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A contribution to the perrhenate crystal chemistry: the crystal structures of new CdTh[MoO4]3-type compounds
Zeitschrift für Kristallographie - Crystalline Materials ( IF 1.2 ) Pub Date : 2022-10-14 , DOI: 10.1515/zkri-2022-0043
Dmitri O. Charkin 1 , Pavel A. Chachin 1 , Evgeni V. Nazarchuk 2 , Oleg I. Siidra 2, 3
Affiliation  

Singe crystals of four new A I M II[ReO4]3 perrhenates (A I = Na, M II = Pb; A I = Na, M II = Sr, Ag, K) have been prepared from the respective A I[ReO4] and M II[ReO4]2 perrhenates using melt and solution evaporation techniques. All new compounds belong to the hexagonal CdTh[MoO4]3 structure type, similar to previously known NaCa[ReO4]3. We discuss the crystal chemical relationships within this structure type and suggest existence of some more representatives involving other tetrahedral anions.

中文翻译:

对高铼酸盐晶体化学的贡献:新型 CdTh[MoO4]3 型化合物的晶体结构

烧四新晶一个 [铼4]3高铼 (一个 = 钠, =铅;一个 = 钠, = Sr、Ag、K) 已从各自的一个 [铼4] 和 [铼4]2使用熔体和溶液蒸发技术的高铼酸盐。所有新化合物都属于六方 CdTh[MoO4]3结构类型,类似于以前已知的 NaCa[ReO4]3. 我们讨论了这种结构类型内的晶体化学关系,并建议存在一些涉及其他四面体阴离子的更多代表。
更新日期:2022-10-14
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