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Reactivity of 5-Methylpyridyl-2-Selenolate With Platinoid Metal Precursors: Isolation of Tri and Hexanuclear Complexes via Se-Se and Se-C Bond Cleavage

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Abstract

A series of palladium (II) and platinum (II) selenolate complexes have been isolated depending upon the nature of the phosphine ligand. The substitution reaction of [PdCl2(PPh3)2] with two equivalents of NaSeC5H3(5-Me)N resulted in the hexanuclear complex [Pd6Br0.87Cl1.13{2-SeC5H3(5-Me)N2}2(PPh3)6] (1a) whereas a chelated compound [Pt{κ-Se, κ-N: SeC5H3(5-Me)N}{SeC5H3(5-Me)N}(PPh3)] (1b) has been obtained in the case of [PtCl2(PPh3)2]. However, chelated phosphine as an ancillary ligand with a similar reaction by using [PtCl2(P∩P)] (P∩P = dppm, dppe) yielded cis-configured monomer [Pt{2-SeC5H3(5-Me)N}2(P∩P)]. The trinuclear complexes [M3(µ-Se)3(dppp)3]2+ [M = Pd (2d), Pt (2e)] were isolated by reactions of [MCl2(dppp)] (M = Pd, Pt) with NaSeC5H3(5-Me)N via facile cleavage of Se-C bond in presence of chlorinated solvents. All the synthesized complexes have been characterized by elemental analyses, 1H, 31P{1H}, 77Se{1H} NMR spectroscopy. The molecular structure of complexes [Pd6Br0.87Cl1.13{2-SeC5H3(5-Me)}2(PPh3)6] (1a) and [Pt{2-SeC5H3(5-Me)N}2(dppm)].C6H5CH3 (2a) were determined by single crystal X-ray diffraction analyses.

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Scheme 1
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Acknowledgements

One of the authors Dr. Afsar Ali Siddiki is thankful to DST-SERB for providing grant (TARE/2022/000220) to carry out this work. Authors are also thankful to Mr. Kamlesh Sathpute from IIT Ropar for carrying out the single crystal XRD.

Funding

One of the authors Afsar Ali Siddiki is thankful to DST-SERB for providing grant (TARE/2022/000220) to carry out this work.

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Authors and Affiliations

  1. Department of Chemistry, K. J. Somaiya College of Science and Commerce, Vidyavihar, Mumbai, 400077, India

    Saili Vikram Lokhande, Atharva Yeshwant Kulkarni, Afsar Ali Siddiki & Rohit Singh Chauhan

  2. Department of Chemistry, Howard University, Washington DC, 20059, USA

    Raymond J. Butcher

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  1. Saili Vikram Lokhande
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  2. Atharva Yeshwant Kulkarni
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Contributions

Saili Vikram Lokhande: Investigation, methodology, data curation, writing main manuscript; Atharva Yeshwant Kulkarni: Data curation; Afsar Ali Siddiki: Data curation; Raymond J. Butcher: Data curation, writing-review and editing, Rohit Singh Chauhan: Conceptualization, supervision, writing-review and editing.

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Correspondence to Rohit Singh Chauhan.

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Supplementary Material 1

Appendix A. Supplementary Data

Appendix A. Supplementary Data

CCDC 2326944, 2294251 for complexes [Pd6Br0.87Cl1.13{2-SeC5H3(5-Me)N2}2(PPh3)6] and [Pt{2-SeC5H3(5-Me)N}2(dppm)] respectively contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/data_request/cif, from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: (+ 44) 1223-336-033; or e-mail: deposit@ccdc.cam.ac.uk.

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Lokhande, S.V., Kulkarni, A.Y., Siddiki, A.A. et al. Reactivity of 5-Methylpyridyl-2-Selenolate With Platinoid Metal Precursors: Isolation of Tri and Hexanuclear Complexes via Se-Se and Se-C Bond Cleavage. J Clust Sci (2024). https://doi.org/10.1007/s10876-024-02606-z

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