Abstract
A new member of the A2B5C5X16 family of compounds – the first one containing Se – has been synthesized. Following a one-step mechanochemical synthesis route, starting from the binary selenides and Mg metal, Cu2Mg5Sn5Se16 has been obtained. Structural evaluation was carried out using X-ray diffraction with subsequent Rietveld refinement. Cu2Mg5Sn5Se16 adopts the spinel type with space group Fd
Dedicated to Professor Thomas Bredow of the University of Bonn on the occasion of his 60th birthday.
Acknowledgments
Special thanks to the Zentrum für Elektronenmikroskopie (ZELMI) of the TU Berlin giving access to the EDX measurements. EDX measurements were carried out by Christoph Fahrenson.
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Research ethics: Not applicable.
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Author contributions: The authors have accepted responsibility for the entire content of this manuscript and approved its submission.
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Competing interests: The authors state no conflict of interest.
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Research funding: None declared.
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Data availability: Not applicable.
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