Abstract

Methods for obtaining basic substituted gem-dichlorocyclopropanes and 1,3-dioxacyclanes based on petroleum products are considered. Separate reactions of O-, N-, C-alkylation of these compounds leading to the formation of heterocycles containing gem-dichlorocyclopropane and 1,3-dioxolane fragments are presented. Data are provided on radical polymerization, copolymerization, low-temperature ozonolysis, catalytic isomerization of vinyl-gem-dichlorocyclopropanes, as well as the study of reactions of 2,2-dimethyl-1,3-dioxolane with diazoacetoacetic ester. The possibilities of using the synthesized substances as biologically active compounds, as well as preparations capable of inhibiting the acid corrosion of metals, are shown.

中文翻译：

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宝石二氯环丙烷和 1,3-二氧杂环烷：基于石油产品的合成及其在低吨位化学中的应用

摘要

考虑了基于石油产品获得碱性取代偕二氯环丙烷和1,3-二氧杂环烷的方法。提出了这些化合物的O-、N-、C-烷基化的单独反应，导致形成含有偕二氯环丙烷和1,3-二氧戊环片段的杂环。提供了乙烯基-宝石的自由基聚合、共聚、低温臭氧分解、催化异构化的数据-二氯环丙烷，以及 2,2-二甲基-1,3-二氧戊环与重氮乙酰乙酸酯的反应研究。显示了使用合成物质作为生物活性化合物以及能够抑制金属酸腐蚀的制剂的可能性。