Electrochemical nickel-catalyzed cross-coupling of glycosyl thiols with preactivated phenols and ketones†
Qingju
Zhang 
*a
and
Liming
Wang
*a
*a
and
Liming
Wang
*a
Abstract
An efficient electrochemical nickel-catalyzed cross-coupling reaction has been reported here for the synthesis of S-glycosides from preactivated phenols and ketones under mild conditions. Various glycosyl thiols, including unprotected sugar, and a diverse range of aryl/alkenyl triflates, including some complex biorelevant phenols and ketones, were well tolerated in this method.
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