Skip to main content
Log in

Efficient Degradation of Diazinon Pesticide under Visible Light Irradiation Using CeO2 Functionalized Magnetite Graphene Oxide Heterojunction-Based Photocatalyst

  • Published:
Water, Air, & Soil Pollution Aims and scope Submit manuscript

Abstract

Controlling the structure of cerium dioxide (CeO2)-based photocatalysts for the removal of organic contaminants in water is essential. Herein, GO/Fe3O4/CeO2 heterojunction photocatalyst is designed by a clear and simple method for photodegradation of diazinon under visible-light excitation. SEM, EDS, XRD, FTIR, VSM, and UV–vis were used to analyze the crystallinity and morphology of the GO/Fe3O4/CeO2 heterojunction. The UV–Vis analysis revealed a bandgap value of 3.19, 3.08, and 2.98 eV, respectively, for GO, GO@Fe3O4, and GO@Fe3O4@CeO2. The effects of important parameters such as pH (2.0–9.0), photocatalyst dose (10–40 mg), and contact time (0–180 min) were also investigated. The maximum diazinon degradation rate was found to be 97.9% in 60 min. In conclusion, the results indicated that GO@Fe3O4@CeO2 nanocomposite could be used as an efficient photocatalyst for the degradation of organic contaminants from water medium.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

Data Availability

The authors declare that they have not need research data support with this submission. Also, the authors are sure that all data and materials as well as software application or custom code support their published claims and comply with field standards.

References

  • Amiri, S., & Anbia, M. (2023). Enhanced degradation of diazinon in aqueous solution using C-TiO2/g-C3N4 nanocomposite under visible light: Synthesis, characterization, kinetics, and mechanism studies. Materials Research Bulletin, 165, 112289.

    Article  CAS  Google Scholar 

  • Cao, M., Wang, P., Ao, Y., Wang, C., Hou, J., & Qian, J. (2016). Visible light activated photocatalytic degradation of tetracycline by a magnetically separable composite photocatalyst: Graphene oxide/magnetite/cerium-doped titania. Journal of Colloid and Interface Science, 467, 129–139.

    Article  CAS  Google Scholar 

  • Cheraghi, M. (2022). Synthesis of GO/Fe3O4-ZnO/CS nanocomposite as an ideal adsorbent for removal of tamoxifen from water. International Journal of Environmental Analytical Chemistry, 102, 7135–7154.

    Article  CAS  Google Scholar 

  • Ghanbari, F., Ahmadi, M., & Gohari, F. (2019). Heterogeneous activation of peroxymonosulfate via nanocomposite CeO2-Fe3O4 for organic pollutants removal: The effect of UV and US irradiation and application for real wastewater. Separation and Purification Technology, 228, 115732.

    Article  CAS  Google Scholar 

  • Ghodsi, S., Esrafili, A., Kalantary, R. R., Gholami, M., & Sobhi, H. R. (2020). Synthesis and evaluation of the performance of g-C3N4/Fe3O4/Ag photocatalyst for the efficient removal of diazinon: Kinetic studies. Journal of Photochemistry and Photobiology a: Chemistry, 389, 112279.

    Article  CAS  Google Scholar 

  • Gusain, R., Gupta, K., Joshi, P., & Khatri, O. P. (2019). Adsorptive removal and photocatalytic degradation of organic pollutants using metal oxides and their composites: A comprehensive review. Advances in Colloid and Interface Science, 272, 102009.

    Article  CAS  Google Scholar 

  • Jalili-Jahani, N., Fatehi, A., Azizi-Saadi, J., & Moallem, M. (2022). Enhanced photocatalytic degradation of diazinon by bimetallic Au/Ag-decorated TiO2 nanorods and quadrupole time-of-flight LC-MS/MS assay for detection of by-products. Ceramics International, 48, 34415–34427.

    Article  CAS  Google Scholar 

  • Li, J., Wei, L., Yu, C., Fang, W., Xie, Y., Zhou, W., & Zhu, L. (2015). Preparation and characterization of graphene oxide/Ag2CO3 photocatalyst and its visible light photocatalytic activity. Applied Surface Science, 358, 168–174.

    Article  CAS  Google Scholar 

  • Liu, C., Cui, X., Li, Y., & Duan, Q. (2020a). A hybrid hollow spheres Cu2O@TiO2-g-ZnTAPc with spatially separated structure as an efficient and energy-saving day-night photocatalyst for Cr(VI) reduction and organic pollutants removal. Chemical Engineering Journal, 399, 125807.

    Article  CAS  Google Scholar 

  • Liu, F., Sun, Y., Gu, J., Gao, Q., Sun, D., Zhang, X., Pan, B., & Qian, J. (2020b). Highly efficient photodegradation of various organic pollutants in water: Rational structural design of photocatalyst via thiol-ene click reaction. Chemical Engineering Journal, 381, 122631.

    Article  CAS  Google Scholar 

  • Maleki, A., Moradi, F., Shahmoradi, B., Rezaee, R., & Lee, S.-M. (2020). The photocatalytic removal of diazinon from aqueous solutions using tungsten oxide doped zinc oxide nanoparticles immobilized on glass substrate. Journal of Molecular Liquids, 297, 111918.

    Article  CAS  Google Scholar 

  • Mohagheghian, A., Besharati-Givi, N., Ayagh, K., & Shirzad-Siboni, M. (2022). Mineralization of diazinon by low-cost CuO-Kaolin nanocomposite under visible light based RSM methodology: Kinetics, cost analysis, reaction pathway and bioassay. Journal of Industrial and Engineering Chemistry, 116, 276–292.

    Article  CAS  Google Scholar 

  • Mohammadi, A., Mirhosseini, H., Hekmatiyan, A., Abdolahi, L., Mehrabi, F., & Shahmirzaei, M. (2023). Efficient degradation of parathion as a pollutant and diazinon as a nerve agent by reaction mechanism with rGO-Co3O4/ZnO nanocomposite photocatalyst. Journal of Environmental Chemical Engineering, 11, 110912.

    Article  CAS  Google Scholar 

  • Nie, X., Zhang, R., Tang, Z., Wang, H., Deng, P., & Tang, Y. (2020). Sensitive and selective determination of tryptophan using a glassy carbon electrode modified with nano-CeO2/reduced graphene oxide composite. Microchemical Journal, 159, 105367.

    Article  CAS  Google Scholar 

  • Rad, T. S., Khataee, A., & Pouran, S. R. (2018). Synergistic enhancement in photocatalytic performance of Ce (IV) and Cr (III) co-substituted magnetite nanoparticles loaded on reduced graphene oxide sheets. Journal of Colloid and Interface Science, 528, 248–262.

    Article  CAS  Google Scholar 

  • Sun, T., Shi, Z., Zhang, X., Wang, X., Zhu, L., & Lin, Q. (2019). Efficient degradation of p-arsanilic acid with released arsenic removal by magnetic CeO2–Fe3O4 nanoparticles through photo-oxidation and adsorption. Journal of Alloys and Compounds, 808, 151689.

    Article  CAS  Google Scholar 

  • Thakur, K., & Kandasubramanian, B. (2019). Graphene and graphene oxide-based composites for removal of organic pollutants: A review. Journal of Chemical & Engineering Data, 64, 833–867.

    Article  CAS  Google Scholar 

  • Vasseghian, Y., Sezgin, D., Nguyen, D. C., Hoang, H. Y., & Sari Yilmaz, M. (2023). A hybrid nanocomposite based on CuFe layered double hydroxide coated graphene oxide for photocatalytic degradation of trimethoprim. Chemosphere, 322, 138243.

    Article  CAS  Google Scholar 

  • Wang, P., Cai, Y., Mo, W., Fan, Z., Li, Z., Wu, L., Zhong, S., & Bai, S. (2024). Modulating the Schottky barrier heights of plasmonic metal/semiconductor heterojunctions by graphene substrates for boosting photocatalytic water oxidation. Applied Surface Science, 642, 158561.

    Article  CAS  Google Scholar 

  • Wei, Y., Li, X., Zhang, Y., Yan, Y., Huo, P., & Wang, H. (2021). G-C3N4 quantum dots and Au nano particles co-modified CeO2/Fe3O4 micro-flowers photocatalyst for enhanced CO2 photoreduction. Renewable Energy, 179, 756–765.

    Article  CAS  Google Scholar 

  • Xiang, D., Lu, S., Ma, Y., & Zhao, L. (2022). Synergistic photocatalysis-fenton reaction of flower-shaped CeO2/Fe3O4 magnetic catalyst for decolorization of high concentration congo red dye. Colloids and Surfaces a: Physicochemical and Engineering Aspects, 647, 129021.

    Article  CAS  Google Scholar 

  • Xu, X., Meng, L., Luo, J., Zhang, M., Wang, Y., Dai, Y., Sun, C., Wang, Z., Yang, S., & He, H. (2021). Self-assembled ultrathin CoO/Bi quantum dots/defective Bi2MoO6 hollow Z-scheme heterojunction for visible light-driven degradation of diazinon in water matrix: Intermediate toxicity and photocatalytic mechanism. Applied Catalysis b: Environmental, 293, 120231.

    Article  CAS  Google Scholar 

  • Zandipak, R., Sobhan Ardakani, S., & Shirzadi, A. (2020). Synthesis and application of nanocomposite Fe3O4@SiO2@CTAB–SiO2 as a novel adsorbent for removal of cyclophosphamide from water samples. Separation Science and Technology, 55, 456–470.

    Article  CAS  Google Scholar 

  • Zandipak, R., & Sobhanardakani, S. (2018). Novel mesoporous Fe3O4/SiO2/CTAB–SiO2 as an effective adsorbent for the removal of amoxicillin and tetracycline from water. Clean Technologies and Environmental Policy, 20, 871–885.

    Article  CAS  Google Scholar 

  • Zhang, Y., Zhou, B., Chen, H., & Yuan, R. (2023). Heterogeneous photocatalytic oxidation for the removal of organophosphorus pollutants from aqueous solutions: A review. Science of the Total Environment, 856, 159048.

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors are grateful to the Hamedan Branch, Islamic Azad University for providing facilities to conduct and complete this study.

Funding

Not applicable.

Author information

Authors and Affiliations

Authors

Contributions

All authors contributed to the study conception and design. Material preparation, data collection, and analysis were performed by Seyed Khabat Naynava, Bahareh Lorestani, Mehrdad Cheraghi, Soheil Sobhan Ardakani, and Behzad Shahmoradi. The first draft of the manuscript was written by Seyed Khabat Naynava and Soheil Sobhan Ardakani, and all authors commented on previous versions of the manuscript. The corresponding author ensures that all the listed authors have approved the manuscript before submission, including the names and order of authors.

Corresponding author

Correspondence to Bahareh Lorestani.

Ethics declarations

Ethical Approval and Consent to Participate

This article does not contain any studies with animals and human subjects. The authors confirm that all the research meets ethical guidelines and adheres to the legal requirements of the study country.

Consent for Publication

The authors declare that this manuscript does not contain any individual person's data and material in any form.

Conflict of Interest

The authors declare no competing interests.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Naynava, S.K., Lorestani, B., Cheraghi, M. et al. Efficient Degradation of Diazinon Pesticide under Visible Light Irradiation Using CeO2 Functionalized Magnetite Graphene Oxide Heterojunction-Based Photocatalyst. Water Air Soil Pollut 235, 274 (2024). https://doi.org/10.1007/s11270-024-07087-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s11270-024-07087-4

Keywords

Navigation