review, and editing of the paper. All authors have read and consented to the published version of the manuscript.

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Correspondence to Atiqur R. Tuhin or Akio Miyara.

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Selected Papers of the 22nd European Conference on Thermophysical Properties.

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Tuhin, A.R., Morshed, M., Kariya, K. et al. Measurement and Empirical Models of Thermal Conductivity of Trifluoroiodomethane (CF3I). Int J Thermophys 45, 63 (2024). https://doi.org/10.1007/s10765-024-03358-8

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  • DOI: https://doi.org/10.1007/s10765-024-03358-8

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