Richards, Emma - Cardiff University

个人简介

BSc(Hons) Natural Sciences with study in Industry, (Infineum, Oxfordshire; 1st Class Honours, Accenture prize for highest graduating student), University of Bath (1999 – 2003); PhD, University of Wales, Cardiff (2003 – 2007, Prof D. Murphy); Welsh Livery Guild Trust Travel Scholarship, University of Antwerp, (July 2008); Postdoctoral Research Associate, Cardiff University (2007 – 2015); Appointed Cardiff University Research Fellow 2015.

研究领域

The research interests of the group focus on utilizing the powerful technique of Electron Paramagnetic Resonance (EPR) spectroscopy and associated hyperfine methodologies [e.g. Electron Nuclear Double Resonance (ENDOR), Hyperfine Sublevel Correlation Spectroscopy (HYSCORE) and Pulsed Electron Double Resonance (PELDOR)] in two main areas of activity: investigating electron transfer processes in condensed matter materials of importance in visible-light activated catalysis, elucidating the nature of transition metal active sites in metalloenzymes and bioinorganic systems.

近期论文

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Constantinides, C.et al. 2017. Effects of Halo-substitution on 2'-Chloro-5'-halo-phenyl-1,2,3,5-dithiadiazolyl Radicals: A Crystallographic, Magnetic and EPR Case Study. Crystal Growth and Design (10.1021/acs.cgd.6b01700) pdf Zhang, S.et al. 2016. Delocalized hypervalent silyl radical supported by amidinate and imino substituents. Inorganic Chemistry 56(2), pp. 701-704. (10.1021/acs.inorgchem.6b02427) pdf Pelties, S.et al. 2016. Influence of ring-expanded N-Heterocyclic Carbenes on the structures of half-sandwich Ni(I) complexes: An X-ray, electron paramagnetic resonance (EPR), and electron nuclear double resonance (ENDOR) study. Inorganic Chemistry 55(21), pp. 11006-11017. (10.1021/acs.inorgchem.6b01540) pdf Su, R.et al. 2016. Mechanistic insight into the interaction between a titanium dioxide photocatalyst and Pd co-catalyst for improved photocatalytic performance. ACS Catalysis 6(7), pp. 4239-4247. (10.1021/acscatal.6b00982) pdf Et-Tarhouni, Z.et al. 2016. Quantifying the micellar structure formed from hydrocarbon-fluorocarbon surfactants. Colloids and Surfaces A: Physiochemical and Engineering Aspects 492, pp. 255-262. (10.1016/j.colsurfa.2015.12.015) Hallett, A.et al. 2016. Copper(II) complexes of pyridine-oxazoline (Pyox) ligands: coordination chemistry, ligand stability, and catalysis. Inorganica Chimica Acta 441, pp. 86-94. (10.1016/j.ica.2015.10.032) pdf Healy, M.et al. 2015. EPR/ENDOR and computational study of outer sphere interactions in copper complexes of phenolic oximes. Inorganic Chemistry 54(17), pp. 8465-8473. (10.1021/acs.inorgchem.5b01180) Carter, E.et al. 2015. Structure determination of bound nitrogen-based adducts with copper(ii) acetylacetonato; an EPR, ENDOR and DFT study. Physical Chemistry Chemical Physics 17(17), pp. 11445-11454. (10.1039/C5CP00559K) Ambrose, L.et al. 2014. Investigating mitochondrial metabolism in contracting HL-1 cardiomyocytes following hypoxia and pharmacological HIF activation identifies HIF-dependent and independent mechanisms of regulation. Journal of Cardiovascular Pharmacology and Therapeutics 19(6), pp. 574-585. (10.1177/1074248414524480) Bedford, R.et al. 2014. Iron-catalyzed borylation of alkyl, allyl, and aryl halides: isolation of an iron(I) boryl complex. Organometallics 33(21), pp. 5940-5943. (10.1021/om500847j) Bedford, R.et al. 2014. Iron phosphine catalyzed cross-coupling of tetraorganoborates and related group 13 nucleophiles with alkyl halides. Organometallics 33(20), pp. 5767-5780. (10.1021/om500518r)