From the journal:

Chemical Communications

Visible light-promoted [3+2] cyclization reaction of vinyl azides with perfluoroalkyl-substituted-imidoyl sulfoxonium ylides†

Ming Yang,a   Yu-Xuan Meng,a   Haroon Mehfooza  and  Yu-Long Zhao ORCID logo *a  

* Corresponding authors

a Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Department of Chemistry, Northeast Normal University, Changchun 130024, China
E-mail: zhaoyl351@nenu.edu.cn

Abstract

Visible-light-induced [3+2] cyclization of vinyl azides with perfluoroalkyl-substituted imidoyl sulfoxonium ylides has been developed for the first time. In this transformation, perfluoroalkyl-substituted imidoyl sulfoxonium ylides are firstly employed as a carbon radical precursor under visible light irradiation, providing a new and efficient method for the construction of perfluoroalkyl-substituted 1-pyrrolines.

Graphical abstract: Visible light-promoted [3+2] cyclization reaction of vinyl azides with perfluoroalkyl-substituted-imidoyl sulfoxonium ylides

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Article information

DOI
https://doi.org/10.1039/D4CC00777H
Article type
Communication
Submitted
17 Feb 2024
Accepted
16 Apr 2024
First published
17 Apr 2024

Chem. Commun., 2024, Advance Article

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Visible light-promoted [3+2] cyclization reaction of vinyl azides with perfluoroalkyl-substituted-imidoyl sulfoxonium ylides

M. Yang, Y. Meng, H. Mehfooz and Y. Zhao, Chem. Commun., 2024, Advance Article , DOI: 10.1039/D4CC00777H

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