Sludge biochar loaded with Fe–Mn oxides (FMBC) was prepared and employed to remove Cr(VI) from wastewater. The influences of solution pH, co-existing ion, contact time, adsorption temperature and Cd(VI) concentrations on removing Cr(VI) by FMBC were investigated. The Cr(VI) adsorption on FMBC had strong pH dependence. Additionally, Na⁺, Mg²⁺, Ca²⁺, SiO₃²⁻, NO₃⁻ and Cl⁻ ions exhibited no influence on Cr(VI) removal efficiency for FMBC, whereas there were inhibition effects of Pb²⁺, Cu²⁺, Ni²⁺, CO₃²⁻, SO₄²⁻, and PO₄³⁻ on removing Cr(VI). The Cr(VI) adsorption from solution for FMBC was well described by models of pseudo-second-order and Langmuir, and the largest Cr(VI) removal capacity of FMBC reached 172.3 mg g⁻¹. FMBC had good capacity for treating electroplating wastewater and mineral dissolving wastewater containing Cr(VI). After five regenerations, the 50 and 5 mg L⁻¹ Cr(VI) removing efficiency of FMBC was 82.34% and 97.68%, respectively. The Cr(VI) removal for FMBC involved adsorption-reduction and re-adsorption of Cr(III) generated by reduction. These results indicated that FMBC has good prospects for remediating Cr(VI)-containing wastewater.