个人简介

Univ. of Illinois at Urbana-Champiagn(USA)(Ph.D.) (1978) National Tsing Hua University(B.S.) (1971)

研究领域

Organometallic; Material Chemistry and dye sensitized photovoltaic

1. Transition Metal Cluster Chemistry Synthesis and characterization of acetylide, alkylidyne, carbido and oxo- ligands containing carbonyl cluster compounds. These studies are focused on the exploration of their solid-state crystal structures, solution dynamics, and the possible application as efficient catalysts or as templates for assembling small organic intermediates. 2. Materials Chemistry Chemical Vapor Deposition. Design and preparation of a variety of highly volatile transition-metal or main-group complexes useful in depositing thin film materials such as Co, Cu, Pd, Ir, Ru or Os, metal fluorides, oxides and sulfides such as BaF2, SrF2, Ga2O3, In2O3, RuO2, IrO2, CdS and ZnS or even mixed metal alloys such as Ru/Pt, which is a highly effective catalyst for DMFC applications. In addition, we are also interested in the growth of patterned nano-materials on various substrates using our custom-made CVD source reagents. Luminescent Organometallic Compounds. This section of work is probably the most significant research for Prof. Chi in terms of the potential for industrial applications and led to the issue of three patents and several more pending. He was the first to prepare the highly luminescent Os(II) b-diketonate complexes (Chem. Commun. 2003, 3046), which was highly praised by Platinum Metals Reviews (2004, 48, 12) for their ingenious molecular designs, and to develop the blue-emitting Os (II) phosphorescent materials (Organometallics 2003, 22, 4938) at the time when the fabrication of blue phosphorescent OLEDs is just at dawn. As a result, the second paper was selected as the most accessed article on Organometallics in 2003 and 2004, as well as the second most accessed paper in the first half-year of 2005. Six months later, his work on red-emitting osmium (II) phosphorescent complexes eliminated the long-time dominance of Ir(III) based complexes in fabricating red-emitting OLEDs and set up the new records for the device performances (Organometallics 2004, 23, 3745). Not surprisingly, this paper was selected as the most accessed paper in the category of Technical Note, Commentary and Review in 2004. Furthermore, he also completed the synthesis of neutral Ru(II) emitters, despite of the skepticism that the weaker ligand field strength as well as its less efficient spin-orbit coupling of Ru(II) element would prohibit their application for making high performance OLEDs. Nevertheless, good progress was achieved and these are apparently credited to the rational ligand design via the standpoint of fundamental chemistry and photophysics (Adv. Mater. 2005, 17, 1059). In the mean time, he has started collaboration with Dr. Chin-Ti Chen of Academic Sinica, focusing on the preparation and utilization of blue-emitting iridium (III) complexes. In short, they have finished the fabrication of the high efficiency blue phosphorescent OLEDs, using direct physical vapor deposition of the tailor-made iridium emitting complexes and the carbazolyl substituted tetraphenylsilane as the host material. The paper appeared in the prestigious material journal (Adv. Mater. 2005, 17, 285) was selected by its editorial staffs as the second most downloaded article in the year of 2005. Moreover, he also joined another collaborator (Prof. Ching-Fong Hsu of National Chiao Tung University) and took part in the investigation using fluorene-based copolymer for preparation of PLEDs (Macromolecules 2005, 38, 9028) and white-emitting OLEDs (J. Mater. Chem. 2006, 16, in press). The first part of their endeavors was featured by an article (Research News) in the monthly magazine (MaterialsToday, December, 2005), while the second was nominated as the Hot Article of that journal. Finally, in recognizing his outstanding contribution in this fast growing OLEDs research area, he was invited to write (i) a feature article, which will be published on a WILEY-VCH book “Highly Efficient OLEDs with Phosphorescent Materials”, (ii) a Microreview Article (Eur. J. Inorg. Chem. 2006, 3319; SCI IF ~ 2.51) which was rated as the most download article in the period of August and September, as well as a (iii) a Concept Article on “Phosphorescent Dyes for OLEDs”, see: Chem. Eur. J. 2007, 13, 380. (SCI IF ~ 4.91). Luminescent Quantum Dots. Chi and Pi-Tai Chou’s have developed a conceptual photodynamic therapy (PDT) system with dual functions. Firstly, it has a high enough emission from the luminescent CdSe/ZnS quantum dot for use in medical imaging. Secondly, the iridium phosphorescent complexes are positioned in a way that enables them to sensitize oxygen molecules to produce a toxic singlet oxygen, on exposure to light as an alternative method for destroying cancer cells (Chem. Commun. 2006, 615). This work was cited by the RSC Publishing “Chemical Technology” as the application highlights “Hot-Article” on February 15, 2006. From January to April, 2006, this article was amongst the top ten accessed on the web from the online version of Chemical Communications

近期论文

查看导师最新文章 （温馨提示：请注意重名现象，建议点开原文通过作者单位确认）

1.Wu, K.-L.; Ku, W.-P.; Wang, S.-W.; Yella, A.; Chi, Y.; Liu, S.-H.; Chou, P.-T.; Nazeeruddin, M. K.; Grätzel, M.;"Thiocyanate-free Ru(II) Sensitizers with a 4,4'-Dicarboxyvinyl-2,2'-Bipyridine Anchor for Dye-Sensitized Solar Cells"Adv. Funct. Mater.2013, 23, 2285. 2.Zhang, F. S.;Wang, L.; Chang, S.-H.; Huang, K.-L.; Chi, Y.; Hung, W.-Y.; Chen, C.-M.; Lee, G.-H.; Chou, P.-T.;"Phosphorescent Ir(III) complexes with both cyclometalate chromophores and phosphinesilanolate ancillary: concurrent conversion of organosilane to silanolate"Dalton Trans. 2013, 42, 7111. 3.Wu, K.-L.; Ku, W.-P.; Clifford, J. N.; Palomares, E.; Shu-Te Ho, S.-T.; Chi, Y.; Liu, S.-H.; Chou, P.-T.; Nazeeruddin, M.K.; Grätzel, M.; "Harnessing the Open-Circuit Voltage via A New Series of Ru(II) Sensitizers Bearing (iso-)Quinolinyl Pyrazolate Ancillaries"Energy Environ. Sci. 2013, 6, 859. 4.Chang,C.-H.; Ho,C.-L.; Chang, Y.-S.; Lien,I.-C.; Lin, C.-H.; Yang, Y.-W.; Liao,J.-L.; Chi, Y.; "Blue-Emitting Ir(III) Phosphors with 2-Pyridyl Triazolate Chromophores and Fabrication of Sky Blue and White-Emitting OLEDs"J. Mater. Chem. C. 2013, 1, 2639. 5.Chang, S.-H.;Chang, C.-F.;Liao, J.-L.; Chi, Y.; Zhou, D.-Y.; Liao, L.-S.; Jiang, T.-Y.; Chou, T.-P.; Li, E. Y.; Lee, G.-H.; Kuo, T.-Y.;Chou, P.-T.;"Emissive Osmium(II) Complexes with Tetradentate Bis(pyridyl pyrazolate) Chelates"Inorg. Chem. 2013, 52, 5867. 6.Wang, S.-W.; Wu, K.-L.; Ghadiri, E.; Lobello, M. G.; Ho, S.-T.; Chi,Y.; Moser,J.-E.;De Angelis, F.; Grätzel, M.; Nazeeruddin, M. K.;"Engineering of thiocyanate-free Ru(II) sensitizers for high efficiency dye-sensitized solar cells"Chem. Sci. 2013, 4, 2423. 7.Yeh, H.-H.; Ho, S.-T.; Chi, Y.; Clifford, J. N.; Palomares,E.; Liu,S.-H.; Chou, P.-T.; "Ru(II) sensitizers bearing dianionic biazolate ancillaries: ligand synergy for high performance dye sensitized solar cells" J. Mater. Chem. A. 2013, 1, 7681. 8.Hu, F.-C.; Wang, S.-W.; Planells, M.; Robertson, N.; Padhy, H.; Du, B.-S.; Chi, Y.; Yang, P.-F.; Lin, H.-W.; Lee, G.-H.; Chou, P.-T.;"Design of Os(II) based sensitizers for dye-sensitized solar cells; assessing the influence of heterocyclic ancillaries" ChemSusChem2013, 6, 1366. 9.Chang,C.-H.; Wu, Z.-J.; Chiu, C.-H.; Liang, Y.-H.;Tsai, Y.-S.; Liao, J.-L.; Chi, Y.; Hsieh, H.-Y.; Kuo, T.-Y.; Lee, G.-H.; Pan, H.-A.; Chou, P.-T.; Lin, J.-S.; Tseng, M.-R.; "A New Class of Sky blue-Emitting Ir(III) PhosphorsAssembled Using Fluorine-free Pyridyl Pyrimidine Cyclometalates; Application toward High Performance Sky blue- and White-Emitting OLEDs"ACS Appl. Mater. Int.2013, 5, 7341. 10.Huang, L.-M.; Tu, G.-M.; Chi, Y.; Hung, W.-Y.; Song, Y.-C.; Tseng, M.-R.; Chou, P.-T.; Lee, G.-H.; Wong, K.-T.; Cheng, S.-H.; Tsai, W.-S.;"Mechanoluminescent and efficient white OLEDs for Pt(ii) phosphors bearing spatially encumbered pyridinyl pyrazolate chelates"J. Mater. Chem. C. 2013, 1, 7582. 11.Chang, Y.-F.; Chiu, Y.-C.; Chang, H.-W.; Wang, Y.-S.; Shih, Y.-L.; Wu, C.-H.; Liu, Y.-L.; Lin, Y.-S.; Meng, H.-F.; Chi, Y.; Huang, H.-L.; Tseng, M.-R.; Lin, H.-W.; Zan, H.-W.; Horng, S.-F.; Juang, J.-Y.;"Interface and thickness tuning for blade coated small-molecule organic light-emitting diodes with high power efficiency"J. Appl. Phys. 2013, 114, 123101. 12.Moehl, T.; Tsao, H. N.; Wu, K.-L.; Hsu, H.-C.; Chi, Y.; Ronca, E.; De Angelis, F.; Nazeeruddin, M. K.; Grätzel, M.;"High Open Circuit Voltages: Evidence for a Sensitizer-Induced TiO2 Conduction Band Shift in Ru(II)-Dye Sensitized Solar Cells"Chem. Mater. 2013, 25, 4497. 13.Chou, C.-C.; Hu, F.-C.; Yeh, H.-H.; Wu, H.-P.; Chi, Y.*; Clifford, J. N.*; Palomares, E.; Liu, S.-H.; Chou, P.-T.*; Lee, G.-H.;"Highly Efficient Dye-Sensitized Solar Cells based on Panchromatic Ruthenium Sensitizers with Novel Quinolinyl-bipyridine Anchors"Angew. Chem. Int. Ed. 2014, 53, 178. 14.Tsai, Y.-T.; Chen, C.-Y.; Chen, L.-Y.; Liu, S.-H.; Wu, C.-C.*; Chi, Y.; Chen, S. H.; Hsu, H.-F.; Lee, J.-J.; "Analyzing nanostructures in mesogenic host–guest systems for polarized phosphorescence"Org. Electron.2014, 15, 311. 15.Fan, C.-C.; Huang, M.-H.; Lin, W.-C.; Lin, H.-W.*; Chi, Y.; Meng, H.-F.; Chao, T.-C.; Tseng, M.-R. "Single-emission-layer white organic light-emitting devices: Chromaticity and colour-rendering consideration" Org. Electron.2014, 15, 517. 16.Lobello, M. G.; Wu, K.-L.; Reddy, M. A.; Marotta, G.; Grätzel, M.; Nazeeruddin, M. K.; Chi, Y.; Chandrasekharam, M.*; Vitillaro, G.; De Angelis, F.*; "Engineering of Ru(ii) dyes for interfacial and light-harvesting optimization"Dalton Trans.2014, 43, 2726. 17.Hewat, T.; McDonald, S.; Lee, J.; Rahman, M.; Cameron, P.*; Hu, F.-C.; Chi, Y.*; Yellowlees, L. J.; Robertson, N.*; "Varying numbers and positions of carboxylate groups on Ru dyes for dye-sensitized solar cells: uptake on TiO2, cell performance and cell stability"RSC Adv. 2014, 4, 10165. 18.Hu, F.-C.; Wang, S.-W.; Chi, Y.*; Robertson, N.*; Hewat, T.; Hu, Y.; Liu, S.-H.; Chou, P.-T.*; Yang, P.-F.; Lin, H.-W.;"Geometrical Isomerism of Ru(II) DSC Sensitizers and Effects on Photophysical Properties and Device Performances"ChemPhysChem2014, 15, 1207. 19.Chou, C.-C.; Chen, P.-H.; Hu, F.-C.; Chi, Y.*; Ho, S.-T.; Kai, J.-J.*; Liu, S.-H.; Chou, P.-T.*;"Structural Tuning of Ancillary Chelate in Tri-carboxyterpyridine Ru(II) Sensitizers for Dye Sensitized Solar Cells"J. Mater. Chem. A2014, 2, 5418. 20.Jou, J.-H.*; Chou, K.-Y.; Yang, F.-C.; Agrawal, A.; Chen, S.-Z.; Tseng, J.-R.; Lin, C.-C.; Chen, P.-W.; Wong, K.-T.; Chi, Y.; "A universal, easy-to-apply light-quality index based on natural light spectrum resemblance"Appl. Phys. Lett.2014, 104, 203304. 21.Wu, K.-L.; Clifford,J. N.; Wang, S.-W.; Aswani, Y.; Palomares, E.; Lobello, M. G.; Mosconi, E.; De Angelis, F.*; Ku, W.-P.; Chi, Y.*; Nazeeruddin, M. K.*; Grätzel. M.;"Thiocyanate-Free Ru(II) Sensitizers for Dye-Sensitized Solar Cells Based on the Cobalt Redox Couples" ChemSusChem2014, 7, 2930. 22.Liao, J.-L.; Chi, Y.*;Su, Y.-D.; Huang, H.-X.; Chang, C.-H.*; Liu, S.-H.; Lee, G.-H.; Chou, P.-T.*; "Os(II) Metal Phosphors Bearing Tridentate 2,6-Di(pyrazol-3-yl)pyridine Chelate; Synthetic Design, Characterization and Application in OLED Fabrications"J. Mater. Chem. C2014, 2, 6269. 23.Chou, C.-C.; Hu, F.-C.; Wu, K.-L.; Chi, Y.*; Liu, S.-H.; Lee, G.-H.; Chou, P.-T.*; "4,4',5,5'-Tetracarboxy-2,2'-Bipyridine Ru(II) Sensitizers for Dye-Sensitized Solar Cells"Inorg. Chem.2014, 53, 8593. 24.Liao, J.-L.; Chi, Y.*;Liu, S.-H.; Lee, G.-H.; Chou, P.-T.*; Huang, H.-X.; Su, Y.-D.; Chang, C-H.*; Lin, J.-S.; Tseng, M.-R.;"Os(II) Phosphors with Near-Infrared Emission Induced by Ligand-to-Ligand Charge Transfer Transition"Inorg. Chem.2014, 53, 9366. 25.Chi, Y.*; Tong, B.; Chou, P.-T.*; "Metal Complexes with Pyridyl Azolates: Design, Preparation and Applications"Coord. Chem. Rev.2014, 281, 1-25. 26.Wang, S.-W.; Chou, C.-C.; Hu, F.-C.; Wu, K.-L.; Chi, Y.*; Clifford, J. N.; Palomares, E. J.; Liu, S.-H.; Chou, P.-T.*; Wei, T. C.*; Hsiao, T. Y.;"Panchromatic Ru(II) Sensitizers Bearing Single Thiocyanate for High Efficiency Dye Sensitized Solar cells"J. Mater. Chem. A2014, 2, 17618. 27.Wu, K.-L.; Hu, Y.; Chao, C.-T.; Yang, Y.-W.; Hsiao, T.-Y.; Robertson, N.*; Chi, Y.*;"Dye Sensitized Solar Cells with Cobalt and Iodine-Based Electrolyte: The Role of Thiocyanate-Free Ruthenium Sensitizers"J. Mater. Chem. A2014, 2, 19556. 28.Li, Y.-T. E.*; Jiang, T.-Y.; Chi, Y.; Chou, P.-T.*;"Semi-quantitative assessment of the intersystem crossing rate: an extension of the El-Sayed rule to the emissive transition metal complexes"Phys. Chem. Chem. Phys.2014, 16, 26184. 29.Chi, Y.*; Wu, K.-L.; Wei, T. C.; "Ruthenium and Osmium Complexes Bearing Functional Azolate Chelate for Dye-Sensitized Solar Cells"Chem. Asian J.2015, 10, 1098-1115. 30.Lin, C.-H.; Liao, J.-L.; Wu, Y.-S.; Liao, K.-Y.; Chi, Y.*; Chen, C.-L.; Lee, G.-H.; Chou, P.-T.*; "New Insight into the Chemistry of Iridium(III) Complexes Bearing Phenyl Phenylphosphonite Cyclometalate and Chelating Pyridyl Triazolate: The Excited-State Proton Transfer Tautomerism via Inter-ligand PO-H∙∙∙N Hydrogen Bond"Dalton Trans.2015, 44, 8406-8418. 31.Ku, H.-Y.; Tong, B.; Chi, Y.*; Kao, H.-C.; Yeh, C.-C.; Chang, C.-H.*; Lee, G.-H.;"Luminescent Pt(II) Complexes Bearing Dual Isoquinolinyl Pyrazolates: Fundamentals and Applications"Dalton Trans.2015, 44, 8552-8563. 32.Huang, M.-H.; Lin, W.-C.; Fan, C.-C.; Wang, Y.-S.; Lin, H.-W.; Liao, J.-L.; Lin, C.-H.; Chi, Y.; "Tunable chromaticity stability in solution-processed organic light emitting devices" Org. Electron.2015, 20, 36-42. 33.Tong, B.; Ku, H. Y.; Chen, I. J.; Chi, Y.; Kao, H.-C.; Yeh, C.-C.; Chang, C.-H.; Liun, S.-H.; Lee, G.-H.; Chou, P.-T.; "Heteroleptic Ir(III) Phosphors with Bis-Tridentate Chelating Architecture for High Efficiency OLEDs"J. Mater. Chem. C2015, 3, 3460-3471. 34.Liao, K.-Y.; Hsu, C.-W.; Chi, Y.; Hsu, M.-K.; Wu, S.-W.; Chang, C.-H.; Liu, S.-H.; Lee, G.-H.; Chou, P.-T.; Hu, Y.; Robertson, N.; "Pt(II) Metal Complexes Tailored with a Newly Designed Spiro-Arranged Tetradentate Ligand; Harnessing of Charge-Transfer Phosphorescence and Fabrication of Sky Blue and White OLEDs"Inorg. Chem.2015, 54, 4029-4038. 35.Liao, J.-L.; Chi, Y.; Yeh, C.-C.; Kao, H.-C.; Chang, C.-H.; Fox, M. A.; Low, P.; Lee, G.-H.; "Near Infrared-Emitting Tris-Bidentate Os(II) Phosphors: Control of Excited State Characters and Fabrication of OLEDs" J. Mater. Chem. C2015, 3, 4910-4920. 36.Duan, T.; Chang, T.-K.; Chi, Y.; Wang, J.-Y.; Chen, Z.-N.; Hung, W.-Y.; Chen, C.-H.; Lee, G.-H.; "Blue-Emitting Heteroleptic Ir(III) Phosphors with Functional 2,3'-Bipyridine or 2-(Pyrimidin-5-yl)pyridine Cyclometalates" Dalton Trans.2015, 44, 14613-14624. 37.Chang, T.-K.; Li, H.; Chen, K.-T.; Tsai, Y.-C.; Chi, Y.; Hsiao, T.-Y.; Kai, J.-J.; "Substituent Effect of Ru(ii)-Based Sensitizers Bearing a Terpyridine Anchor and a Pyridyl Azolate Ancillary for Dye Sensitized Solar Cells" J. Mater. Chem. A2015, 3, 18422-18431. 38.Li, M.-H.; Hsu, C.-W.; Shen, P.-S.; Cheng, H.-M.; Chi, Y.; Chen, P.; Guo, T.-F.; "Novel spiro-based hole transporting materials for efficient perovskite solar cells" Chem. Commun.2015, 51, 15518-15521. 39.Hsu, C.-W.; Zhao, Y.; Yeh, H.-H.; Lu, C.-W.; Fan, C.; Hu, Y.; Robertson, N.; Lee, G.-H.; Sun, X.; Chi, Y.; "Efficient Pt(II) Emitters Assembled from Neutral Bipyridine and Dianionic Bipyrazolate: Designs, Photophysical Characterizations and Fabrication of Non-doped OLEDs"J. Mater. Chem. C2015, 3, 10837-10847. 40.Liao, J.-L.; Chi, Y.; Sie, Z.-T.; Ku, C.-H.; Chang, C.-H.; Fox, M. A.; Low, P. J.; Tseng, M.-R.; Lee, G.-H. "Ir(III)-Based Phosphors with Bipyrazolate Ancillaries; Rational Design, Photophysics, and Applications in Organic Light-Emitting Diodes" Inorg. Chem.2015, 54, 10811-10821. 41.Duan, T.; Hsiao, T.-Y.; Chi, Y.; Chen, X.; He, Y.; Zhong, C. "End-capped “thiophene-free” organic dye for dye-sensitized solar cell: Optimized donor, broadened spectra and enhanced open-circuit voltage" Dyes Pigm.2016, 124, 45-52. 42.Shiu, Y.-J.; Cheng, Y.-C.; Tsai, W.-L.; Wu, C.-C.; Chao, C.-T.; Lu, C.-W.; Chi, Y.; Chen, Y.-T.; Liu, S.-H.; Chou, P.-T. "Pyridyl Pyrrolide Boron Complexes: The Facile Generation of Thermally Activated Delayed Fluorescence and Preparation of Organic Light-Emitting Diodes" Angew. Chem. Int. Ed.2016, 55, 3017-3021. 43.Kim, K.-H.; Liao, J.-L.; Lee, S. W.; Sim, B.; Moon, C.-K.; Lee, G.-H.; Kim, H. J.; Chi, Y.; Kim, J.-J.; "Crystal Organic Light-Emitting Diodes with Perfectly Oriented Non-Doped Pt-Based Emitting Layer" Adv. Mater.2016, 28, 2526-2532. 44.Kuei, C.-Y.; Tsai, W.-L.; Tong, B.; Jiao, M.; Lee, W.-K.; Chi, Y.; Wu, C.-C.; Liu, S.-H.; Lee, G.-H.; Chou, P.-T.; "Bis-tridentate Ir(III) Complexes with Nearly Unitary RGB Phosphorescence and Organic Light-Emitting Diodes with External Quantum Efficiency Exceeding 31%" Adv. Mater.2016, 28, 2795-2800. 45.Lin, J.; Chau, N.-Y.; Liao, J.-L.; Wong, W.-Y.; Lu, C.-Y.; Sie, Z.-T.; Chang, C.-H.; Fox, M. A.; Low, P. J.; Lee, G.-H.; Chi, Y.; "Bis-Tridentate Iridium(III) Phosphors Bearing Functional 2-Phenyl-6-(imidazol-2-ylidene)pyridine and 2-(Pyrazol-3-yl)-6-phenylpyridine Chelates for Efficient OLEDs" Organometallics2016, 35, 1813-1824. 46.Liao, J.-L.; Chi, Y.; Wang, J.-Y.; Chen, Z.-N.; Tsai, Z.-H.; Hung, W.-Y.; Tseng, M.-R.; Lee, G.-H.; "Pt(II) Phosphors Featuring Both Dicarbene and Functional Biazolate Chelates: Synthesis, Luminescent Properties, and Applications in Organic Light-Emitting Diodes" Inorg. Chem., 2016, 55, 6394-6404. 47.Wu, K.-L.; Huckaba, A. J.; Clifford, J. N.; Yang, Y.-W.; Yella, A.; Palomares, E.; Grätzel, M.; Chi, Y.; Nazeeruddin, M. K.; "Molecularly Engineered Ru(II) Sensitizers Compatible with Cobalt(II/III) Redox Mediators for Dye-Sensitized Solar Cells"Inorg. Chem., 2016, 55, 7388-7395. 48.Xu, L.-J.; Zeng, X.-C.; Wang, J.-Y.; Zhang, L.-Y.; Chi, Y.*; Chen, Z.-N.*; "Phosphorescent PtAu2 Complexes with Differently Positioned Carbazole-Acetylide Ligands for Solution-Processed Organic Light-Emitting Diodes with External Quantum Efficiencies of over 20%" ACS Appl. Mater. Int., 2016, 8, 20251-20257. 49.Lu, C.-W.; Wang, Y.; Chi, Y.*; "Metal Complexes with Azolate-Functionalized Multiden­tate Ligands: Tactical Designs and Optoelectronic Applications" Chem. Eur. J., 2016, 22, 17892-17908. 50.Kuei, C.-Y.; Liu, S.-H.; Chou, P.-T.*; Lee, G.-H.; Chi, Y.*; "Room Temperature Blue Phos­phorescence; A Combined Experimental and Theoretical Study on the Bis-tridentate Ir(III) Metal Complexes" Dalton Trans.2016, 45, 15364-15373. 51.Hsu, C. W.; Ly, K. T.; Lee, W.-K.; Wu, C.-C.*; Wu, L.-C.; Lee, J.-J.; Lin, T.-C.; Liu, S.-H.; Chou, P.-T.*; Lee, G.-H.; Chi, Y.* "Triboluminescence and Metal Phosphor for Organic Light-Emitting Diodes: Functional Pt(II) Complexes with Both 2-Pyridylimidazol-2-ylidene and Bipyrazolate Chelates"ACS Appl. Mater. Interfaces 2016, 8, 33888-33898. 52.Ly, K. T.; Chen-Cheng, R.-W.; Lin, H.-W.*; Shiau, Y.-J.; Liu, S.-H.; Chou, P.-T.*; Tsao, C.-S.; Huang, Y.-C.; Chi, Y.*; "Near-infrared organic light-emitting diodes with very high external quantum efficiency and radiance" Nat. Photon.2017, 11, 63-68. 53.Chi, Y.*; Chang, T.-K.; Ganesan, P.; Rajakannu, P.; "Emissive Bis-Tridentate Ir(III) Metal Complexes: Tactics, Photophysics and Applications" Coord. Chem. Rev.2017, 346, 91-100. 54.Tseng, C.-H.; Fox, M. A.*; Liao, J.-L.; Ku, C.-H.; Sie, Z.-T.; Chang, C.-H.*; Wang, J.-Y.; Chen, Z.-N.; Lee, G.-H.; Chi, Y.* "Luminescent Pt(II) Complexes Featuring Imidazolylidene-Pyridylidene and Dianionic Bipyrazolate: from Fundamentals to OLED Fabrications"J. Mater. Chem. C 2017, 5, 1420-1435. 55.Hsu, Y.-J.; Chen, Y.-T.; Lee, W.-K.; Wu, C.-C.*; Lin, T.-C.; Liun, S.-H.; Chou, P.-T.*; Lu, C.-W.; Cheng, I. C.; Lien, Y.-J.; Chi, Y.* "Efficient Thermally Activated Delayed Fluorescence of Functional Phenylpyridinato Boron Complexes and High Performance Organic Light-Emitting Diodes"J. Mater. Chem. C 2017, 5, 1452-1462. 56.Ganesan, P.; Ranganathan, R.; Chi, Y.*; Liu, X.-K.; Lee, C.-S.*; Liu, S.-H.; Lee, G.-H.; Lin, T.-C.; Chen, Y.-T.; Chou, P.-T.* "Functional Pyrimidine-based Thermally Activated Delay Fluorescence Emitters: Photophysics, Mechanochromism and Fabrication of Organic Light-Emitting Diodes"Chem. Eur. J. 2017, 23, 2858-2866. 57.Chen, C.-Y. et.al. "Performance Characterization of Dye-Sensitized Photovoltaics under Indoor Lighting."J. Phys. Chem. Lett. 2017, 8 (8), 1824-1830. 58.Chi, Y.*; Tsai, H.-Y.; Chen, Y.-K. "Pt(II) Complexes with Azolate-Containing Bidentate Chelate: Design, Photophysics and Application"J. Chinese Chem. Soc. 2017, 67, 574-588. 59.Wang, Y.; Zhu, Z.; Chueh, C.-C.; Jen, A. K.-Y.*; Chi, Y.* "Spiro-Phenylpyrazole-9,9’-Thioxanthene Analogues as Hole-transporting Materials for Efficient Planar Perovskite Solar Cells"Adv. Energy Mater. 2017, 7, 1700823. 60.Kuo, H.-H.; Chen, Y.-T.; Devereux, L. R.; Wu, C.-C.*; Fox, M. A.*; Kuei, C.-Y.; Chi, Y.*; Lee, G.-H. "Bis-Tridentate Ir(III) Metal Phosphors for Efficient Deep-Blue Organic Light-Emitting Diodes."Adv. Mater. 2017, 29, 1702464. 61.Wang, Y.; Su, T.-S.; Tsai, H.-Y.; Wei, T.-C.*; Chi, Y.* "Spiro-Phenylpyrazole/Fluorene as Hole-Transporting Material for Perovskite Solar Cells"Sci. Rep. 2017, 7, 7859. 62.Lien, Y.-J.; Lin, T.-C.; Yang, C.-C.; Chiang, Y.-C.; Chang, C.-H.; Liu, S.-H.; Chen, Y.-T.; Lee, G.-H.; Chou, P.-T.; Lu, C.-W.; Chi, Y. "First N-Borylated Emitters Displaying Highly Efficient Thermally Activated Delayed Fluorescence and High Performance OLEDs"ACS Appl. Mater. Interfaces 2017,9, 27090-27101. 63.Lin, J.; Wang, Y.; Gnanasekaran, P.; Chiang, Y.-C.; Yang, C.-C.; Chang, C.-H.; Liu, S.-H.; Lee, G.-H.; Chou, P.-T.; Chi, Y.; Liu, S.-W. "Unprecedented Homoleptic Bis-Tridentate Iridium(III) Phosphors: Facile, Scaled-Up Production, and Superior Chemical Stability"Adv. Funct. Mater. 2017, 27, 1702856. 64.Li, Y.-S.; Liao, J.-L.; Lin, K.-T.; Hung, W.-Y.; Liu, S.-H.; Lee, G.-H.; Chou, P.-T.; Chi, Y. "Sky Blue-Emitting Iridium(III) Complexes Bearing Nonplanar Tetradentate Chromophore and Bidentate Ancillary"Inorg. Chem. 2017,56, 10054-10060. 65.Chang, T.-K.; Chi, Y. "Bis-tridentate Ru(ii) sensitizers with a spatially encumbered 2,6-dipyrazolylpyridine ancillary ligand for dye-sensitized solar cells"RSC Adv. 2017,7, 42013-42023. 66.Sarma, M.; Tsai, W.-L.; Lee, W.-K.; Chi, Y.; Wu, C.-C.; Liu, S.-H.; Chou, P.-T.; Wong, K.-T. "Anomalously Long-Lasting Blue PhOLED Featuring Phenyl-Pyrimidine Cyclometalated Iridium Emitter"Chem 2017, 3, 461-476. 67.Chiang, C.-C.; Hung, C.-Y.; Chou, S.-W.; Shyue, J.-J.; Cheng, K.-Y.; Chang, P.-J.; Yang, Y.-Y.; Lin, C.-Y.; Chang, T.-K.; Chi, Y.; Chou, H.-L.; Chou, P.-T."PtCoFe Nanowire Cathodes Boost Short-Circuit Currents of Ru(II)-Based Dye-Sensitized Solar Cells to a Power Conversion Efficiency of 12.29%"Adv. Funct. Mater. 2018, 28, 1703282. 68.Liao, J.-L.; Devereux, L.-R.; Fox, M.-A.; Yang, C.-C.; Chiang, Y.-C.; Chang, C.-H.; Lee, G.-H.; Yun Chi, Y."Role of the Diphosphine Chelate in Emissive, Charge-Neutral Iridium(III) Complexes"Chem. Eur. J. 2018, 24, 624-635. Hydrocarbyl Ligands" In Comprehensive Organometallic Chemistry II; The Synthesis, Reactions 專利：(After 2013) 1.Chi, Y.; Hung, J.-Y.; Chou, P.-T.; Lin, C.-H.; “Phosphorescent transition metal complex having a facially arranged carbon-phosphorus-carbon (C^P^C) tridentate chelate and organic light emitting diode containing the same” 2013,U. S. Patent No. 8,415,030 B2 2.季昀、洪瑞意、周必泰、林政輝；"具有面構形碳－磷－碳（Ｃ^Ｐ^Ｃ）三牙螫合體的磷光過渡金屬錯合物及其有機發光二極體” 2013，中華民國專利，發明第I392721號。 3.季昀、洪瑞意、林政輝、周必泰、白宜玄、徐健維；"同時含有碳－磷輔助螯合體及發光螯合體的發光過渡金屬錯合物、其合成方法及磷光有機發光二極體” 2013，中華民國專利，發明第I403569號。. 4.Chi, Y.; Chou, C.-C.; Wu, K.-L.; “Heteroleptic, dual tridentate Ru(II) complexes as sensitizers for dye-sensitized solar cells”2013, U. S. Patent No. 8,507,679 B2. 5.Chi, Y.; Hung, J.-Y.; Lin, C.-H.; Chou, P.-T.; Pai, I-H.; Hsu, C.-W.; “Emissive transition-metal complexes with both carbon-phosphorus ancillary and chromophoric chelates, synthetic method of preparing the same and phosphorescent organic light emitting diode thereof “, 2013, U. S. Patent No. 8,557,988 B2. 6.季昀、張仕瀚、黃冠霖；"芳香基磷矽化合物及由該芳香基磷矽化合物所形成的銥錯合物" 2013，中華民國專利，發明公開號第TW201345917A號 7.Chi, Y.; Hsu, C.-W.; Ho, S.-T.; “2-phenyl-6-azolylpyridine-based ligand and group VIII transition metal complex”, 2013, U. S. Patent No. 8,580,961 B2. 8.Chi, Y.; Chang, S.-H.; Huang, K.-L.; "Phenylsilyl phosphine compound and iridium complex made from the same" U.S. Pat. Appl. Publ. 2013, US 20130303765 A1 20131114. 9.季昀、周俊誠、吳冠霖；"雜配、雙三芽釕錯合物以及敏化染料太陽能電池製備” 2013，中華民國專利，發明第I419878號。 10.季昀、陳凱倫、許惠筑、吳冠霖；"無硫氰酸根配基的光敏錯合物及敏化染料太陽能電池”2014，中華人民共和國專利，第CN102277007B號。 11.Chi, Y.; Chang, S.-H.; Huang, K.-L.; "Phenylsilyl phosphine compound and iridium complex made from the same" U.S. Pat. Appl. Publ. 2013, US 20130303765 A1 20131114. 12.季昀、陳凱倫、許惠筑、吳冠霖；"無硫氰酸根配基的光敏錯合物及敏化染料太陽能電池”2014，中華民國專利，發明第I428343號。 13.季昀、李承軒、楊深涵、吳欣蓓、吳冠霖、徐健維、張仕瀚；"衍生自4,4’-二酸-2,2’-雙吡啶之三牙配位子、金屬錯合物及其應用”2014，中華民國專利，發明第I429637號。 14.Chi, Y.; Hung, L.-M.; "Phosphorescent four-coordinated platinum (II) complex" 2014, U. S. Patent No. 8,722,885 B1. 15.Chi, Y.; Chen, K.; Hong, Y.-H.; Chou, P.-T.; Chen, B.-S.; “Panchromatic photosensitizers and dye-sensitized solar cell using the same”2014, U.S. Patent No.8,759,521 B2. 16..Chi, Y.; Hu, F.-C.; Wang, S.-W.; Ku, W.-P.; Chen, P.-H.; Yang, Y.-W.; "Six-coordinated ruthenium complex". 2014, U. S. Patent No. 8,779,134 B1. 17.Chi, Y.; Li, C.-X.; Yang, S.-H.; Wu, H.-P.; Wu, K.-L.; Hsu, C.-W.; Chang, S.-H. “4,4'-dicarboxy-2,2'-bipyridine derived tridentate ligand, metal complex containing the same, and application thereof”2014, U. S. Patent No. 8,822,818 B2. 18.季昀、胡發鈞、王聖爲、古宛平、陳珮樺、楊雅雯；"六配位釕錯合物”2014，中華民國專利，發明第I453210號。 19.季昀、葉秀炫、何恕德;"鹵烷基雙唑類化合物及第八族過渡金屬錯合物”2014，中華民國專利，發明第I457344號。 20.Chi, Y.; Yeh, H.-H.; Ho, S.-T.; Chang, S.-H.; "Bisazole-based compound and group VIII transition metal complex". 2014, U. S. Patent No. 8,889,872 B2. 21.季昀、周俊诚、吴冠霖；"雜配、雙三芽釕錯合物以及敏化染料太陽能電池製備" 2014，中華人民共和國專利，第CN102485731B號。 22.季昀、周俊誠、胡發鈞、王聖爲；”應用於高效率染料敏化太陽能電池的新型釕金屬錯合物” 2015，中華民國專利，發明第I469986號。 23.Chi, Y.; Liao, J.-L.; "Heteroleptic iridium complex bearing diazolate chelate" 2015, U. S. Patent No. 8,957,208 B1. 24.季昀、廖家翎；“含雙唑類配基的銥金屬錯合物"2015，中華民國專利，發明第I484020號。 25.季昀、蔡毓珊、廖家翎 、曾美榕、林晉聲; "有機金屬化合物、包含其之有機發光裝置及照明裝置”2015，中華民國專利，中華人民共和國專利，第CN104628785A號。 26.Chi, Y.; Yeh, H.-H.; "Luminescent platinum(II) complexes with biazolate chelates". 2015, U. S. Patent No. 9,040,702 B1. 27.季昀、葉秀炫; "雙唑類鉑金屬發光錯合物”2015，中華民國專利，發明第I498322號。 28.Chi, Y.; Chou, C.-C.; Hu, F.-C.; Wang, S.-W.; "Ruthenium complex for dye-sensitized solar cell". 2015, U. S. Patent No. 9,156,869 B2. 29.季昀、黃琍敏; "含環金屬碳-磷螯合基的藍色磷光鉑(II)錯合物”2015，中華民國專利，發明第I510479號。 30.季昀、徐健維、何恕德；"2-苯基-6-唑基吡啶系配基及由其所形成的第八族過渡金屬錯合物" 2015，中華人民共和國專利，第CN102731487B號 31.Chi, Y.; Tong, B.-H.; Duan, T.-N.; Ku, H.-Y.; Chen, I-J.; "Heteroleptic Ir(III) phosphors with bis-tridentate chelating architecture for high efficiency OLEDs". 2015, U. S. Patent No. 9,219,237 B1. 32.季昀、蔡毓珊、廖家翎 、曾美榕、林晉聲; "有機金屬化合物、包含其之有機發光裝置及照明裝置”2016，中華民國專利，發明第I523933號。 33.季昀、李承軒、楊深涵、吳欣蓓、吳冠霖、徐健維、張仕瀚；"衍生自4,4’-二酸-2,2’-雙吡啶之三牙配位子、金屬錯合物及其應用" 2016，中華人民共和國專利，第CN102731487B號。 34.季昀、童碧海、段泰男、古筱筠、陳以仁; "含雙(三牙配基)的銥金屬錯合物”2016，中華人民共和國專利，第CN105801627A號。 35.季昀、童碧海、段泰男、古筱筠、陳以仁; "含雙(三牙配基)的銥金屬錯合物”2016，中華民國專利，發明第I546309號。 36.季昀、童碧海、陳以仁、桂楚雲; "含雙卡賓暨吡唑配基之銥金屬磷光材料”2016，中華民國專利，發明第I546310號。 37.Tao, Y.; Carty, A. J.; Chi, Y.; Tung, Y.-L.; Chou, P.-T.; “Phosphorescent osmium and ruthenium complexes and uses thereof” 2016, Canada Patent No. CA2487118C. 38.Chi, Y.; Tong, B.-H.; Chen, I-J.; Kuei, C.-Y.; "Iridium (iii) based phosphors bearing pincer carbene and pyrazolyl chelates" U.S. Pat. Appl. Publ. 2016, US 20160355534 A1 20161208. 39.Chi, Y.; Hsu, C.-W.; Tseng, C.-H.; Liao, J.-L.; "Platinum complex having carbene fragment, oled using the same, and nitrogen-containing heterocyclic bidentate chelate having carbene unit" U.S. Pat. Appl. Publ. 2017, US 20170005279 A1 20170115. 40.季昀、許維哲、曾崇豪、廖家翎；"具碳烯结構的鉑錯合物及使用其的有機發光二極管" 2017，中華人民共和國專利，第CN106317122A號 41.Chi, Y.; Kuei, C.-Y.; "Iridium complexes and organic light-emitting diodes using the same". 2017, U. S. Patent No. 9,553,277 B2. 42.季昀、林駿、陳碧玉; "銥錯合物及含氮三牙配基”2017，中華民國專利，發明第I568725號。 43.季昀、崔培培; "鉑錯合物、有機發光二極體與可發出可見光或近紅外光的裝置”2017，中華民國專利，發明第I57601號。 44.季昀、葉秀炫；"雙唑類鉑金屬發光錯合物" 2017，中華人民共和國專利，第CN104761588B號。 45.季昀、拉賈卡努、納達; "鉑錯合物、有機發光二極體與可發出可見光或近紅外光的裝置”2017，中華民國專利，發明第I586662號。 46.Chi, Y.; Lin, J.; "Iridium complex, oled using the same, and nitrogen-containing tridentate ligand having carbene unit" U.S. Pat. Appl. Publ. 2017, US 20170194575 A1 20170706. 47.Chi, Y.; Ly, K. T.; "Platinum complex and oled using the same" U.S. Appl. Publ. 2017, US 20170194578 A1 20170706. 48.季昀、林駿; "鉑錯合物、使用其的有機發光二極管及具炭烯結構的含氮三牙配基”2017，中華民國專利，發明申請案號第TW201723143A號。 49.季昀、林駿; "鉑錯合物、使用其的有機發光二極管及具炭烯結構的含氮三牙配基”2017，中華人民共和國專利，第CN106928281A號。 50.季昀、施理健; "鉑錯合物及使用其的有機發光二極管”2017，中華人民共和國專利，第CN106928282A號。 51.季昀、許哲維、曾崇豪、廖家翎; "具碳烯結構的鉑錯合物及使用其的有機發光二極體”2017，中華民國專利，發明第I599568號。 52.季昀、林駿、陳碧玉; "銥錯合物及含氮三牙配基”2017，中華人民共和國專利，第CN107383105A號。 53.Chi, Y.; Lin, J.; Chen, P.-Y.; "Iridium complex and nitrogen-containing tridentate ligand" U.S. Pat. Appl. Publ. 2017, US 20170338426 A1 20171123. 54.Chi, Y.; "Platinum based oled emitter showing visible or near-infrared emission" U.S. Pat. Appl. Publ. 2017, US 20170352822 A1 20171207. 55.季昀、崔培培; "鉑錯合物、有機發光二極管與可發出可見光或近紅外光的裝置”2017，中華人民共和國專利，第CN107474071A號。 56.Chi, Y.; Tsai, Y.-S.; Liao, J.-L.; Tseng, M.-R.; Lin, J.-S.; "Organometallic compound, organic light-emitting device, and lighting device employing the same" 2018, U. S. Patent No. 9,865,824 B2. 57.季昀、施理健; "鉑錯合物及使用其的有機發光二極體”2018，中華民國專利，發明第I611004號。 58.季昀、王漾、蔡涵諺; "具有類四面體構形的有機化合物”2018，中華民國專利，發明申請案號第I614253號。 59.Chi, Y.; Wang, Y.; Tsai, H.-Y.; "Organic compound with tetrahedral-like geometry" 2018, U. S. Patent No. 9,896,467 B1.