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Photoinduced Radical Addition Process Enabled Deoxygenative Hydroacylation and Hydrophosphonylation of Carbonyls Xiaoqiang Wu, Jun Zhou, Zihao Hu, and Tao XU* Chem Catalysis 2024, 4, accepted.
Formal Deoxygenative Cross-Coupling of Aldehydes to Ketones through α-Haloboronates: A Route to Deoxygenative Hydroacylation of Aldehydes Zihao Hu, Wanqi Zhang, and Tao XU* Chinese Journal of Chemistry 2023, 41, 3593-3597.
Nickel-Catalyzed Regio- and Enantioselective Borylative Coupling of Terminal Alkenes with Alkyl Halides (Invited Highlight) Hepan Wang, and Tao XU* Chinese Journal of Organic Chemistry 2023, 43, 3328-3330.
Synthesis of Chiral Allylic Phosphonates via Asymmetric Reductive Cross-Coupling of α-Bromophosphonates and Vinyl Bromides Hepan Wang, Xinxuan Li, and Tao XU* Science China Chemistry 2023, 66, 2621-2625.
Cross-Coupling of Aldehydes and α-Bromophosphonates to Modularly Access α-Substituted-β-Ketophosphonates Under Dual Nickel/Photoredox Catalysis Xinxuan Li‡, Hepan Wang‡, and Tao XU* (‡equal contribution) Organic Chemistry Frontiers 2023, 10, 3061-3066.
Selectively Tunable Synthesis of α-Trifluoromethyl Ketones Pan Zhou, Shanya Lu, Xiaoqiang Wu, Wei Zhong*, and Tao XU* Organic Letters 2023, 25, 2344-2348.
Enantioconvergent Reductive C(sp)-C(sp3) Cross-Coupling to Access Chiral α-Alkynyl Phosphonates Under Dual Nickel/Photoredox Catalysis (Hot Paper) Hepan Wang, Xiaoqiang Wu, and Tao XU* Angewandte Chemie International Edition 2023, 62, e202218299.
Recent Advances on The Preparation and Asymmetric Transformation of α-Haloboron Compounds Dong Wang, and Tao XU* Synlett 2023, 34, 2085-2096.
Enantioselective C(sp3)-C(sp3) Reductive Cross-Electrophile Coupling of Unactivated Alkyl Halides with α-Chloroboronates via Dual Nickel/Photoredox Catalysis Jun Zhou, Dong Wang, Wenhao Xu, Zihao Hu, and Tao XU* Journal of the American Chemical Society 2023, 145, 2081-2087.
Deoxygenative Alkylboration of Aldehydes to Synthesize Versatile Secondary α,α-Dialkyl Boronates (Synpacts) Wenhao Xu, Liejin Zhou*, and Tao XU* Synlett 2023, 34, 1075-1078.
Deoxygenative Haloboration and Enantioselective Chloroboration of Carbonyls Dong Wang, Jun Zhou, Zihao Hu, and Tao XU* Journal of the American Chemical Society 2022, 144, 22870-22876.
Deoxygenative Arylboration of Aldehydes via Copper and Nickel/Photoredox Catalysis Purui Zheng, Wenhao Xu, Hepan Wang, Dong Wang, Xiaoqiang Wu, and Tao XU* ACS Catalysis 2022, 12, 14926-14933.
Modular and Fast Synthesis of Versatile Secondary α,α-Dialkyl Boronates via Deoxygenative Alkylboration of Aldehydes Wenhao Xu, Purui Zheng, Jun Zhou, Zihao Hu, and Tao XU* Angewandte Chemie International Edition 2022, 61, e202214213.
Molybdenum-Catalyzed Cross-Coupling of Benzyl Alcohols: Direct C-OH Bond Transformation via [2+2]-Type Addition and Elimination Pan Zhou, Yuqiang Li*, and Tao XU* Organic Letters 2022, 24, 4218-4223.
Modular and Facile Access to Chiral α-Aryl Phosphonates via Dual Nickel- and Photoredox-catalyzed Reductive Cross-Coupling Hepan Wang, Purui Zheng, Xiaoqiang Wu, Yuqiang Li*, and Tao XU* Journal of the American Chemical Society 2022, 144, 3989-3997.
A Pivotal Role of Chloride Ion on Nickel-Catalyzed Reductive Cross-Coupling to Access Chiral Perfluoroalkylated Boronate Esters Dong Wang, and Tao XU* ACS Catalysis 2021, 11, 12469-12475.
Dual Nickel- and Photoredox-Catalyzed Reductive Cross-Coupling to Access Chiral Trifluoromethylated Alkanes Pan Zhou, Xinxuan Li, Dong Wang, and Tao XU* Organic Letters 2021, 23, 4683-4687.
Reductive Cross-Coupling to Access C-N Bond from Aryl Halides and Diazoesters under Dual Nickel/Photoredox-Catalyzed Conditions Xiaoqiang Wu, Purui Zheng, Wanfang Li*, and Tao XU* Organic Chemistry Frontiers 2021, 8, 4118-4123.
Dual Ni/Photoredox-catalyzed asymmetric cross-coupling to access chiral benzylic boronic esters Purui Zheng, Pan Zhou, Dong Wang, Wenhao Xu, Hepan Wang, and Tao XU* Nature Communications 2021, 12, 1646.
Dual Nickel- and Photoredox-Catalyzed Reductive Cross-Coupling of Aryl Halides with Dichloromethane via a radical process Wenhao Xu‡, Purui Zheng‡, and Tao XU* (‡equal contribution) Organic Letters 2020, 22, 8643-8647.
A Novel Bisoxazoline-Imidazolium Salt in Ytterbium-Catalyzed Asymmetric Reduction of Ketone Yujie Zhai, Wenhao Xu, Dong Wang, Purui Zheng, Xiaoming Zhao*, and Tao XU* European Journal of Organic Chemistry 2020, 2020, 5025-5028.
Nickel-catalyzed Intramolecular Desymmetrization Addition of Aryl Halides to 1,3-Diketones Pan Zhou, and Tao XU* Chemical Communications 2020, 56, 8194-8197.
Enantioselective Copper-Catalyzed Desymmetrization of 1,3-Diketones Involving Borylation of Styrenes Purui Zheng, Xiaoyu Han, Jiao Hu, Xiaoming Zhao*, and Tao XU* Organic Letters 2019, 21, 6040-6044.
Palladium-Catalyzed Cross-Coupling of gem-Bis(boronates) with Aryl Halides: An Alternative To Access Quaternary α-Aryl Aldehydes Purui Zheng, Yujie Zhai, Xiaoming Zhao*, and Tao XU* Organic Letters 2019, 21, 393-396.
Difunctionalization of ketones via gem-bis(boronates) to synthesize quaternary carbon with high selectivity Purui Zheng, Yujie Zhai, Xiaoming Zhao*, and Tao XU* Chemical Communications 2018, 54, 13375-13378.
A Water-bridged H-bonding network contributes to the catalysis of a SAM-dependent C-methyltransferase HcgC Liping Bai#, Tristan Wagner#, Tao Xu, Xile Hu, Ulrich Ermler, and Seigo Shima* Angewandte Chemie International Edition 2017, 56, 10806-10809.
Towards artificial methanogenesis: biosynthesis of the [Fe]-hydrogenase cofactor and characterization of the semi-synthetic hydrogenase Liping Bai, Takashi Fujishiro, Gangfeng Huang, Jürgen Koch, Atsushi Takabayashi, Makio Yokono, Ayumi Tanka, Tao Xu, Xile Hu, Ulrich Ermler, and Seigo Shima* Faraday Discussion 2017, 198, 37-58.
Nickel pincer model of the active site of lactate racemase involves ligand participation in hydride transfer Tao Xu, Matthew D. Wodrich, Rosario Scopelliti, Clemence Corminboeuf, and Xile Hu* Proceedings of the National Academy of Sciences USA 2017, 114, 1242-1245.
Identification of HcgC as SAM-Dependent Pyridinol Methyltransferase in [Fe]- Hydrogenase Cofactor Biosynthesis Takashi Fujishiro#, Liping Bai#, Tao Xu, Xiulan Xie, Michael Schick, Jörg Kahnt, Michael Rother, Xile Hu, Ulrich Ermler, and Seigo Shima* Angewandte Chemie International Edition 2016, 55, 9648-9651.
A Functional Model of [Fe]-Hydrogenase Tao Xu, Chih-Juo Madeline Yin, Matthew D. Wodrich, Simona Mazza, Katherine M. Schultz, Rosario Scopelliti, and Xile Hu* Journal of the American Chemical Society 2016, 138, 3270-3273.
Mechanistic Investigation on the Silver-Catalyzed Oxidative Intramolecular Aminofluorination of Alkynes Tao Xu, Yichen Wu, Zheliang Yuan, Hairong Guan, and Guosheng Liu* Organometallics 2016, 35, 1347-1349.
A Novel Nickel Pincer Complex in the Active Site of Lactate Racemase Tao Xu, Gerald Bauer, and Xile Hu* ChemBioChem 2016, 17, 31-32.
Reconstitution of [Fe]-hydrogenase using model complexes Seigo Shima*, Dafa Chen, Tao Xu, Matthew D. Wodrich, Takashi Fujishiro, Katherine M. Schultz, Jörg Kahnt, Kenichi Ataka, and Xile Hu* Nature Chemistry 2015, 7, 995-1002.
Abnormal Mesoionic Carbene Silver Complex: Synthesis, Reactivity, and Mechanistic Insight on Oxidative Fluorination Qilun Liu, Zheliang Yuan, Hao-yang Wang*, Yang Li, Yichen Wu, Tao Xu, Xuebing Leng, Pinhong Chen, Yinlong Guo, Zhenyang Lin*, and Guosheng Liu* ACS catalysis 2015, 5, 6732-6737.
Hydrogen-activating models of hydrogenases Tao Xu, Dafa Chen, and Xile Hu* Coordination Chemistry Reviews 2015, 303, 32-41.
Copper-Catalyzed 1,2-Addition of α-Carbonyl Iodides to Alkynes Tao Xu, and Xile Hu* Angewandte Chemie International Edition 2015, 54, 1307-1311.
Iron-catalyzed 1,2-Addition of Perfluoroalkyl Iodides to Alkynes and Alkenes Tao Xu, Chi Wai Cheung, and Xile Hu* Angewandte Chemie International Edition 2014, 53, 4910-4914.
Ag(I)-Catalyzed Aminofluorination of Alkynes: Efficient Synthesis of 4-Fluoroisoquinolines and 4‑Fluoropyrrolo[α]isoquinolines Tao Xu, and Guosheng Liu* Organic Letters 2012, 14, 5416-5419.
Silver-Catalyzed Fluorination Reactions Tao Xu, and Guosheng Liu* Synlett 2012, 23, 955-958.
Silver-Catalyzed Intramolecular Aminofluorination of Activated Allenes Tao Xu, Xin Mu, Haihui Peng, and Guosheng Liu* Angewandte Chemie International Edition 2011, 50, 8176-8179.
Palladium-Catalyzed Intramolecular Aminofluorination of Styrenes Tao Xu, Shuifa Qiu, and Guosheng Liu* Chinese Journal of Chemistry 2011, 29, 2785-2790.
Palladium-catalyzed inter- and intramolecular hydroamination of styrenes coupled with alcohol oxidation using N-fluorobenzenesulfonimide as the oxidant Tao Xu, Shifa Qiu, and Guosheng Liu* Journal of Organometallic Chemistry 2011, 696, 46-49.
Palladium-Catalyzed Intermolecular Aminofluorination of Styrenes Shifa Qiu, Tao Xu, Juan Zhou, Yinlong Guo, and Guosheng Liu* Journal of the American Chemical Society 2010, 132, 2856-2857.
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