Skip to main content
SpringerLink
Log in

Composites Based on Guanidinium Polyampholytes and Silver Nanoparticles

  • Macromolecular Compounds and Polymeric Materials
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Copolymers of 2,2-diallyl-1,1,3,3-tetraethylguanidinium chloride with acrylic, methacrylic, crotonic and vinylacetic acids were synthesized by radical copolymerization in the presence of a radical initiator azobiisobutyronitrile. Composite materials containing silver nanoparticles ranging in size from 7 to 43.5 nm, depending on the nature of the polymer matrix, were fabricated according to the borohydride method. The structure of the nanocomposites was analyzed by UV, IR, NMR spectroscopy, scanning electron microscopy, and X-ray diffraction analysis. The synthesized nanocomposites have antimicrobial activity and are promising for the creation of new drugs.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme
Fig. 1.
Fig. 2.
Fig. 3.

REFERENCES

  1. Nanomaterials and Polymer Nanocomposites. Raw Materials to Applications, Karak, N., Ed., Amsterdam: Elsevier, 2019. https://doi.org/10.1016/B978-0-12-814615-6.00002-3

  2. Hazra Chowdhury, A., Debnath, R., Islam, S.M., and Saha, T., Sustainable Polymer Composites and Nanocomposites, Inamuddin, S., Thomas, R., Kumar, M., Asiri, and, A.M., Eds., Cham: Springer, 2019. https://doi.org/10.1007/978-3-030-05399-4_37

    Article  Google Scholar 

  3. Chumachenko, V., Kutsevol, N., Rawiso, M., Schmutz, M., and Blanck, C., Nanoscale Res. Lett., 2014, vol. 9, ID 164. https://doi.org/10.1186/1556-276X-9-164

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  4. Kang, H., Buchman, J.T., Rodriguez, R.S., Ring, H.L., He, J., Bantz, K.C., and Haynes, C.L., Chem. Rev., 2019, vol. 119, pp. 664–699. https://doi.org/10.1021/acs.chemrev.8b00341

    Article  CAS  PubMed  Google Scholar 

  5. Zhao, P., Zhou, X., Huang, Y., Xu, Y., Chen, S., Zheng, C., Jin, Y., and Xia, C., Surfaces and Interfaces, 2022, vol. 29, ID 101788. https://doi.org/10.1016/j.surfin.2022.101788

    Article  CAS  Google Scholar 

  6. Guanidines as Reagents and Catalysts II. Topics in Heterocyclic Chemistry, Selig, P., Ed., Amsterdam: Springer, 2015, vol. 51, pp. 95−164.

    Google Scholar 

  7. Krutyakov, Yu.A., Kudrinskiy, A.A., Gusev, A.A., Zakharova, O.V., Klimov, A.I., Yaprintsev, A.D., Zherebin, P.M., Shapoval, O.A., and Lisichkin, G.V., Mater. Res. Express., 2017, vol. 4, ID 075018. https://doi.org/10.1088/2053-1591/aa7a2e

    Article  CAS  Google Scholar 

  8. Kuznetsov, V.V., Smagina, V.V., Krivoshchepov, A.F., Avramenko, G.V., and Katuleva, S.P., Butlerovskie soobshch., 2015, vol. 44, no. 11, pp. 60–64. https://www.elibrary.ru/vbfzzr

  9. Nanoparticle Therapeutics: Production Technologies, Types of Nanoparticles, and Regulatory Aspects, Kesharwani, P. and Singh, K.K., Eds., London: Acad. Press, 2021. https://doi.org/10.1016/C2019-0-02042-0

  10. Deshmukh, S.P., Patil, S.M., Mullani, S.B., and Deleka, S.D.., Mater. Sci. Eng, C., Mater. Biol. Appl., 2019, vol. 97, pp. 954–965. https://doi.org/10.1016/j.msec.2018.12.102

    Article  CAS  PubMed  Google Scholar 

  11. Gorbunova, M.N., Voro’eva, A.I., Tolstikov, A.G., and Monakov, Yu.B., Polym. Adv. Tech., 2009, vol. 20, no. 3. pp. 209–215. https://doi.org/10.1002/pat.1253

    Article  Google Scholar 

  12. Gordon, A.J. and Ford, R.A., The Chemist’s Companion, New York: Wiley, 1972.

    Google Scholar 

  13. Gorbunova, M.N., Zagumennova, D.D., and Lemkina, L.M., Polym. Adv. Tech., 2023, vol. 34, no. 9, pp. 2961–2973. https://doi.org/10.1002/pat.6118

    Article  CAS  Google Scholar 

  14. Guidelines MUK, 4.2.1890-04. Determination of the Sensitivity of Microorganisms to Antibacterial Drugs.

  15. Gorbunova, M.N., Batueva, T.D., Eroshenko, D.V., and Kiselkov, D.M., Russ. J. Appl. Chem., 2021, vol. 94, no. 2, pp. 192–201. https://doi.org/10.1134/S1070427221020087

    Article  CAS  Google Scholar 

  16. Karpov, S.V. and Slabko, V.V., Opticheskie i fotofizicheskie svoistva fraktal’no-strukturirovannykh zolei metallov (Optical and Photophysical Properties of Fractal-Structured Metal Sols), Novosibirsk: Izd. SO RAN, 2003.

    Google Scholar 

  17. Heard, S.M., Greiser, F., Barraclough, C.G., and Sanders, J.V., Colloid. Interface Sci., 1983, vol. 93, pp. 545–555. https://doi.org/10.1016/0021-9797(83)90439-3

    Article  CAS  Google Scholar 

  18. Du, B.D., Phu, D.V., Duy, N.N., Lan, N.T.K., Lang, V.T.K., Thanh, N.V.K., Phong, N.T.P., and Hien, N.Q., J. Expert. Nanosci., 2008, vol. 3, pp. 207–213. https://doi.org/10.1080/17458080802353527

    Article  CAS  Google Scholar 

  19. Yin, B., Ma, H., Wang, Sh., and Chen, Sh., J. Phys. Chem. B, 2003, vol. 107, pp. 8898–8904. https://doi.org/10.1021/jp0349031

    Article  CAS  Google Scholar 

  20. Temgire, M.K. and Joshi, S.S., Radiat. Phys. Chem., 2004, vol. 71, pp. 1039–1044. https://doi.org/10.1016/j.radphyschem.2003.10.016

    Article  CAS  Google Scholar 

  21. Gorbunova, M.N. and Lemkina, L.M., J. Nanopart. Res., 2014, vol. 16. ID 2566. https://doi.org/10.1007/s11051-014-2566-0

    Article  Google Scholar 

  22. Pozdnyakov, A.S., Emelʹyanov, A.I., Ermakova, T.G., and Prozorova, G.F., Polym. Sci. B, 2014, vol. 56, pp. 238–246. https://doi.org/10.1134/S1560090414020122

    Article  CAS  Google Scholar 

  23. Barmatov, E.B., Medvedev, A.S., Pebalk, D.A., Barmatova, M.V., Nikanorova, N.A., Zezin, S.B., Shibaev, V.P., Polym. Sci. A, 2006, vol. 48, pp. 665–675. https://doi.org/10.1134/S0965545X06070017

    Article  Google Scholar 

  24. Sivov, N.A., Biocide Guanidine Containing Polymers. Synthesis, Structure and Properties, London: CRC Press, 2006. https://doi.org/10.1201/b12199

    Book  Google Scholar 

  25. Encyclopedia of Biomedical Polymers and Polymeric Biomaterials, Mishra, M., Ed. New York: Taylor & Francis Group, 2015. https://doi.org/10.1081/E-EBPP-120049929

Download references

ACKNOWLEDGMENTS

The authors thank the Center for Collective Use of Perm Federal Research Center, Ural Branch, Russian Academy of Sciences “Research of Materials and Substances” for spectral, analytical and biological studies.

Funding

The work was carried out with financial support from the Russian Science Foundation (grant no. 23-23-00073).

Author information

Authors and Affiliations

  1. Institute of Technical Chemistry, Ural Branch of the Russian Academy of Sciences, Branch of Perm Federal Research Center of the Ural Branch of the Russian Academy of Sciences, 614068, Perm, Russia

    M. N. Gorbunova & D. M. Kisel’kov

  2. Perm State University, 614990, Perm, Russia

    A. V. Ovcharuk

  3. Institute of Ecology and Genetics of Microorganisms, Ural Branch of the Russian Academy of Sciences, Branch of Perm Federal Research Center of the Ural Branch of the Russian Academy of Sciences, 614081, Perm, Russia

    L. M. Lemkina

Authors
  1. M. N. Gorbunova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Ovcharuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. M. Kisel’kov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. M. Lemkina
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. N. Gorbunova.

Ethics declarations

The authors declare that there are no conflicts of interest

Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 6, pp. 580–589 , June, 2023 https://www.elibrary.ru/SVRZRH

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gorbunova, M.N., Ovcharuk, A.V., Kisel’kov, D.M. et al. Composites Based on Guanidinium Polyampholytes and Silver Nanoparticles. Russ J Appl Chem 96, 656–664 (2023). https://doi.org/10.1134/S1070427223060046

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427223060046

Keywords:

Search

Navigation