Abstract

Methods developed over the past 60 years for the preparation of unbranched С₆–С₁₄ 2-ketones by catalytic oxidation of linear α-olefins have been analyzed and summarized. Particular attention has been paid to the consideration of the catalytic Wacker system, which is important for industrial organic synthesis, and the proposed ways for its modification. Methods for controlling the reaction selectivity have been discussed, and the role of cocatalysts, oxidizing agents, and ligands has been considered.

中文翻译：

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生产高级 2-酮的催化方法：瓦克体系在 α-烯烃氧化中的前景（综述）

摘要

分析和总结了过去 60 年来通过催化氧化直链 α-烯烃制备无支链 С ₆ –С _{14 2-酮的方法。}特别注意了对工业有机合成很重要的催化 Wacker 系统的考虑，以及对其改进的建议方法。讨论了控制反应选择性的方法，并考虑了助催化剂、氧化剂和配体的作用。