Abstract
Iron oxides have found a large number of applications in fields ranging from biomedical to space science. Amongst all iron oxides, the most favored is Fe3O4 owing to high saturation magnetization, biocompatibility, and cost-effectiveness. The Fe3O4 has an inverse spinel structure with colors ranging from dark brown to black. In this research paper, the Fe3O4 and Co-doped Fe3O4 nanoparticles were synthesized by co-precipitate method. The X-ray diffractometer (XRD), Scanning electron microscopy (SEM), EDX and RAMAN spectroscopy analysis confirm the formation of synthesized nanoparticles. From UV visible, the optical properties are studied and it is found that after doping of Co, the band gap had increased, and the electrical property of doped Fe3O4 goes towards the dielectric behavior. From the vibrating sample magnetometer (VSM), magnetic properties are studied. By Gouy’s balance susceptibility was determined and values calculated, are in good agreement with the susceptibility calculated by VSM. The temperature-dependent conductivity was assessed using the four-probe method. The degradation of dye like methyl orange with the synthesized nanomaterials was studied.
Similar content being viewed by others
Data Availability
Data is available upon request from the corresponding author.
References
A.G. Magdalena, I.M.B. Silva, R.F.C. Marques, A.R.F. Pipi, P.N. Lisboa-Filho, M. Jafelicci Jr., J. Phys. Chem. Solids 113, 5 (2018)
C. Yang, H. Li, D. Xiong, Z. Cao, React. Funct. Polym. 69, 137 (2009)
M. Houshiar, F. Zebhi, Z.J. Razi, A. Alidoust, Z. Askari, J. Magn. Magn. Mater. 371, 43 (2014)
Y. Wei, B. Han, X. Hu, Y. Lin, X. Wang, X. Deng, Procedia Eng. 27, 632 (2012)
P. Sharma, S. Thakor, S.J. Yadav, I.A. Shaikh, D.V. Shah, V.A. Rana, M. Solanki, J. Cryst. Growth, 628, 127551 (2023)
C.N. Chinnasamy, M. Senoue, B. Jeyadevan, O. Perales-Perez, K. Shinoda, K. Tohji, J. Colloid Interface Sci. 263, 80 (2003)
P. Sharma, D.V. Shah, S. Thakor, A.D. Watpade, V.A. Rana, C.R. Vaja, J. Macromol. Sci. Part B 1, 63(5), 279 (2023)
D. Mishra, K.K. Senapati, C. Borgohain, A. Perumal, J. Nanotechnol. 2012(323145), 6 (2012)
H. Kyung, J. Lee, W. Choi, Environ. Sci. Technol. 39, 2376 (2005)
H. Lachheb, E. Puzenat, A. Houas, M. Ksibi, E. Elaloui, C. Guillard, J.-M. Herrmann, Appl. Catal. B Environ. 39, 75 (2002)
W.S. Kuo, P.H. Ho, Chemosphere 45, 77 (2001)
V. Subramanian, R.K. Roeder, E.E. Wolf, Ind. Eng. Chem. Res. 45, 2187 (2006)
D.L. Liao, B.Q. Liao, J. Photochem. Photobiol. A Chem. 187, 363 (2007)
R.S. Yadav, I. Kuřitka, J. Vilcakova, J. Havlica, J. Masilko, L. Kalina, J. Tkacz, J. Švec, V. Enev, M. Hajdúchová, Adv. Nat. Sci. Nanosci. Nanotechnol. 8, 45002 (2017)
D.S. Nikam, S.V. Jadhav, V.M. Khot, R.A. Bohara, C.K. Hong, S.S. Mali, S.H. Pawar, RSC Adv. 5, 2338 (2015)
A.D. Watpade, S. Thakor, P. Sharma, D.V. Shah, C.R. Vaja, P. Jain, J. Mater. Sci. Mater. Electron. 35, 466 (2024)
S.G. Thakor, V.A. Rana, H.P. Vankar, T.R. Pandit, Indian J. Pure Appl. Phys. 59, 643 (2021)
R.C. Kambale, P.A. Shaikh, S.S. Kamble, Y.D. Kolekar, J. Alloys Compd. 478, 599 (2009)
S.G. Thakor, V.A. Rana, H.P. Vankar, T.R. Pandit, J. Adv. Dielectr. 11, 2150011 (2021)
F. Ansari, A. Sobhani, M. Salavati-Niasari, RSC Adv. 4, 63946 (2014)
H. Espinoza-Gómez, L.Z. Flores-López, K.A. Espinoza, G. Alonso-Nuñez, Appl. Nanosci. 10, 127 (2020)
R. Dhir, Chem. Phys. Lett. 746, 137302 (2020)
L. Ferraris, F. Franchini, E. Pošković, In 2019, IEEE Transactions on Industry Applications, 55(6), 5779–5788 92 (2019)
L. Blane, Magnetite (Fe3O4): Properties, synthesis, and applications. (2017)
Y. Singh, in Int. J. Mod. Phys. Conf. Ser. (World Scientific, 2013), pp. 745–756 (2013)
V. Batra, S. Kotru, M. Varagas, C.V. Ramana, Opt. Mater. (Amst). 49, 123 (2015)
Acknowledgements
The author would like to thank I. A. Shaikh; Department of Basic Science and Humanities, Bharti Vidyapeeth (Deemed to be University) College of Engineering, Dhankawadi, Pune-411043; for his support during the synthesis process.
Author information
Authors and Affiliations
Contributions
Poonam Sharma played a key role in the synthesis of materials, their characterization, and the initial drafting of the manuscript. Sunita J. Yadav contributed significantly to the characterization aspects of the study. Dr. Dimple V. Shah provided valuable guidance, contributed to the development of the methodology, and supervised the overall research process.
Corresponding author
Ethics declarations
Conflict of Interest
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Sharma, P., Yadav, S.J. & Shah, D.V. Synthesis, Characterizations, and Applications of Fe3O4 and Co-Doped Fe3O4 Nanomaterials. Braz J Phys 54, 88 (2024). https://doi.org/10.1007/s13538-024-01469-z
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s13538-024-01469-z