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Adsorption of Molecular Oxygen on N-graphene

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Abstract

The adsorption and dissociation of molecular oxygen on the surface of N-graphene/Au/Ni(111) epitaxial system with high crystalline quality of N-graphene have been investigated. The system is formed in such a way that nitrogen impurities in it are exclusively represented by graphitic and pyridinic configurations in equal concentrations. Using X-ray photoelectron spectroscopy and density functional theory calculations, the relationship between the chemical shift of the N 1s core level caused by the adsorption of molecular oxygen and the atomic position of individual oxygen atoms after molecular dissociation has been established.

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Funding

This work was supported by St. Petersburg State University (grant no. 94031444) and by Helmholtz-Zentrum Berlin für Materialien und Energie within the bilateral Russian–German Laboratory program.

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  1. St. Petersburg State University, St. Petersburg, Russia

    K. A. Bokai, O. Yu. Vilkov & D. Yu. Usachov

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  1. K. A. Bokai
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Bokai, K.A., Vilkov, O.Y. & Usachov, D.Y. Adsorption of Molecular Oxygen on N-graphene. Crystallogr. Rep. 69, 102–108 (2024). https://doi.org/10.1134/S1063774523601314

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