Zinc iso-plating/stripping: toward a practical Zn powder anode with ultra-long life over 5600 h

Abstract

Zn powder with large-scale production and good tunability is promising for aqueous Zn-ion batteries, but its extremely short lifespan seriously hinders the practical application. Herein, we disclose that Zn powder anode failure is majorly caused by top-down plating and bottom-up stripping behaviors. Therefore, an iso-plating/stripping strategy has to be developed accordingly to achieve an ultra-long lifetime Zn powder anode for practical applications. Zincophilic Bi-metal nanosheets are anchored on the Zn powder surface, which could serve as preferred Zn nucleation sites and charge-aggregated protrusions, leading to homogeneous plating/stripping and gradient-free Zn2+ distribution throughout the powder electrode. Furthermore, Bi has additional advantages including the ability to guide Zn(002)-orientated growth and suppress side reactions for achieving further structural stability, permitting unprecedented stable cycling of over 5600 h at 1 mA cm−2 and 585 h even at 15 mA cm−2. The corresponding Bi@Zn powder//MnO2 full batteries feature an extraordinary capacity retention of 82.12% after 1150 cycles at 2 A g−1 and a low negative/positive electrode capacity ratio of 6.65. When applied in pouch-type batteries, Bi@Zn powder delivers an impressive energy density of 138.6 W h kg−1 at a superfast power density of 700 W kg−1. This study clarifies the failure mechanism of the Zn powder anode and develops a concise yet effective strategy that paves the way for fabricating practical Zn anodes with a long life and dendrite-free structure.

Graphical abstract: Zinc iso-plating/stripping: toward a practical Zn powder anode with ultra-long life over 5600 h

Supplementary files

Article information

Article type
Paper
Submitted
13 Dec 2023
Accepted
02 Apr 2024
First published
03 Apr 2024

Energy Environ. Sci., 2024, Advance Article

Zinc iso-plating/stripping: toward a practical Zn powder anode with ultra-long life over 5600 h

H. Chen, W. Zhang, S. Yi, Z. Su, Z. Zhao, Y. Zhang, B. Niu and D. Long, Energy Environ. Sci., 2024, Advance Article , DOI: 10.1039/D3EE04333A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements