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成果及论文

43. Changhao Niu, Zheng Zhang, Qi Li, Zengrui Cheng, Ning Jiao*, Chun Zhang*,  Selective Ring-Opening Amination of Isochromans and Tetrahydroisoquinolines. Angew. Chem. Int. Ed. 2024, e202401318. link


42. Qitao Guan, Zhen Shen, Yiqiang Tian, Genping Huang*, Chun Zhang*,  Ni-catalyzed Highly regio- and stereo-selective diborylative cyclization of 1,6-enynes with diboron reagent, Sci. China Chem. 2024, 67, 981-989. link


41. Changhao Niu, Qi Li, Chun Zhang*,  The boration reaction using B2pai2. Tetrahedron, 2023, 137, 133381. (review paper) link


40. Xinyu Liu, Juanjuan Wu, Chun Zhang*, Copper and Palladium Co-catalyzed Defluorinative Coupling of gem-Difluoroalkenes and Acyl Chloride, Org. Lett. 2023, 25, 1564-1568. link


39. Huanhuan Cui, Changhao Niu, Mimi Xing, Chun Zhang*, NiH-catalyzed C(sp3)–Si coupling of alkenes with vinyl chlorosilanes. Chem. Commun., 2022, 58, 11989-11992. link


38. Chenchen Zou, Chun Zhang*, Iron-catalyzed regioselective protoboration of alkenes on N-heterocycles, Org. Chem. Front., 2022, 9, 6325-6330. link


37. Chenchen Zouǂ, Hongli Wuǂ, Yuqi Jiǂ, Penglin Zhangǂ, Huanhuan Cui, Genping Huang*, Chun Zhang*, Palladium-catalyzed Intramolecular Dehydrogenative Arylboration of Alkenes. Chin. J. Chem. 2022, 40, 2437-2444. (ǂcontributed equally) link


36. Jiapan Niu, Hongli Wu, Changhao Niu, Genping Huang*, Chun Zhang*, Palladium and Amino Acid Co-catalyzed Highly Regio- and Enantio-Selective Hydroarylation of Unbiased Alkenes. ACS Catalysis2022, 12, 8667-8675. link.


35. Juanjuan Wu, Hongli Wu, Xinyu Liu, Yuekun Zhang, Genping Huang*, Chun Zhang*, Nickel-catalyzed Cross-Coupling of Acyl Chloride with Racemic α-Trifluoromethyl Bromide to Access Chiral α-Trifluoromethyl Ketones. Org. Lett. 2022, 24, 4322-4327. link


34. Min Zhang, Yuqi Ji, Zheng Zhang, Chun Zhang*, Copper-Catalyzed Highly Selective Hydrosilylation of Silyl or Boryl Alkene: A Method to Prepare Chiral Geminated Disilyl and Borylsilyl Reagents. Org. Lett. 2022, 24, 2756-2761. link


33. Min Zhang,ǂ Yuqi Ji,ǂ Chun Zhang*, Transition Metal Catalyzed Enantioselective Migratory Functionalization Reactions of Alkenes through Chain-walking. Chin. J. Chem. 2022, 40, 1608-1622. (ǂcontributed equally, review paper) link


32. Jiapan Niu, Wenbo Liu, Chun Zhang*, Metal-free Thiolation and Hydroxylation of CF3-Substituted Alkene: a Practical Method to Synthesize Trifluoromethyl Tertiary Alcohol. Synthesis, 202254, 3977-3988. (Invited Feature Article)


31. Qitao Guan, Yuqi Ji, Qian Zhao, Chun Zhang*. Copper-Catalyzed Highly Enantioselective 1,4-Protoboration of Terminal 1,3-Diene. CCS Chem. 20224, 1545-1556. link


30. Mimi Xing, Huanhuan Cui, Chun Zhang*, Nickel-Catalyzed Reductive Cross-Coupling of Alkyl Bromides and Chlorosilanes. Org. Lett. 2021, 23, 7645-7649. link


29. Huanhuan Cui, Changhao Niu, Chun Zhang*, Aerobic Oxidative Cascade Thiolation and Cyclization to Construct Indole-Fused Isoquinolin-6(5H)‑one Derivatives in EtOH. J. Org. Chem. 2021, 86, 15835-15844. link


28. Chenchen Zouǂ, Changhao Niuǂ, Xinyu Liuǂ, Chun Zhang*, Recent Advances about Protoboration of Conjugated Dienes. Chin. J. Org. Chem. 2021, 41, 4240-4254. (ǂ contributed equally, Invited review paper) link


27. Juanjuan Wu, Hongli Wu, Xinzhi Li, Xinyu Liu, Qian Zhao, Genping Huang*, Chun Zhang*, Copper-Catalyzed Highly Selective Protoboration of CF3-containing 1,3-Dienes. Angew. Chem. Int. Ed. 2021, 60, 20376-20682. link


26. Qian Zhao, Jiawei Jiang, Wei Zhao, Sheng-Hua Li, Wenbo Mi*, Chun Zhang*. Truxone Based Conductive Metal-Organic Frameworks for Oxygen Reductive ReactionJ. Phys. Chem. C. 2021, 125, 12690-12698. link


25. Penglin Zhang, Cehnchen Zou, Qian Zhao, Chun Zhang*. Nickel-Catalyzed Alkenylboration of Alkenylarenes to Access Homoallylic Boronic Esters. Org. Chem. Front. 2021, 8, 2589-2594. link.  


24. Yuqi Jiǂ, Min Zhangǂ, Mimi Xingǂ, Huanhuan Cui, Qian Zhao, Chun Zhang*. Transition Metal Catalyzed Enantioselective Borylative Cyclization Reactions. Chin. J. Chem. 2021, 39, 391-401.  (ǂcontributed equally, review paper) link 



23. Zhanglang Zhou, Jin Zhou, Lan Chen,* Qian Zhao, Chun Zhang, Guanglu Ge*. Chirality reversal, enhancement and transfer by pH-adjusted surfactant assembly. Chem. Commun., 2020, 56, 15345-15348. link


22. Penglin Zhang, Min Zhang, Yuqi Ji, Mimi Xing, Qian Zhao and Chun Zhang*. Nickel-Catalyzed Highly Selective Hydroalkenylation of Alkenyl Boronic Esters to Access Allyl Boron. Org. Lett. 2020, 22, 8258-8290. link


21. Rumeng Zhang, Qifan Li, Min Zhang, Sida Chai, Yuqi Duan, Jingfei Su, Qian Zhao, and Chun Zhang*. Copper and Palladium Co-catalyzed Highly Regio-selective 1,2-Hydroarylation of Terminal 1,3-Diene. Chem. Commun., 2020, 56, 13551-13554. link


20. Penglin Zhang, Zhanglang Zhou, Rumeng Zhang, Qian Zhao, Chun Zhang*. Cu-Catalyzed highly regioselective 1,2-hydrocarboxylation of 1,3-dienes with CO2Chem. Commun., 2020, 56, 11469-11472. link

 


19. Qian Zhao,* Sheng-Hua Li, Rui-Lin Chai, Xv Ren, Chun Zhang*. Two-Dimensional Conductive Metal−Organic Frameworks Based on Truxene. ACS Appl. Mater. Interfaces. 2020, 12, 7504-7509. link


18. Penglin Zhang, Mimi Xing, Qitao Guan, Jinguo Zhang, Qian Zhao, Chun Zhang*. Pd-Catalyzed Stereoselective 1,2-Aryboration of Alkenylarenes. Org. Lett. 2019, 21, 8106-8109. link


17. Qifan Li, Xiaoyang Jiao, Mimi Xing, Penglin Zhang, Qian Zhao, Chun Zhang*. Cu-Catalyzed highly selective reductive functionalization of 1,3-diene using H2O as a stoichiometric hydrogen atom donor. Chem. Commun., 2019, 55, 8651-8654. link 


独立开展科研工作之前:

以第一作者发表文章:


16.    Chun Zhang, Celine B. Santiago, Jennifer M. Crawford, Matthew S. Sigman*, Enantioselective Dehydrogenative Heck Arylations of Tri-substituted Alkenes with Indoles to Construct Quaternary Stereocenters, J. Am. Chem. Soc. 2015, 137, 15668. 

 

15.    Chun Zhang, Celine B. Santiago, Lei Kou, Matthew S. Sigman*, Alkenyl Carbonyl Derivatives in Enantioselective Redox Relay Heck Reactions: Accessing α,β-Unsaturated Systems, J. Am. Chem. Soc. 2015, 137, 7290. 


14. Chun Zhang, Peng feng, Ning Jiao*, Cu-Catalyzed Esterification Reaction via Aerobic Oxygenation and C–C Bond Cleavage: An Approach to α-Ketoesters, J. Am. Chem. Soc. 2013135, 15257. 


13. Chun Zhang, Ning Jiao*, Dioxygen activation under ambient conditions: Cu-catalyzed      oxidative amidation−diketonization of terminal alkynes leading to α-ketoamides, J. Am. Chem. Soc. 2010132, 28. 


12. Chun Zhang, Zejun Xu, Liangren Zhang, Ning Jiao*, Copper-catalyzed aerobic oxidative coupling of aryl acetaldehydes with anilines leading to α-ketoamides, Angew. Chem. Int. Ed. 201150, 11088. 

 

11. Chun Zhang, Ning Jiao*, Copper-catalyzed aerobic oxidative dehydrogenative coupling of anilines leading to aromatic azo compounds using dioxygen as an oxidant, Angew. Chem. Int. Ed. 201049, 6174. 

 

10. Zejun Xu,§ Chun Zhang,§ Ning Jiao*, (§ These authors contributed equally to this work) Copper-mediated aerobic oxidative dehydrogenative annulation of aldehydes, amines and molecular oxygen for oxazoles via C-H functionalization and dioxygen activation. Angew. Chem. Int. Ed. 201251, 11367. 


9. Chun Zhang, Brandon Tutkowski, Ryan J. DeLuca, Leo A. Joyce, Olaf Wiest,  Matthew S. Sigman*, Palladium-catalyzed enantioselective Heck alkenylation of trisubstituted allylic alkenols: a redox-relay strategy to construct vicinal stereocenters, Chem. Sci.  20178, 2277. 


8. Chun Zhang, Conghui Tang, Ning Jiao*, Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process, Chem. Soc. Rev. 201241, 3464. 

 

7. Chun Zhang, Ning Jiao*, A Cu-catalyzed Practical Approach to α-Ketoesters under Air: an Efficient Aerobic Oxidative Dehydrogenative Coupling of Alcohols and α-Carbonyl Aldehydes, Org. Chem. Frontiers, 2014, 1, 109. 

 

6. Chun Zhang, Xiaoyang Wang, Ning Jiao*, Copper-Catalyzed Aerobic Oxidative C–C Bond Cleavage of 1,3-Diaryl­diketones To Synthesize 1,2-Diketones, Synlett, 2014, 25, 1458. 


5. Chun Zhang, Liangren Zhang, Ning Jiao*, Catalyst and additive free procedure to construct benzimidazoles using air as the oxidant under room temperature. Green Chem. 2012, 14, 3273. 

  

4. Chun Zhang, Xiaolin Zong, Liangren Zhang, Ning Jiao*, Copper-catalyzed aerobic oxidative cross-dehydrogenative coupling (CDC) of amine and α-carbonyl aldehyde: a pratical and efficient method to α-ketoamides with wide substrate scope. Org. Lett. 2012, 14, 3280. 

 

3. Chun Zhang, Zejun Xu, Tao Shen, Guolin Wu, Liangren Zhang, Ning Jiao*, Mn-mediated aerobic oxidative C-C bond cleavage of aldehydes with dioxygen activation: a simple synthetic approach to formamide. Org. Lett. 2012, 14, 2362. 

 

2. Chun Zhang, Zejun Xu, Liangren Zhang, Ning Jiao*, Et3N-catalyzed dehydrogenative oxidation of α-unsubstituted carbonyl compounds with aryl diamine leading to quinoxalines using molecular oxygen as oxidant. Tetrahedron. 2012, 68, 5258. 

 

1. Chun Zhang, Liangren Zhang, Ning Jiao*, Multiple oxidative dehydrogenative functionalization of aryl acetaldehydes using molecular oxygen as oxidant leading to 2-oxo-acetamidines. Adv. Synth. Catal. 2012, 354, 1293.